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    Thermoplastic linoleum
    11.
    发明授权
    Thermoplastic linoleum 失效
    热塑性油毡

    公开(公告)号：US08697795B2

    公开(公告)日：2014-04-15

    申请号：US13216391

    申请日：2011-08-24

    申请人： Konrad Knoll ,  Michel Pepers

    发明人： Konrad Knoll ,  Michel Pepers

    IPC分类号： C08K5/09 ,  C09B67/00

    CPC分类号： C08F8/46 ,  C08F22/14 ,  C08L25/06 ,  C08L25/12 ,  C09F7/06 ,  C08F242/00 ,  C08L51/006 ,  C08L53/02

    摘要： The present invention relates to a thermoplastic molding composition at least comprising particles made of nonoxidatively polymerized vegetable oil which has been crosslinked by way of functional groups, as component (A), at least one thermoplastic polymer, as component (B), optionally at least one resin, as component (C), optionally at least one filler, as component (D), and optionally further additives, use thereof and a process for production thereof.

    摘要翻译： 本发明涉及一种热塑性模塑组合物，其至少包含通过官能团交联的非氧化聚合植物油，作为组分（A），至少一种热塑性聚合物作为组分（B），任选地至少 一种树脂，作为组分（C），任选的至少一种填料，作为组分（D），以及任选的其它添加剂，其用途及其制备方法。

    THERMOPLASTIC MOULDING COMPOSITION WITH IMPROVED ADHESION OF ELECTROPLATED METAL LAYER
    12.
    发明申请
    THERMOPLASTIC MOULDING COMPOSITION WITH IMPROVED ADHESION OF ELECTROPLATED METAL LAYER 审中-公开
    具有改善电镀金属层粘合的热塑性成型组合物

    公开(公告)号：US20120034478A1

    公开(公告)日：2012-02-09

    申请号：US13206139

    申请日：2011-08-09

    申请人： Michel Pepers ,  Klaus Wendel ,  Davy Roger Suwier ,  Norbert Nießner

    发明人： Michel Pepers ,  Klaus Wendel ,  Davy Roger Suwier ,  Norbert Nießner

    IPC分类号： B32B15/082 ,  B29C71/00 ,  B32B27/28 ,  C08L51/00 ,  B05D7/00

    CPC分类号： C08F279/02 ,  C08F212/10 ,  C08F222/08 ,  C08L25/12 ,  C08L55/02 ,  Y10T428/31696 ,  Y10T428/31699 ,  C08L35/06 ,  C08F220/44 ,  C08F212/08

    摘要： A thermoplastic moulding composition with improved metal plating properties is provided. This thermoplastic moulding composition is produced from a graft copolymer (A) a thermoplastic polymer (B) and a thermoplastic polymer (C) that is not, or only to a limited amount miscible with the thermoplastic polymer (B). The thermoplastic polymer (C) contains from 1.2 to 3% by weight of at least one monoethylenically unsaturated monomer, like acrylic acid, methacrylic acid, or dicarboxylic acids, such as maleic acid and fumaric acid and their anhydrides, such as maleic anhydride. The vinyl aromatic content of component (C) is at least 5 units lower compared to that of component (B).The graft copolymer is produced from a soft elastomeric particulate graft base with a glass transition temperature below 0° C. obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer or of at least one C1-8-alkyl acrylate, or of mixtures of these, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer.

    摘要翻译： 提供了具有改善的金属电镀性能的热塑性模塑组合物。 这种热塑性模塑组合物是由热塑性聚合物（B）和热塑性聚合物（C）的接枝共聚物（A）制成的，该热塑性聚合物（C）不是或只有与热塑性聚合物（B）可混溶的有限量。 所述热塑性聚合物（C）含有1.2至3重量％的至少一种单烯属不饱和单体，如丙烯酸，甲基丙烯酸或二羧酸，如马来酸和富马酸及其酸酐，如马来酸酐。 组分（C）的乙烯基芳族化合物含量比组分（B）的乙烯基芳族化合物含量低5个单位。 接枝共聚物由玻璃化转变温度低于0℃的软弹性体颗粒接枝基质制备，通过共轭二烯单独或与少量的单烯键式不饱和单体或至少一种C 1-8 - 丙烯酸烷基酯或它们的混合物，其上接枝乙烯基芳族单体和丙烯腈以及任选的另一种单烯属不饱和单体。

    THERMOPLASTIC MOULDING COMPOSITIONS FOR METAL PLATED ARTICLES WITH IMPROVED RESISTANCE AGAINST REPEATED IMPACT
    15.
    发明申请
    THERMOPLASTIC MOULDING COMPOSITIONS FOR METAL PLATED ARTICLES WITH IMPROVED RESISTANCE AGAINST REPEATED IMPACT 有权
    用于金属制品的热塑性成型组合物具有改善的抗重复性影响的电阻

