公开(公告)号：US20040029724A1

公开(公告)日：2004-02-12

申请号：US10380361

申请日：2003-03-13

Inventor： Yoshimasa Seo ,  Atsushi Sudo ,  Hideki Sugi

IPC: B01J027/14 ,  B01J027/188 ,  B01J027/19 ,  B01J027/198 ,  B01J027/199

CPC classification number: B01J23/002 ,  B01J27/199 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0223 ,  B01J37/0236 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/52 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/15 ,  B01J2523/3712 ,  B01J2523/53 ,  B01J2523/842 ,  B01J2523/32 ,  B01J2523/13 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/21 ,  B01J2523/43 ,  B01J2523/845 ,  B01J2523/14 ,  B01J2523/305 ,  B01J2523/42 ,  B01J2523/54

Abstract: The present invention relates to a catalyst for producing methacrylic acid by the vapor-phase catalytic oxidation of methacrolein, comprising Mo, V, P and Cu as the indispensable active components, wherein copper acetate is used for all or a part of the necessary amount of a material for said Cu, a coated catalyst and a method for manufacturing the coated catalyst, and methacrolein is reacted in a high conversion and methacrylic acid is produced in a high selectivity by use of the catalyst of the present invention, and the catalyst can be used for reaction under high loading condition.

Abstract translation: 本发明涉及通过甲基丙烯醛的气相催化氧化制备甲基丙烯酸的催化剂，其包含Mo，V，P和Cu作为不可缺少的活性组分，其中使用乙酸铜全部或部分所需量的 通过使用本发明的催化剂，以高选择性生产所述Cu的材料，涂覆的催化剂和制备涂覆的催化剂的方法和甲基丙烯醛以高转化率和甲基丙烯酸反应，催化剂可以 用于高负荷条件下的反应。

公开(公告)号：US20030036475A1

公开(公告)日：2003-02-20

申请号：US10169676

申请日：2002-07-01

Inventor： Kostantinos Kourtakis ,  Pratibha Gai

IPC: B01J027/186 ,  B01J027/198 ,  B01J027/19 ,  B01J027/18

CPC classification number: B01J23/002 ,  B01J27/198 ,  B01J27/199 ,  B01J35/0006 ,  B01J37/0009 ,  B01J2523/00 ,  C07C51/215 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/72 ,  B01J2523/48 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/47 ,  B01J2523/17 ,  B01J2523/847 ,  B01J2523/54 ,  B01J2523/842 ,  B01J2523/31 ,  B01J2523/43

Abstract: The present invention concern, a method for enhancing the activity of vanadium phosphorus oxide (VPO) catalysts. Promoter reagents are grafted onto or reacted with the catalyst surface. An optional calcination and activation heating cycle transforms the catalyst precursor into a final active phase. A preferred VPO catalyst produced has a ratio of molybdenum to vanadium on the surface of the catalyst to molybdenum to vanadium in the overall bulk of the catalyst represented by the equation (Mo/V) Surfacenull1.10 (Mo/V) overall bulk.

Abstract translation: 本发明涉及一种提高钒氧化物（VPO）催化剂活性的方法。 促进剂试剂接枝到催化剂表面上或与催化剂表面反应。 可选的煅烧和活化加热循环将催化剂前体转化为最终活性相。 所生产的优选的VPO催化剂在催化剂表面的钼与钒之间的比例（Mo / V）表面积= 1.10（Mo / V）的整体体积表示的催化剂总体积中的钼与钒的比例。

公开(公告)号：US20030032837A1

公开(公告)日：2003-02-13

申请号：US09889354

申请日：2001-07-17

Inventor： Etsuko Kadowaki ,  Tomoyoshi Higashi ,  Wataru Oguchi ,  Hiroshi Uchida

IPC: C07C069/02 ,  B01J027/19 ,  B01J027/198

CPC classification number: B01J35/002 ,  B01J21/08 ,  B01J27/188 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  C07C67/04 ,  C07C69/14

Abstract: A catalyst for use in producing a lower aliphatic carboxylic acid ester, wherein the catalyst is produced by a process comprising a step of contacting the catalyst with a gas containing at least one member selected from water, lower aliphatic carboxylic acids and lower aliphatic alcohols; a process for producing the catalyst; and a process for producing a lower aliphatic carboxylic acid ester using the catalyst. The catalyst can exhibit high initial activity and high space time yield, ensure sufficiently long catalyst life in practice in industry, and can prevent the production of by-product materials.

Abstract translation: 一种用于制备低级脂肪族羧酸酯的催化剂，其中催化剂通过包括使催化剂与含有选自水，低级脂族羧酸和低级脂族醇中的至少一种的气体接触的方法制备的方法制备; 催化剂的制造方法; 以及使用该催化剂制造低级脂肪族羧酸酯的方法。 该催化剂可以表现出高的初始活性和高的空时产率，确保了工业实践中足够长的催化剂寿命，并且可以防止副产物材料的生产。

公开(公告)号：US20020142913A1

公开(公告)日：2002-10-03

申请号：US09737989

申请日：2000-12-15

Applicant: Shell Oil Company

Inventor： Charles Lee Edwards

IPC: B01J027/198

CPC classification number: C07C41/03 ,  B01J27/1804 ,  C07C43/11

Abstract: Abstract of DisclosureA process to prepare an improved fluid rare earth phosphate catalyst composition useful in preparing alkylene oxide adducts of organic compounds having active hydrogen atoms is provided. The catalyst is prepared by dissolving a rare earth salt in a C9-C30 active hydrogen containing organic compound and then adding phosphoric acid to the organic compound rare earth mixture.

Abstract translation: 提供了一种制备用于制备具有活性氢原子的有机化合物的环氧烷加合物的改进的流体稀土磷酸盐催化剂组合物的方法。 通过将稀土盐溶解在含C9-C30活性氢的有机化合物中，然后向有机化合物稀土混合物中加入磷酸制备催化剂。