公开(公告)号：US20040054222A1

公开(公告)日：2004-03-18

申请号：US10466244

申请日：2003-07-15

Inventor： Raimund Felder ,  Signe Unverricht ,  Heiko Arnold ,  Jochen Petzoldt

IPC: B01J023/31 ,  B01J027/14 ,  B01J027/186 ,  B01J027/188 ,  B01J027/19 ,  B01J027/192 ,  C07C051/16

CPC classification number: C07C51/235 ,  B01J19/30 ,  B01J23/28 ,  B01J23/31 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/002 ,  B01J35/026 ,  B01J2219/30223 ,  B01J2219/30242 ,  B01J2219/30475 ,  C07C45/35 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04

Abstract: The invention relates to a method for the heterogenically catalysed gas-phase partial oxidation of precursor compounds of (meth)acrylic acid in a fixed catalyst bed, containing as the catalyst an activated mass of mixed oxide, shaped to form a geometric body. Said geometric body is a geometric base body, into whose surface a cavity is incorporated.

Abstract translation: 本发明涉及在固定催化剂床中异构催化气相部分氧化（甲基）丙烯酸的前体化合物的方法，该方法含有形成几何体的成形为混合氧化物的活化物质作为催化剂。 所述几何体是几何基体，其表面中并入有空腔。

公开(公告)号：US20040030202A1

公开(公告)日：2004-02-12

申请号：US10636114

申请日：2003-08-07

Inventor： Sanjay Chaturvedi ,  Anne Mae Gaffney ,  Ruozhi Song ,  Elsie Mae Vickery

IPC: B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  B01J027/198 ,  B01J027/188 ,  B01J027/19 ,  B01J027/192 ,  B01J023/00 ,  C07C027/00

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J23/6525 ,  B01J23/686 ,  B01J27/0576 ,  B01J37/0238 ,  B01J2523/00 ,  C07C51/215 ,  C07C253/24 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

Abstract: A catalyst comprising a mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.

Abstract translation: 包含混合金属氧化物的催化剂可用于烷烃或烷烃和烯烃与不饱和羧酸的混合物的气相氧化，以及烷烃或烷烃和烯烃的混合物的气相氨氧化反应 不饱和腈。

公开(公告)号：US20040116760A1

公开(公告)日：2004-06-17

申请号：US10719972

申请日：2003-11-21

Inventor： Kostantinos Kourtakis ,  Leo Ernest Manzer

IPC: C07C005/333 ,  B01J027/22 ,  B01J027/24 ,  B01J027/14 ,  B01J027/186 ,  C07C005/367 ,  B01J027/187 ,  B01J027/199 ,  B01J027/02

CPC classification number: C07C5/325 ,  B01J21/04 ,  B01J23/26 ,  B01J23/6522 ,  B01J37/0209 ,  B01J37/0211 ,  B01J37/0215 ,  B01J37/036 ,  B01J38/12 ,  C07C5/324 ,  C07C5/327 ,  C07C2521/04 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/52 ,  Y02P20/584 ,  C07C11/09

Abstract: A gel composition substantially contained within the pores of a solid material is disclosed for use as a catalyst or as a catalyst support in dehydrogenation and dehydrocyclization processes.

Abstract translation: 公开了基本上包含在固体材料的孔内的凝胶组合物用作催化剂或用作脱氢和脱氢环化方法中的催化剂载体。

公开(公告)号：US20040052726A1

公开(公告)日：2004-03-18

申请号：US10461258

申请日：2003-06-12

Inventor： Mark E. Davis ,  Hyunjoo Lee ,  Stacey I. Zones

IPC: C01B015/16 ,  C01B025/26 ,  C01F007/00 ,  C01B033/36 ,  C01B039/00 ,  B01J029/04 ,  B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  B01J027/182

CPC classification number: C01B37/00 ,  C01B37/02 ,  C01B37/04 ,  C01B37/08 ,  C01B39/04 ,  C01B39/12 ,  Y10S423/22 ,  Y10S423/30 ,  Y10S423/36

Abstract: A structure directing agent is removed from a microporous solid at a temperature below the temperature that would cause the structure directing agent to decompose by cleaving the structure directing agent within the pores of the microporous solid, at a temperature below the temperature that would cause the structure directing agent to decompose, into two or more fragments and removing the fragments from the pores of the microporous solid at a temperature below the temperature that would cause the structure directing agent or its fragments to decompose.

