公开(公告)号：US20040030202A1

公开(公告)日：2004-02-12

申请号：US10636114

申请日：2003-08-07

Inventor： Sanjay Chaturvedi ,  Anne Mae Gaffney ,  Ruozhi Song ,  Elsie Mae Vickery

IPC: B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  B01J027/198 ,  B01J027/188 ,  B01J027/19 ,  B01J027/192 ,  B01J023/00 ,  C07C027/00

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J23/6525 ,  B01J23/686 ,  B01J27/0576 ,  B01J37/0238 ,  B01J2523/00 ,  C07C51/215 ,  C07C253/24 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

Abstract: A catalyst comprising a mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.

Abstract translation: 包含混合金属氧化物的催化剂可用于烷烃或烷烃和烯烃与不饱和羧酸的混合物的气相氧化，以及烷烃或烷烃和烯烃的混合物的气相氨氧化反应 不饱和腈。

公开(公告)号：US20040235648A1

公开(公告)日：2004-11-25

申请号：US10491964

申请日：2004-04-08

Inventor： Michael Bartsch ,  Robert Baumann ,  Dagmar Pascale Kunsmann-Keitel ,  Gerd Haderlein ,  Tim Jungkamp ,  Marco Atmayer ,  Wolfgang Siegel ,  Ferenc Molnar

IPC: C07F001/00 ,  C07H011/04 ,  B01J027/14 ,  B01J027/199

CPC classification number: C07F9/4875 ,  B01J31/1865 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07

Abstract: Phosphonites I of the formula 1 or 2 1 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.

Abstract translation: 式1或2的亚膦酸酯I其中R 1，R 2各自独立地为氢，具有1至8个碳原子的烷基或亚烷基或具有1至8个碳原子的烷氧基，条件是 R1和R2不同时为H，R3为H或甲基，R4为叔丁基，R5，R6，R7，R8，R9各自独立地为H或具有1至8个碳原子的烷基或亚烷基 原子

公开(公告)号：US20040029725A1

公开(公告)日：2004-02-12

申请号：US10636113

申请日：2003-08-07

Inventor： Anne Mae Gaffney ,  Michele Doreen Heffner ,  Ruozhi Song

IPC: B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  B01J027/198 ,  B01J027/188 ,  B01J027/19 ,  B01J027/192 ,  B01J023/00

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/10 ,  B01J23/22 ,  B01J23/28 ,  B01J27/0576 ,  B01J2523/00 ,  C07C51/215 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/3737 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  C07C255/08

Abstract: A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; calcining the recovered insoluble material in a non-oxidizing atmosphere; admixing the calcined recovered insoluble material with (i) at least one promoter element or compound thereof and (ii) at least one solvent for the at least one promoter element or compound thereof; removing the at least one solvent to form a catalyst precursor; and calcining the catalyst precursor.

Abstract translation: 可以是斜方相材料的混合金属氧化物作为用于从烷烃或烷烃和烯烃的混合物生产不饱和羧酸或不饱和亚硝酸盐的催化剂，通过以下方式改进：与选自 由有机酸，醇，无机酸和过氧化氢组成的组合形成接触混合物; 从接触混合物中回收不溶物质; 在非氧化性气氛中煅烧回收的不溶物; 将煅烧回收的不溶物与（i）至少一种助催化剂元件或其化合物和（ii）至少一种用于至少一种助催化剂元件或其化合物的溶剂混合; 除去所述至少一种溶剂以形成催化剂前体; 并煅烧催化剂前体。

公开(公告)号：US20040063575A1

公开(公告)日：2004-04-01

申请号：US10670222

申请日：2003-09-26

Applicant: Degussa AG

Inventor： Hemanus Gerhardus Jozef Lansink Rotgerink ,  Heike Reidemann ,  Helmfried Krause

IPC: B01J021/08 ,  B01J021/12 ,  B01J027/199 ,  B01J027/187 ,  B01J027/14 ,  B01J027/186 ,  B01J027/188 ,  B01J021/14

CPC classification number: B01J21/066 ,  B01J21/063 ,  B01J21/08 ,  B01J27/16 ,  B01J37/0009 ,  B01J37/0018

Abstract: A catalyst support consisting mainly of synthetic silica, with 0.5-10 parts by weight of one or more oxides or phosphates of the elements of group IIA, IIIB, IVB, VB, VIIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides characterised in that the support preparation method comprises mixing particulate synthetic silica with particulate oxides or phospates of the elements of Groups IIA, IIIB, IVB, VB, VIIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides, or with precursors thereof, a forming step and calcination. The catalyst support is used together with phosphoric acid in the production of alcohols from olefins by hydration.

