Abstract:
Provided is a regeneration rotary kiln capable of reducing the proportion of combustible gas in waste gas and capable of reducing cost for generating superheated steam.A regeneration rotary kiln (1) is characterized by including: a superheated steam generation unit (2) that generates superheated steam; a tube (3) capable of rotating about its axis and having a heating section (A) where, while the superheated steam is being supplied thereto, carbon fiber reinforced plastic (10) containing a matrix resin and carbon fibers is heated to generate combustible gas (10G) from the matrix resin to extract the carbon fibers (10S) from the carbon fiber reinforced plastic (10); a first combustion chamber (43a) that is placed outside the tube (3) and that burns the gas (10G) introduced from the heating section (A) to heat the heating section (A); and a second combustion chamber (43b) that burns the gas (10G) introduced from the first combustion chamber (43a) to supply heat for generating the superheated steam.
Abstract:
The invention relates to a method for recovering organic fibers from a composite material comprising a polymer matrix and organic fibers, wherein the method comprises the following steps: providing a solution comprising a mixture of water and alcohol; placing the composite material inside a reactor; contacting the mixture and the composite material in order to perform a solvolysis reaction of the composite material; and recovering the organic fibers; wherein the pressure and the temperature in the reactor are adjusted such as to fall within the homogeneous sub-critical range of the phase diagram, within the super-critical range or near the critical point; and wherein the temperature is lower than the melting temperature of the organic fibers.
Abstract:
The present invention is a method for decomposing a polymer material by chemically decomposing a polymer material containing a first monomer and a second monomer in a mixture of the polymer material with the first monomer or a derivative of the first monomer to produce a chemical raw material. A relationship between a proportion of number of molecules of the second monomer to number of molecules of the first monomer in a reaction system for decomposing the polymer material and the molecular weight of the chemical raw material produced in the reaction system is acquired in advance (S101). Subsequently, an addition mount of the derivative of the first monomer to be added to the polymer material is determined based on the above relationship (S102). The first monomer in the addition amount determined is then mixed with the polymer material (S103).
Abstract:
The present invention relates to a method for decomposing, in the presence of subcritical water, a thermosetting resin comprising a polyester moiety and a crosslinking moiety therewith to provide a compound comprising an acid residue derived from the polyester moiety and a residue derived from the crosslinking moiety, and collecting the compound in an efficient yield, specifically, which comprises steps of: (I) decomposing the thermosetting resin in the presence of subcritical water to provide a solid comprising a compound comprising an acid residue derived from the polyester moiety and a residue derived from the crosslinking moiety, (II) subjecting the solid to an organic solvent to dissolve the compound into the organic solvent, wherein the organic solvent has a higher solubility which can dissolve the compound than that of water, and (III) collecting, separating or isolating the compound from the organic solvent.
Abstract:
An object of the invention is to provide a decomposing system for polyisocyanate residues that is capable of suppressing reaction of polyisocyanate residues with high temperature and high pressure water to allow smooth start-up of the operation, and a start-up method for the decomposing system for the polyisocyanate residues. The decomposing system is used for hydrolyzing the polyisocyanate residues to polyamine using high temperature and high pressure water, comprising a hydrolyzer, a water feed pipe connected to the hydrolyzer, a residual feed pipe connected to the water feed pipe, a solvent feed line for filling an organic solvent in a solvent filling portion of the residual feed pipe, and a solvent draining line. Upon start-up of the operation, the organic solvent is previously filled in the solvent filling portion via the solvent feed line and the solvent draining line, first, and then, the high temperature and high pressure water is fed from the water feed pipe to the hydrolyzer. Then, the organic solvent is fed from the residual feed pipe to the water feed pipe, first, and then, the polyisocyanate residues are fed thereto.
Abstract:
A method for treating vulcanized rubber, the method including the steps of (i) providing an aqueous stream that includes vulcanized rubber particles suspended in water, (ii) feeding the aqueous stream to the top of a hydraulic downdraft column, (iii) conducting the aqueous stream to the bottom of the hydraulic downdraft column, (iv) conducting the aqueous stream into an ultrasonic treatment zone, (v) subjecting the aqueous stream to ultrasonic energy and, (vi) conducting the aqueous stream up a hydraulic updraft column.
Abstract:
A method for treating vulcanized rubber, the method including the steps of (i) providing an aqueous stream that includes vulcanized rubber particles suspended in water, (ii) feeding the aqueous stream to the top of a hydraulic downdraft column, (iii) conducting the aqueous stream to the bottom of the hydraulic downdraft column, (iv) conducting the aqueous stream into an ultrasonic treatment zone, (v) subjecting the aqueous stream to ultrasonic energy and, (vi) conducting the aqueous stream up a hydraulic updraft column.
Abstract:
There are provided a bottle which has a laminate structure including a glycolic acid polymer layer showing good gas-barrier property in addition to a principal resin layer and is yet provided with excellent recyclability, and also an efficient method of recycling the bottle. More specifically, a bottle having a laminate structure including at least one layer of glycolic acid polymer in addition to a principal resin layer, is obtained. After breaking the bottle, the broken pieces are washed with alkaline water, water or acidic water to remove the glycolic acid polymer layer, thereby recovering the principal resin.
Abstract:
A structure material of the present invention consisting essentially of 20 parts by weight or more of a polymer mixture consisting essentially of of a thermoplastic aromatic polyester and a thermoplastic aliphatic polyester on the basis of 100 parts by weight of the structure material. The polymer mixture comprises 3 to 40 parts by weight of the aliphatic polyester on the basis of 100 parts by weight of the polymer mixture.
Abstract:
The proposed method of chemical recycling of polyethylene terephthalate waste to terephthalic acid and ethandiol is based on a continuous series of gradual steps, namely (a) separation of the polyethylene terephthalate component of the input material by its conversion to brittle form through crystallization, grinding and subsequent sifting, followed by (b) continuous two-stage hydrolysis of the polyethylene terephthalate, carried out in the first stage by feeding steam to the polymer melt, and in the second stage, by the reaction of the products of the first stage of hydrolysis with ammonium hydroxide, followed by (c) condensation of terephthalic acid from an aqueous solution of the second-stage hydrolysis products by inorganic acid, and its separation by means of filtration, and finally (d) rectification separation of ethandiol from a solution of the products of the second stage of hydrolysis, after the separation of terephthalic acid.