公开(公告)号：US20030069131A1

公开(公告)日：2003-04-10

申请号：US10214376

申请日：2002-08-07

Inventor： Jackie Y. Ying ,  Jinsuo Xu

IPC: B01J023/24 ,  B01J023/28 ,  B01J023/30 ,  B01J023/40 ,  B01J023/42 ,  B01J023/44 ,  B01J023/46 ,  B01J027/02 ,  B01J027/045 ,  B01J027/047 ,  B01J027/049 ,  B01J027/051 ,  B01J027/14 ,  B01J027/185 ,  B01J027/186 ,  B01J027/188 ,  B01J027/19

CPC classification number: C10G35/085 ,  B01J21/02 ,  B01J21/04 ,  B01J21/06 ,  B01J21/066 ,  B01J23/002 ,  B01J23/54 ,  B01J23/58 ,  B01J23/62 ,  B01J23/6522 ,  B01J23/6527 ,  B01J23/89 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/03 ,  B01J2523/00 ,  C07C5/226 ,  C07C5/2791 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/652 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/86 ,  C10G35/06 ,  C10G2400/02 ,  B01J2523/31 ,  B01J2523/48

Abstract: One aspect of the present invention relates to a catalytic compound of anion-modified metal oxides doped with metal ions. Another aspect of the present invention relates to a method of isomerizing an alkane or alkyl moiety.

Abstract translation: 本发明的一个方面涉及掺杂有金属离子的阴离子改性金属氧化物的催化剂化合物。 本发明的另一方面涉及使烷烃或烷基部分异构化的方法。

公开(公告)号：US20040186013A1

公开(公告)日：2004-09-23

申请号：US10482041

申请日：2003-12-29

Inventor： Yoshiki Iwata ,  Chikanori Nakaoka ,  Yasuhito Goto

IPC: B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/19

CPC classification number: B01J35/002 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0203 ,  C10G45/08

Abstract: A method for producing a hydrorefining catalyst has the steps of preparing an impregnation solution containing molybdenum, phosphorus, cobalt and/or nickel, and citric acid, bringing a carrier into contact with the impregnation solution, and then calcinating the carrier in an oxidizing atmosphere at a temperature at which citric acid is removed. In the impregnation solution, a molar ratio of molybdenum/phosphorus is 6 to 13, a molar ratio of (cobalt and nickel)/phosphorus is 0.5 to 7, and a molar ratio of (cobalt and nickel)/citric acid is 0.5 to 2. As for the hydrorefining catalyst obtained by this method, the activity of the catalyst is high, and the catalyst life is long.

Abstract translation: 一种加氢精制催化剂的制造方法，其特征在于，制备含有钼，磷，钴和/或镍的浸渍溶液和柠檬酸，使载体与浸渍溶液接触，然后在氧化气氛中煅烧载体 去除柠檬酸的温度。 在浸渍溶液中，钼/磷的摩尔比为6〜13，（钴和镍）/磷的摩尔比为0.5〜7，（钴和镍）/柠檬酸的摩尔比为0.5〜2 对于通过该方法获得的加氢精制催化剂，催化剂的活性高，催化剂寿命长。

公开(公告)号：US20040181085A1

公开(公告)日：2004-09-16

申请号：US10808861

申请日：2004-03-24

Inventor： Leonard Edward Bogan JR. ,  Anne Mae Gaffney ,  Scott Han ,  Michele Doreen Heffner ,  Ruozhi Song

IPC: B01J023/00 ,  B01J027/132 ,  B01J027/14 ,  B01J027/186 ,  B01J027/199 ,  B01J027/06 ,  C07C253/26

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J27/0576 ,  B01J37/0236 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  C07C255/08

Abstract: A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contacting member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; and calcining the recovered insoluble material in a non-oxidizing atmosphere.

Abstract translation: 作为斜方相材料的混合金属氧化物作为用于从烷烃或烷烃和烯烃的混合物生产不饱和羧酸或不饱和亚硝酸盐的催化剂，通过以下方式改进：与选自 由有机酸，醇，无机酸和过氧化氢组成的组合形成接触混合物; 从接触混合物中回收不溶物质; 并将回收的不溶物质煅烧在非氧化性气氛中。

公开(公告)号：US20040063990A1

公开(公告)日：2004-04-01

申请号：US10676884

申请日：2003-09-30

Inventor： Anne Mae Gaffney ,  Ruozhi Song

IPC: B01J027/128 ,  B01J027/132 ,  B01J027/135 ,  B01J027/06 ,  B01J027/13 ,  B01J027/125 ,  B01J027/192 ,  B01J027/19 ,  B01J027/188 ,  B01J027/198 ,  B01J027/199 ,  B01J027/187 ,  B01J027/186 ,  B01J027/14

