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    Polyolefin catalysts
    15.
    发明授权
    Polyolefin catalysts 失效
    聚烯烃催化剂

    公开(公告)号：US06365539B1

    公开(公告)日：2002-04-02

    申请号：US09576620

    申请日：2000-05-23

    Applicant: James Allen Ponasik, Jr. ,  Peter Borden Mackenzie ,  Christopher Moore Killian

    Inventor： James Allen Ponasik, Jr. ,  Peter Borden Mackenzie ,  Christopher Moore Killian

    IPC: B01J3118

    CPC classification number: C08F110/02 ,  C08F10/00 ,  C08F4/025 ,  C08F2500/03 ,  C08F2500/10 ,  C08F4/7006

    Abstract: This invention is directed to novel Group 8-10 transition metal catalysts and to batch or continuous polymerizations using these catalysts. The catalysts of the present invention readily convert ethylene and &agr;-olefins to high molecular weight polymers, and allow for olefin polymerizations under various conditions, including ambient temperature and pressure, and in solution. Preferred catalysts are group 8-10 transition metals having certain dipyridyl ligands bonded thereto.

    Abstract translation: 本发明涉及新型的第8-10族过渡金属催化剂和使用这些催化剂的间歇或连续聚合。 本发明的催化剂容易将乙烯和α-烯烃转化为高分子量聚合物，并允许在各种条件下进行烯烃聚合，包括环境温度和压力，以及在溶液中。 优选的催化剂是具有与其键合的某些二吡啶基配体的8-10族过渡金属。

    Catalysts for olefin polymerization
    16.
    发明授权
    Catalysts for olefin polymerization 失效
    用于烯烃聚合的催化剂

    公开(公告)号：US06333292B1

    公开(公告)日：2001-12-25

    申请号：US09301074

    申请日：1999-04-28

    Applicant: Vernon Charles Gibson ,  Brian Stephen Kimberley

    Inventor： Vernon Charles Gibson ,  Brian Stephen Kimberley

    IPC: B01J3118

    CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F2410/03 ,  C08F4/64075 ,  C08F4/64013

    Abstract: Novel compounds are disclosed comprising the skeletal unit depicted in Formula (I) wherein O is oxygen; N is nitrogen; R1 is hydrogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; R3, R4, R5 and R6 are hydrogen or hydrocarbyl or heterohydrocarbyl groups containing 1 to 10 carbon atoms and the R12 groups are independently selected from hydrogen, hydrocarbyl, substituted hydrocarbyl, heterocarbyl and substituted heterocarbyl; A is carbon or silicon; and r is 1 or more; M is scandium, yttrium, or a Group IV or Group V metal or a lanthanide or actinide; T is the oxidation state of M and is II or greater; X represents a monodentate atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, and n is from 0 to 5.

    Abstract translation: 公开了包含式（I）中所示的骨架单元的新型化合物，其中O是氧; N是氮; R 1是氢，烃基，取代的烃基，杂烃基或取代的杂烃基; R 3，R 4，R 5和R 6是氢或含有1至10个碳原子的烃基或杂烃基，R 12基团独立地选自氢，烃基，取代的烃基，杂碳原子和取代的杂碳原子; A是碳或硅; r为1以上; M是钪，钇或IV族或Ⅴ族金属或镧系元素或锕系元素; T为M的氧化态，为II以上; X表示与M共价或离子键合的单齿原子或基团; L是与M直接结合的单齿或双齿分子，n为0至5。

    Supported dual transition metal catalyst systems
    17.
    发明授权
    Supported dual transition metal catalyst systems 失效
    支持双过渡金属催化剂体系

    公开(公告)号：US06686306B2

    公开(公告)日：2004-02-03

    申请号：US10120317

    申请日：2002-04-10

    Applicant: Keng-Yu Shih

    Inventor： Keng-Yu Shih

    IPC: B01J3118

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08F4/61904 ,  C08F4/61916 ,  C08F4/025 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/04 ,  C08F210/14 ,  C08F4/7042

    Abstract: A coordination catalyst system comprising at least one metallocene or constrained geometry pre-catalyst transition metal compound, (e.g., rac-ethylene bis(indenyl)zirconium dichloride), at least one non-metallocene, non-constrained geometry, bidentate transition metal compound or tridentate transition metal compound (e.g., tridentate 2,6-diacetylpyridine-bis(2,4,6-trimethylanaline)FeCl2), at least one support-activator (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound (e.g., triisobutyl aluminum), in controlled amounts, and methods for preparing the same. The resulting dual transition metal catalyst system is suitable for addition polymerization of ethylenically and acetylenically unsaturated monomers into polymers; for example, polymers having a broad molecular weight distribution, Mw/Mn, and good polymer morphology.