    公开(公告)号：US20140329100A1

    公开(公告)日：2014-11-06

    申请号：US13992602

    申请日：2011-12-15

    申请人： Michel Pepers ,  Christian Schade ,  Davy Roger Suwier ,  Norbert Niessner

    发明人： Michel Pepers ,  Christian Schade ,  Davy Roger Suwier ,  Norbert Niessner

    IPC分类号： C08L25/12 ,  C23C18/31 ,  C23C18/16

    CPC分类号： C08L25/12 ,  C08L9/00 ,  C08L21/00 ,  C08L25/10 ,  C08L51/00 ,  C08L55/02 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2207/04 ,  C23C18/1601 ,  C23C18/1641 ,  C23C18/31 ,  C25D5/14 ,  C25D5/56 ,  Y10T428/31696

    摘要： Thermoplastic moulding composition (F), comprising: A) from 5 to 80% by weight of a graft polymer (A) having bimodal particle size distribution and a moisture content of 0 to 27% by weight, made, based on (A), a1) from 40 to 90% by weight of an elastomeric particulate graft base (a1), obtained by emulsion polymerization of based on (a1), a11) from 70 to 100% by weight of at least one conjugated diene, or of at least one C1-8-alkyl acrylate, or of mixtures of these, a12) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer and a13) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; a2) from 10 to 60% by weight of a graft a2), made, based on a2), a21) from 64 to 76% by weight of at least one vinyl aromatic monomer, a22) from 24 to 36% by weight of acrylonitrile, a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, and a24) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; B) from 10 to 94% by weight of a thermoplastic polymer (B) having a viscosity number VN of from 50 to 120 ml/g, made, based on (B), b1) from 64 to 72% by weight of at least one vinyl aromatic monomer, b2) from 28 to 36% by weight of acrylonitrile, and b3) from 0 to 4% by weight of at least one other monoethylenically unsaturated monomer; whereby, the difference of the acrylonitrile content in component (B) and that in the graft shell a2) is minimal 2% by weight and maximal 6% by weight and optionally further components, have preferred optical appearance when coated with metal.

    摘要翻译： 热塑性成型组合物（F），其包含：A）5-80重量％的具有双峰粒径分布的接枝聚合物（A）和0-27重量％的水分含量，基于（A）， a1）40〜90重量％的通过基于（a1），a11）的乳液聚合获得的弹性体颗粒接枝基质（a1），70〜100重量％的至少一种共轭二烯，或至少 一种C 1-8 - 烷基丙烯酸酯，或它们的混合物，a12）0至30重量％的至少一种其它单烯属不饱和单体和（ⅰ）0至10重量％的至少一种多官能交联单体 ; a2）10至60重量％的基于a2）制备的接枝物a2），a21）64至76重量％的至少一种乙烯基芳族单体，a22）24至36重量％的丙烯腈 ，a23）0至30重量％的至少一种其它单烯属不饱和单体，以及a24）0至10重量％的至少一种多官能交联单体; B）10至94重量％的基于（B），b1）的粘度VN为50至120ml / g的热塑性聚合物（B），至少64至72重量％ 一种乙烯基芳族单体，b2）28-36重量％的丙烯腈，和b3）0-4重量％的至少一种其它单烯属不饱和单体; 由此，组分（B）中的丙烯腈含量与接枝壳a2）中的丙烯腈含量的差异最小为2重量％，最多6重量％，任选的其它组分在涂覆金属时具有优选的光学外观。

    Thermoplastic molding compositions with improved optical properties
    16.
    发明授权
    Thermoplastic molding compositions with improved optical properties 失效
    具有改善光学性能的热塑性模塑组合物

    公开(公告)号：US08501868B2

    公开(公告)日：2013-08-06

    申请号：US13072099

    申请日：2011-03-25

    申请人： Matthias Müller ,  Ludger Leber ,  Achim Datko ,  Leonie Felicitas Braun ,  Christian Lemaire ,  Piyada Charoensirisomboon ,  Michel Pepers

    发明人： Matthias Müller ,  Ludger Leber ,  Achim Datko ,  Leonie Felicitas Braun ,  Christian Lemaire ,  Piyada Charoensirisomboon ,  Michel Pepers

    IPC分类号： C08L33/12 ,  C08L51/06 ,  C08L25/12 ,  C08L33/20 ,  C08L51/04

    CPC分类号： C08L33/12 ,  C08F285/00 ,  C08L25/00 ,  C08L51/003 ,  C08L51/04 ,  C08L2207/53 ,  C08L25/12 ,  C08F212/08

    摘要： The present invention relates to thermoplastic molding compositions having a mixture of (a) from 10 to 50% by weight of a methyl methacrylate polymer as component (A), from 20 to 60% by weight of a copolymer as component (B), and from 20 to 70% by weight of a graft copolymer as component (C). Component (C) is obtainable from components (c1) a core, (c2) a first graft shell, and (c3) a second graft shell. The second graft shell (c3) is obtainable via polymerization of a C1-C8-alkyl ester of methacrylic acid as component (c31) and a further vinylaromatic monomer as component (c32). Graft copolymer (C) is produced via emulsion polymerization and is isolated from the reaction mixture by precipitation resulting from shear. Also disclosed are processes for producing the molding compositions, the use of the molding compositions, and moldings obtainable from the molding compositions.