Abstract translation: 主要由合成二氧化硅组成的催化剂载体，其具有0.5-10重量份的IIA，IIIB，IVB，VB，VIIB，VIIB，VIII，IB，IIB，VIIA，IVA族元素的一种或多种氧化物或磷酸盐，以及 镧系元素的特征在于载体制备方法包括将颗粒状合成二氧化硅与IIA，IIIB，IVB，VB，VIIB，VIIB，VIII，IB，IIB，VIIA，IVA族和镧系元素的元素的颗粒氧化物或磷酸盐混合，或 其前体，成型步骤和煅烧。 催化剂载体与磷酸一起用于通过水合由烯烃生产醇。

公开(公告)号：US20030100810A1

公开(公告)日：2003-05-29

申请号：US09997778

申请日：2001-11-29

Inventor： Machteld Mertens ,  Karl G. Strohmaier

IPC: B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  C07C002/00 ,  C07C005/00

CPC classification number: C01B37/08 ,  B01J29/85 ,  B01J35/023 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2400/20 ,  Y02P30/20 ,  Y10S423/30 ,  C07C11/02

Abstract: Small particle size silicoaluminophosphate molecular sieves are obtained by providing the source of the silicon in the form of a basic organic solution.

Abstract translation: 通过以碱性有机溶液的形式提供硅源，可以获得小粒径的硅铝磷酸盐分子筛。

公开(公告)号：US20040116760A1

公开(公告)日：2004-06-17

申请号：US10719972

申请日：2003-11-21

Inventor： Kostantinos Kourtakis ,  Leo Ernest Manzer

IPC: C07C005/333 ,  B01J027/22 ,  B01J027/24 ,  B01J027/14 ,  B01J027/186 ,  C07C005/367 ,  B01J027/187 ,  B01J027/199 ,  B01J027/02

CPC classification number: C07C5/325 ,  B01J21/04 ,  B01J23/26 ,  B01J23/6522 ,  B01J37/0209 ,  B01J37/0211 ,  B01J37/0215 ,  B01J37/036 ,  B01J38/12 ,  C07C5/324 ,  C07C5/327 ,  C07C2521/04 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/52 ,  Y02P20/584 ,  C07C11/09

Abstract: A gel composition substantially contained within the pores of a solid material is disclosed for use as a catalyst or as a catalyst support in dehydrogenation and dehydrocyclization processes.

Abstract translation: 公开了基本上包含在固体材料的孔内的凝胶组合物用作催化剂或用作脱氢和脱氢环化方法中的催化剂载体。

公开(公告)号：US20040052726A1

公开(公告)日：2004-03-18

申请号：US10461258

申请日：2003-06-12

Inventor： Mark E. Davis ,  Hyunjoo Lee ,  Stacey I. Zones

IPC: C01B015/16 ,  C01B025/26 ,  C01F007/00 ,  C01B033/36 ,  C01B039/00 ,  B01J029/04 ,  B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  B01J027/182

CPC classification number: C01B37/00 ,  C01B37/02 ,  C01B37/04 ,  C01B37/08 ,  C01B39/04 ,  C01B39/12 ,  Y10S423/22 ,  Y10S423/30 ,  Y10S423/36

Abstract: A structure directing agent is removed from a microporous solid at a temperature below the temperature that would cause the structure directing agent to decompose by cleaving the structure directing agent within the pores of the microporous solid, at a temperature below the temperature that would cause the structure directing agent to decompose, into two or more fragments and removing the fragments from the pores of the microporous solid at a temperature below the temperature that would cause the structure directing agent or its fragments to decompose.

