摘要:
Disclosed is an electrode slurry comprising: (a) an electrode active material capable of lithium intercalation/deintercalation; and (b) monomers capable of forming a polymer via polymerization. An electrode having a binder polymer formed by applying the electrode slurry onto a current collector and carrying out in situ polymerization of the monomers, and an electrochemical device comprising the electrode are also disclosed. The electrode uses monomers capable of forming a binder polymer via polymerization under heat or light upon drying of the electrode, instead of the conventional PVdF or SBR-based binders. Therefore, it is possible to simplify a process for manufacturing an electrode, to provide an eco-friendly electrode by virtue of the use of an aqueous solvent as a dispersion medium, to improve the ion conductivity of a binder by virtue of the use of a solvent for a battery electrolyte as a dispersion medium, and thus to improve the quality of an electrochemical device.
摘要:
Disclosed are anode active material slurry for a lithium secondary cell having improved dispersibility of an anode active material and a conductive agent, and a lithium secondary cell comprising the same. Particularly, the present invention is characterized by adding a dispersant comprising a polymer backbone capable of surface-adsorption and a side-chain having non-ionic surfactant properties in a small amount, to the anode active material slurry comprising a carbon-based anode active material that is capable of lithium ion intercalation/deintercalation, a conductive agent, a binder comprising a styrene-butadiene-based polymer resin, a thickener comprising a cellulose-based or an acrylate-based resin, and water.
摘要:
Disclosed is an electrode, comprising a coating layer of crosslinked polymer, formed on a surface of electrode active material particles, while maintaining a pore structure formed among the electrode active material particles interconnected to each other in the electrode. A method for manufacturing the electrode and an electrochemical device comprising the electrode are also disclosed. The electrode, which comprises a coating layer of crosslinked polymer formed on the surface of the electrode active material particles, can improve the safety of a battery, while minimizing degradation in the quality of a battery.
摘要:
Disclosed is a lithium secondary battery comprising: (a) a cathode; (b) an anode; (c) a separator; and (d) a non-aqueous electrolyte comprising a lithium salt and an organic solvent, wherein the cathode comprises a cathode active material, doped with at least one element selected from the group consisting of Sn, Al and Zr, or containing the element in the form of a solid solution, and the non-aqueous electrolyte comprises a lithium-containing inorganic salt and a lithium imide salt dissociated in at least one organic solvent including gamma-butyrolactone (GBL). The lithium secondary battery can minimize side reactions between both electrodes and gamma-butyrolactone (GBL), used as a conventional electrolyte for a battery, and thus can provide high capacity, long service life and improved quality at high-temperature.
摘要:
Disclosed is an organic/inorganic composite porous film comprising: (a) a porous substrate having pores; and (b) an active layer formed by coating a surface of the substrate or a part of the pores in the substrate with a mixture of inorganic particles and a binder polymer, wherein the inorganic particles in the active layer are interconnected among themselves and are fixed by the binder polymer, and interstitial volumes among the inorganic particles form a pore structure. A method for manufacturing the same film and an electrochemical device including the same film are also disclosed. An electrochemical device comprising the organic/inorganic composite porous film shows improved safety and quality, simultaneously.
摘要:
The present invention provides a separator in which an electrolyte-soluble polymer, which is soluble in liquid electrolyte, is coated on one or both surfaces of the separator, as well as an electrochemical device including the separator. Also, the present invention provides a method for producing an electrochemical device, comprising the steps of: (a) coating an electrolyte-soluble polymer, which is soluble in liquid electrolyte, on one or both surfaces of a separator; (b) interposing the separator produced in the step (a) between a cathode and an anode so as to assemble an electrochemical device; and (c) injecting a liquid electrolyte into the electrochemical device produced in the step (b). The electrochemical device, such as a lithium secondary battery, produced by the inventive method, has an improved safety while deterioration in the battery performance is minimized.
摘要:
Disclosed is an electrode active material comprising: (a) electrode active material particles capable of lithium intercalation/deintercalation; and (b) a multinary oxide coating layer partially or totally formed on the surface of the electrode active material particles, the multinary oxide coating layer comprising Al, P and a halogen element. A method for preparing the electrode active material, an electrode using the electrode active material, and an electrochemical device comprising the electrode, preferably a lithium secondary battery, are also disclosed. The electrode active material comprising a multinary oxide coating layer has improved structural stability and thermal safety, and thus can provide an electrochemical device having high capacity, long service life and excellent safety.
摘要:
Disclosed is an organic/inorganic composite porous film comprising: (a) inorganic particles; and (b) a binder polymer coating layer formed partially or totally on surfaces of the inorganic particles, wherein the inorganic particles are interconnected among themselves and are fixed by the binder polymer, and interstitial volumes among the inorganic particles form a micropore structure. A method for manufacturing the same film and an electrochemical device including the same film are also disclosed. An electrochemical device comprising the organic/inorganic composite porous film shows improved safety and quality.
摘要:
Disclosed is an electrochemical device including an electrode assembly having a cathode, anode and an electrolyte, and a casing surrounding the electrode assembly. The device further includes a protection device to which either or both of a cathode lead for connecting a cathode with an outer terminal and an anode lead for connecting an anode with an outer terminal are connected electrically, wherein the protection device is disposed in the inner space of the casing and the electrode lead equipped with the protection device is folded at both sides of the protection device so that the largest surface of the protection device is layered on a lateral surface of the casing where the electrode lead is present.
摘要:
The present invention provides a cathode produced from a cathode slurry comprising: (a) a cathode active material based on a lithium-containing metal composite oxide or a chalcogenide compound; and (b) an ionic liquid, as well as an electrochemical device including the cathode. The inventive cathode can greatly improve the safety of batteries without causing a significant deterioration in the battery performance.