Decomposing system for polyisocyanate residues, and start-up method for the same
    11.
    发明申请
    Decomposing system for polyisocyanate residues, and start-up method for the same 有权
    多异氰酸酯残留分解体系及其启动方法

    公开(公告)号:US20090137847A1

    公开(公告)日:2009-05-28

    申请号:US11988678

    申请日:2006-07-12

    摘要: An object of the invention is to provide a decomposing system for polyisocyanate residues that is capable of suppressing reaction of polyisocyanate residues with high temperature and high pressure water to allow smooth start-up of the operation, and a start-up method for the decomposing system for the polyisocyanate residues. The decomposing system is used for hydrolyzing the polyisocyanate residues to polyamine using high temperature and high pressure water, comprising a hydrolyzer, a water feed pipe connected to the hydrolyzer, a residual feed pipe connected to the water feed pipe, a solvent feed line for filling an organic solvent in a solvent filling portion of the residual feed pipe, and a solvent draining line. Upon start-up of the operation, the organic solvent is previously filled in the solvent filling portion via the solvent feed line and the solvent draining line, first, and then, the high temperature and high pressure water is fed from the water feed pipe to the hydrolyzer. Then, the organic solvent is fed from the residual feed pipe to the water feed pipe, first, and then, the polyisocyanate residues are fed thereto.

    摘要翻译: 本发明的目的是提供一种能够抑制多异氰酸酯残留物与高温高压水反应以使操作顺利启动的多异氰酸酯残留分解系统,以及分解系统的启动方法 对于多异氰酸酯残基。 分解系统用于使用高温高压水将多异氰酸酯残基水解成多胺,包括水解器,连接到水解器的给水管,连接到给水管的残余进料管,用于填充的溶剂进料管 剩余进料管的溶剂填充部分中的有机溶剂和溶剂排出管线。 在操作开始时,首先通过溶剂供给管线和溶剂排出管路先将有机溶剂填充到溶剂填充部分中,然后将高温高压水从供水管供给到 水解产物。 然后,将有机溶剂从剩余进料管供给到给水管,首先,向其中供给多异氰酸酯残渣。

    Aqueous polyurethane resin
    14.
    发明申请
    Aqueous polyurethane resin 有权
    水性聚氨酯树脂

    公开(公告)号:US20090326147A1

    公开(公告)日:2009-12-31

    申请号:US12311024

    申请日:2007-09-10

    申请人: Takashi Uchida

    发明人: Takashi Uchida

    IPC分类号: C08L75/04

    摘要: An aqueous polyurethane resin having a Si atom content of 0.05 to 1.5% by weight in a polyurethane resin is produced by at least reacting an isocyanate group-terminated prepolymer which contains 1 to 15% by weight of a polyoxyethylene group in a side chain branched from the main chain and has two or more isocyanate groups at an end of the main chain, with a chain extender which contains at least a compound having two or more active hydrogen groups reactive with the isocyanate group and an alkoxysilyl group.

    摘要翻译: 在聚氨酯树脂中的Si原子含量为0.05〜1.5重量%的水性聚氨酯树脂通过至少使含有1〜15重量%的聚氧乙烯基团的异氰酸酯基封端的预聚物在侧链中分支 主链,并且在主链末端具有两个或更多个异氰酸酯基团,扩链剂至少含有具有与异氰酸酯基反应的两个或更多个活性氢基团的化合物和烷氧基甲硅烷基。

    (Meth)acrylate-grafted polyether polyol, and production process and use thereof
    15.
    发明申请
    (Meth)acrylate-grafted polyether polyol, and production process and use thereof 审中-公开
    (甲基)丙烯酸酯接枝聚醚多元醇及其制备方法和用途

    公开(公告)号:US20090111952A1

    公开(公告)日:2009-04-30

    申请号:US11991283

    申请日:2006-08-31

    摘要: A (meth)acrylate-grafted polyether polyol produced by reacting 40 to 95 parts by weight of a polyoxyalkylene polyol and 5 to 60 parts by weight of a vinyl monomer, both relative to 100 parts by weight of the sum total of the polyoxyalkylene polyol and the vinyl monomer, and 0.1 to 5 moles of an alkyl peroxide as a radical initiator per mole of the hydroxyl group in the polyoxyalkylene polyol, wherein the polyoxyalkylene polyol has a hydroxyl number of 25 mg KOH/g or less, and the vinyl monomer contains a (meth)acrylate and/or a hydroxyl-containing (meth)acrylate in an amount of 50% by weight or higher. The (meth)acrylate-grafted polyether polyol is excellent in colorless-transparency, compatibility, mechanical strength, weather resistance, and blending resistance, and therefore is useful as a raw material for a polyurethane resin cured article.

    摘要翻译: 通过使40〜95重量份的聚氧化烯多元醇与5〜60重量份的乙烯基单体反应而得到的(甲基)丙烯酸酯接枝的聚醚多元醇,相对于100重量份的聚氧化烯多元醇和 乙烯基单体和0.1〜5摩尔作为自由基引发剂的烷基过氧化物,相对于聚氧化烯多元醇中的每摩尔羟基,其中聚氧化烯多元醇的羟值为25mgKOH / g以下,乙烯基单体含有 (甲基)丙烯酸酯和/或含羟基的(甲基)丙烯酸酯的量为50重量%以上。 (甲基)丙烯酸酯接枝聚醚多元醇的无色透明性,相容性,机械强度,耐候性和共混性优异,因此可用作聚氨酯树脂固化物的原料。

    Apparatus for Continuously Producing Polyisocyanate
    16.
    发明申请
    Apparatus for Continuously Producing Polyisocyanate 有权
    用于连续生产多异氰酸酯的设备