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/14 ,  B01J23/20 ,  B01J23/24 ,  B01J23/28 ,  B01J23/34 ,  B01J23/64 ,  B01J23/6525 ,  B01J23/8877 ,  B01J27/0576 ,  B01J27/132 ,  B01J35/002 ,  B01J37/06 ,  B01J37/10 ,  B01J37/22 ,  B01J2523/00 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/67 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/845 ,  B01J2523/822 ,  B01J2523/842 ,  B01J2523/22 ,  B01J2523/33 ,  B01J2523/3737 ,  B01J2523/828 ,  B01J2523/824 ,  B01J2523/70 ,  B01J2523/72 ,  B01J2523/27 ,  B01J2523/11 ,  B01J2523/23 ,  B01J2523/847 ,  C07C255/08

Abstract: Hydrothermally synthesized catalysts comprising a mixed metal oxide are utilized to produce unsaturated carboxylic acids by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, in the presence thereof; or to produce unsaturated nitrites by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, and ammonia in the presence thereof.

Abstract translation: 包含混合金属氧化物的水热合成催化剂用于在存在下通过烷烃或烷烃和烯烃的混合物的气相氧化制备不饱和羧酸; 或通过烷烃或烷烃和烯烃的混合物以及氨的气相氧化产生不饱和腈。

公开(公告)号：US20030036475A1

公开(公告)日：2003-02-20

申请号：US10169676

申请日：2002-07-01

Inventor： Kostantinos Kourtakis ,  Pratibha Gai

IPC: B01J027/186 ,  B01J027/198 ,  B01J027/19 ,  B01J027/18

CPC classification number: B01J23/002 ,  B01J27/198 ,  B01J27/199 ,  B01J35/0006 ,  B01J37/0009 ,  B01J2523/00 ,  C07C51/215 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/72 ,  B01J2523/48 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/47 ,  B01J2523/17 ,  B01J2523/847 ,  B01J2523/54 ,  B01J2523/842 ,  B01J2523/31 ,  B01J2523/43

Abstract: The present invention concern, a method for enhancing the activity of vanadium phosphorus oxide (VPO) catalysts. Promoter reagents are grafted onto or reacted with the catalyst surface. An optional calcination and activation heating cycle transforms the catalyst precursor into a final active phase. A preferred VPO catalyst produced has a ratio of molybdenum to vanadium on the surface of the catalyst to molybdenum to vanadium in the overall bulk of the catalyst represented by the equation (Mo/V) Surfacenull1.10 (Mo/V) overall bulk.

Abstract translation: 本发明涉及一种提高钒氧化物（VPO）催化剂活性的方法。 促进剂试剂接枝到催化剂表面上或与催化剂表面反应。 可选的煅烧和活化加热循环将催化剂前体转化为最终活性相。 所生产的优选的VPO催化剂在催化剂表面的钼与钒之间的比例（Mo / V）表面积= 1.10（Mo / V）的整体体积表示的催化剂总体积中的钼与钒的比例。

公开(公告)号：US20040235649A1

公开(公告)日：2004-11-25

申请号：US10442586

申请日：2003-05-21

Inventor： Yun-Feng Chang ,  Stephen N. Vaughn ,  Luc R.M. Martens ,  Kenneth R. Clem

IPC: B01J027/186

CPC classification number: B01J37/0045 ,  B01J29/06 ,  B01J29/85 ,  C07C1/20 ,  C07C2529/83 ,  C07C2529/85 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

Abstract: This invention is directed to a hardened molecular sieve catalyst composition, a method of making the composition and a method of using the composition. The catalyst composition is made by mixing together molecular sieve, liquid, and an effective hardening amount of a dried molecular sieve catalyst to form a slurry. The slurry is dried, and then calcined to form the hardened molecular sieve catalyst composition. The hardened molecular sieve catalyst is highly attrition resistant.

Abstract translation: 本发明涉及硬化分子筛催化剂组合物，制备组合物的方法和使用该组合物的方法。 催化剂组合物通过将分子筛，液体和有效硬化量的干燥的分子筛催化剂混合在一起而形成浆料而制成。 将浆料干燥，然后煅烧以形成硬化的分子筛催化剂组合物。 硬化分子筛催化剂具有高耐磨性。