    摘要翻译： 本发明涉及具有（a）10至50重量％的作为组分（A）的甲基丙烯酸甲酯聚合物，20至60重量％的作为组分（B）的共聚物的混合物的热塑性模塑组合物，以及 20〜70重量％的作为组分（C）的接枝共聚物。 组分（C）可从组分（c1）芯，（c2）第一接枝壳和（c3）第二接枝壳获得。 第二接枝壳（c3）可通过作为组分（c31）的甲基丙烯酸的C 1 -C 8烷基酯和作为组分（c32）的另外的乙烯基芳族单体的聚合获得。 接枝共聚物（C）通过乳液聚合制备，并通过剪切产生的沉淀从反应混合物中分离。 还公开了用于生产模塑组合物的方法，模塑组合物的使用以及可从成型组合物获得的模制品。

    THERMOPLASTIC MOLDING COMPOSITIONS WITH IMPROVED OPTICAL PROPERTIES
    18.
    发明申请
    THERMOPLASTIC MOLDING COMPOSITIONS WITH IMPROVED OPTICAL PROPERTIES 失效
    具有改进的光学性质的热塑性成型组合物

    公开(公告)号：US20110237749A1

    公开(公告)日：2011-09-29

    申请号：US13072099

    申请日：2011-03-25

    申请人： Matthias Müller ,  Ludger Leber ,  Achim Datko ,  Leonie Felicitas Braun ,  Christian Lemaire ,  Piyada Charoensirisomboon ,  Michel Pepers

    发明人： Matthias Müller ,  Ludger Leber ,  Achim Datko ,  Leonie Felicitas Braun ,  Christian Lemaire ,  Piyada Charoensirisomboon ,  Michel Pepers

    IPC分类号： C08L51/06 ,  C08L33/12 ,  C08L33/20

    CPC分类号： C08L33/12 ,  C08F285/00 ,  C08L25/00 ,  C08L51/003 ,  C08L51/04 ,  C08L2207/53 ,  C08L25/12 ,  C08F212/08

    摘要： The present invention relates to thermoplastic molding compositions comprising a mixture of (a) from 10 to 50% by weight, based on the entirety of components (A), (B), and (C), of a methyl methacrylate polymer as component (A), and (b) from 20 to 60% by weight, based on the entirety of components (A), (B), and (C), of a copolymer as component (B), obtainable via polymerization of a vinylaromatic monomer and of a vinyl cyanide, and (c) from 20 to 70% by weight, based on the entirety of components (A), (B), and (C), of a graft copolymer as component (C), obtainable from (c1) from 50 to 70% by weight, based on (C), of a core as component (C1), obtainable via polymerization of a 1,3-diene and of a vinylaromatic monomer and an agglomeration polymer, and (c2) from 15 to 25% by weight, based on (C), of a first graft shell as component (C2), obtainable via polymerization of a vinylaromatic monomer, of a C1-C8-alkyl ester of methacrylic acid, and/or of a C1-C8-alkyl ester of acrylic acid, and a crosslinking monomer, and (c3) from 15 to 25% by weight, based on (C), of a second graft shell as component (C3), obtainable via polymerization of a C1-C8-alkyl ester of methacrylic acid as component (C31) and a further monomer as component (C32), where it is essential to the invention that component (C32) is a vinylaromatic monomer and the graft copolymer (C) is produced via emulsion polymerization and is isolated from the reaction mixture by precipitation resulting from shear, and also to processes for producing said molding compositions, to the use of these, and to the moldings obtainable therefrom.

    摘要翻译： 本发明涉及热塑性模塑组合物，其包含（a）10至50重量％，基于组分（A），（B）和（C）的组分（A），（B）和（C））的混合物，所述甲基丙烯酸甲酯聚合物作为组分 A），（b）20〜60重量％，作为成分（B）的共聚物的组分（A），（B）和（C）的全部，可通过乙烯基芳族单体 和（c）20〜70重量％的组分（A），（B）和（C））作为组分（C）的接枝共聚物，可从（ c1）基于（C）50〜70重量％的作为组分（C1）的芯可通过1,3-二烯和乙烯基芳族单体和附聚聚合物的聚合获得，和（c2）从 15重量％至25重量％，基于（C），作为组分（C2）的第一接枝壳可通过乙烯基芳族单体聚合得到甲基丙烯酸的C 1 -C 8烷基酯和/或C 1 -C 8烷基酯 丙烯酸的-C8-烷基酯，和a 交联单体和（c3）15至25重量％，基于（C），作为组分（C 3）的第二接枝壳可通过作为组分（C31）的甲基丙烯酸的C 1 -C 8烷基酯的聚合 ）和作为组分（C32）的另外的单体，其中本发明组分（C32）是乙烯基芳族单体并且通过乳液聚合制备接枝共聚物（C）是重要的，并且通过沉淀从反应混合物中分离 剪切，以及用于生产所述模塑组合物的方法，使用它们以及由其获得的模制品。