    公开(公告)号:US20090081086A1

    公开(公告)日:2009-03-26

    申请号:US11887583

    申请日:2006-03-30

    IPC分类号: B01J19/18

    摘要: An apparatus for continuously producing polyisocyanate is provided for quickly contacting polyamine and carbonyl chloride in order to suppress an undesirable reaction between polyamine and polyisocyanate so that a by-product can be reduced and the yield of polyisocyanate can be improved. In a circulatory line 7, a material-mixing portion 8, a high-shear pump 3, a reactor 4, a liquid-feeding pump 5 and a cooler 6 are interposed in series along the direction of the flow of a reaction solution, thereby forming a closed line. In this apparatus 1, after polyamine and carbonyl chloride are supplied in the material-mixing portion 8, the reaction solution is sheared by the high-shear pump 3 in a state where the contact of the polyamine with the reaction solution is minimized. Thus, the formation of a urea compound as a by-product can be suppressed and the yield of polyisocyanate can be improved.

    摘要翻译: 提供连续制备多异氰酸酯的装置,用于快速接触多胺和碳酰氯,以抑制多胺和多异氰酸酯之间不期望的反应,从而可以降低副产物并提高多异氰酸酯的产率。 在循环管线7中,沿着反应溶液的流动方向串联插入材料混合部分8,高剪切力泵3,反应器4,送液泵5和冷却器6,由此 形成封闭线。 在该装置1中,在物料混合部分8中供给多胺和碳酰氯之后,在多胺与反应溶液的接触最小化的状态下,通过高剪切泵3剪切反应溶液。 因此,可以抑制作为副产物的尿素化合物的形成,并且可以提高多异氰酸酯的收率。

    Polyisocyanate Production System and Gas Treatment Apparatus
    17.
    发明申请
    Polyisocyanate Production System and Gas Treatment Apparatus 有权
    多异氰酸酯生产系统和气体处理设备

    公开(公告)号:US20080138252A1

    公开(公告)日:2008-06-12

    申请号:US11597756

    申请日:2006-03-17

    IPC分类号: B01J19/00

    摘要: A polyisocyanate production system is provided that can stably produce chlorine from hydrogen chloride produced secondarily while reacting stably between carbonyl chloride and polyamine and can perform an effective treatment of the hydrochloric gas produced secondarily. A hydrochloric gas control unit 32 controls a flow-rate control valve 23 to keep constant an amount of hydrogen chloride supplied from a hydrogen chloride purifying tank 4 to a hydrogen chloride oxidation reactor 6 via a second hydrochloric-gas connection line 11 to be constant, and also controls a pressure control valve 22 based on an inner pressure of the hydrogen chloride purifying tank 4 input from a pressure sensor 25 to discharge the hydrochloric gas from the hydrogen chloride purifying tank 4 to the hydrogen chloride absorbing column 5 via a first hydrochloric-gas connection line 10, so as to keep an inner pressure of the hydrogen chloride purifying tank 4 to be constant.

    摘要翻译: 提供了一种多异氰酸酯生产系统,其能够在氯化碳和多胺之间稳定反应的同时使氯化氢稳定地产生氯,同时可以对二次生成的盐酸进行有效的处理。 盐酸气体控制单元32控制流量控制阀23,使得从氯化氢净化槽4经由第二盐酸气体连接管线11将氯化氢供给到氯化氢氧化反应器6的量恒定, 并且还基于从压力传感器25输入的氯化氢净化槽4的内部压力来控制压力控制阀22,以通过第一盐酸盐排出氯化氢净化槽4的氯化氢气体到氯化氢吸收塔5。 气体连接管线10,以使氯化氢净化槽4的内部压力保持恒定。

    Aqueous Polyurethane Resin and Method For Producing Aqueous Polyurethane Resin and Film
    18.
    发明申请
    Aqueous Polyurethane Resin and Method For Producing Aqueous Polyurethane Resin and Film 有权
    水性聚氨酯树脂及其生产水性聚氨酯树脂和薄膜的方法

    公开(公告)号:US20080045650A1

    公开(公告)日:2008-02-21

    申请号:US11792382

    申请日:2005-12-08

    IPC分类号: C08G18/10 C08G18/08 C08L75/04

    摘要: An object of the present invention is to provide an aqueous polyurethane resin in which stable emulsion is formed, the balance between hydrophilicity and hydrophobicity is controlled and an obtained film has desired permeability and good stability, a method for producing the aqueous polyurethane resin, and a film obtained from the aqueous polyurethane resin. The aqueous polyurethane resin of the present invention includes a plurality of polyurethane resins obtained by reacting macropolyol, polyisocyanate, and a chain extender, and each of the aqueous polyurethane resins contains the macropolyols which are different from one another, and each of the aqueous polyurethane resins is chemically bonded partially to one another through the chain extender. By casting or coating the aqueous polyurethane resin, the film is obtained.

    摘要翻译: 本发明的目的是提供一种其中形成稳定乳液的水性聚氨酯树脂,控制亲水性和疏水性之间的平衡,并且所得膜具有期望的渗透性和良好的稳定性,制备水性聚氨酯树脂的方法和 从水性聚氨酯树脂获得的膜。 本发明的水性聚氨酯树脂包括通过大分子多元醇,多异氰酸酯和扩链剂反应获得的多种聚氨酯树脂,并且每种水性聚氨酯树脂含有彼此不同的大多异氰酸酯,并且每种水性聚氨酯树脂 通过扩链剂彼此部分化学键合。 通过浇铸或涂布水性聚氨酯树脂,得到膜。