公开(公告)号：US20030176753A1

公开(公告)日：2003-09-18

申请号：US10364870

申请日：2003-02-10

Inventor： Doron Levin ,  James Clark Vartuli

IPC: B01J027/199 ,  C07C001/00

CPC classification number: C10G50/02 ,  B01J21/06 ,  B01J21/10 ,  B01J23/02 ,  B01J23/10 ,  B01J29/85 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/10 ,  B01J37/0009 ,  B01J2229/42 ,  C07C1/20 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/08 ,  C07C2529/00 ,  C07C2529/83 ,  C07C2529/85 ,  C10G3/49 ,  C10G11/05 ,  C10G35/095 ,  C10G45/54 ,  C10G45/64 ,  C10G47/20 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1022 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

Abstract: The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one oxide of a metal selected from Group 3 of the Periodic Table of Elements, the Lanthanide series of elements and the Actinide series of elements.

Abstract translation: 本发明涉及一种催化剂组合物，其制备方法及其在将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子 筛选和选自元素周期表第3族的金属的至少一种氧化物，元素的镧系元素和锕系元素系列。

公开(公告)号：US20040181085A1

公开(公告)日：2004-09-16

申请号：US10808861

申请日：2004-03-24

Inventor： Leonard Edward Bogan JR. ,  Anne Mae Gaffney ,  Scott Han ,  Michele Doreen Heffner ,  Ruozhi Song

IPC: B01J023/00 ,  B01J027/132 ,  B01J027/14 ,  B01J027/186 ,  B01J027/199 ,  B01J027/06 ,  C07C253/26

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J27/0576 ,  B01J37/0236 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  C07C255/08

Abstract: A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contacting member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; and calcining the recovered insoluble material in a non-oxidizing atmosphere.

Abstract translation: 作为斜方相材料的混合金属氧化物作为用于从烷烃或烷烃和烯烃的混合物生产不饱和羧酸或不饱和亚硝酸盐的催化剂，通过以下方式改进：与选自 由有机酸，醇，无机酸和过氧化氢组成的组合形成接触混合物; 从接触混合物中回收不溶物质; 并将回收的不溶物质煅烧在非氧化性气氛中。

公开(公告)号：US20040063990A1

公开(公告)日：2004-04-01

申请号：US10676884

申请日：2003-09-30

Inventor： Anne Mae Gaffney ,  Ruozhi Song

IPC: B01J027/128 ,  B01J027/132 ,  B01J027/135 ,  B01J027/06 ,  B01J027/13 ,  B01J027/125 ,  B01J027/192 ,  B01J027/19 ,  B01J027/188 ,  B01J027/198 ,  B01J027/199 ,  B01J027/187 ,  B01J027/186 ,  B01J027/14

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/14 ,  B01J23/20 ,  B01J23/24 ,  B01J23/28 ,  B01J23/34 ,  B01J23/64 ,  B01J23/6525 ,  B01J23/8877 ,  B01J27/0576 ,  B01J27/132 ,  B01J35/002 ,  B01J37/06 ,  B01J37/10 ,  B01J37/22 ,  B01J2523/00 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/67 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/845 ,  B01J2523/822 ,  B01J2523/842 ,  B01J2523/22 ,  B01J2523/33 ,  B01J2523/3737 ,  B01J2523/828 ,  B01J2523/824 ,  B01J2523/70 ,  B01J2523/72 ,  B01J2523/27 ,  B01J2523/11 ,  B01J2523/23 ,  B01J2523/847 ,  C07C255/08

Abstract: Hydrothermally synthesized catalysts comprising a mixed metal oxide are utilized to produce unsaturated carboxylic acids by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, in the presence thereof; or to produce unsaturated nitrites by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, and ammonia in the presence thereof.

Abstract translation: 包含混合金属氧化物的水热合成催化剂用于在存在下通过烷烃或烷烃和烯烃的混合物的气相氧化制备不饱和羧酸; 或通过烷烃或烷烃和烯烃的混合物以及氨的气相氧化产生不饱和腈。