    Abstract translation: 包含至少一种金属茂或约束几何预催化剂过渡金属化合物（例如外消旋 - 亚乙基双（茚基）二氯化锆）的配位催化剂体系，至少一种非茂金属，非约束几何形状，二齿过渡金属化合物或 三齿过渡金属化合物（例如三齿2,6-二乙酰基吡啶 - 双（2,4,6-三甲基苯胺）FeCl 2），至少一种载体活化剂（例如喷雾干燥二氧化硅/粘土附聚物）和任选的至少一种有机金属 化合物（例如，三异丁基铝），以及其制备方法。 所得的双过渡金属催化剂体系适用于将烯属和炔属不饱和单体加成聚合成聚合物; 例如，具有宽分子量分布，Mw / Mn和良好的聚合物形态的聚合物。

    Olefin polymerization catalyst
    18.
    发明授权
    Olefin polymerization catalyst 有权
    烯烃聚合催化剂

    公开(公告)号：US06489263B2

    公开(公告)日：2002-12-03

    申请号：US09843594

    申请日：2001-04-26

    Applicant: Rex E. Murray ,  Simon Mawson ,  Clark C. Williams ,  D. James Schreck

    Inventor： Rex E. Murray ,  Simon Mawson ,  Clark C. Williams ,  D. James Schreck

    IPC: B01J3118

    CPC classification number: C08F210/16 ,  C07F7/00 ,  C07F7/10 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/659 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/10 ,  C08F4/64044

    Abstract: This invention relates to an olefin polymerization catalyst composition comprising the product of the combination of at least one activator and at least two different transition metal compounds each of which is represented by the formula: ((Z)XAt(YJ))qMQn  (I) where M is a metal selected from Group 3 to 13 or lanthanide and actinide series of the Periodic Table of Elements; Q is bonded to M and each Q is a monovalent, divalent or trivalent anion; X and Y are bonded to M; X and Y are independently C or a heteroatom, provided that at least one of X and Y is a heteroatom and Y is contained in a heterocyclic ring J, where J comprises from 2 to 50 non-hydrogen atoms; Z is bonded to X, where Z comprises 1 to 50 non-hydrogen atoms; t is 0 or 1; when t is 1, A is a bridging group joined to at least one of X, Y or J; q is 1 or 2; n is the oxidation state of M minus q if Q is a monovalent anion, n is (the oxidation state of M−q)/2, if Q is a bivalent anion or n is (the oxidation state of M−q)/3 if Q is a trivalent anion.

    Abstract translation: 本发明涉及一种烯烃聚合催化剂组合物，其包含至少一种活化剂和至少两种不同的过渡金属化合物的组合的产物，每种催化剂由下式表示：其中M是选自第3至13族的金属或镧系元素 和元素周期表的锕系列; Q键合到M，每个Q是一价，二价或三价阴离子; X和Y与M键合; X和Y独立地为C或杂原子，条件是X和Y中的至少一个是杂原子，Y包含在杂环J中，其中J包含2至50个非氢原子; Z键合到X，其中Z包含1至50个非氢原子; t为0或1; 当t为1时，A为与X，Y或J中的至少一个连接的桥连基团; q为1或2; 如果Q是二价阴离子，则n是M的氧化态，如果Q是一价阴离子，则n是（Mq的氧化态）/ 2，如果Q是二价阴离子，则n是（Mq的氧化态）/ 3 三价阴离子。

    Late transition metal complexes, their use as catalysts and polymers therefrom
    19.
    发明授权
    Late transition metal complexes, their use as catalysts and polymers therefrom 失效
    后期过渡金属络合物，它们用作催化剂和聚合物

    公开(公告)号：US06479425B1

    公开(公告)日：2002-11-12

    申请号：US09642488

    申请日：2000-08-18

    Applicant: Robert T. Stibrany ,  Smita Kacker

    Inventor： Robert T. Stibrany ,  Smita Kacker

    IPC: B01J3118

    CPC classification number: C08F10/00 ,  B01J23/72 ,  B01J31/143 ,  B01J31/1805 ,  B01J31/1825 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  C07F1/005 ,  C07F1/08 ,  C08F10/02 ,  C08F110/02 ,  C08F210/02 ,  C08F220/10 ,  C08F4/54 ,  C08F4/44 ,  C08F4/50 ,  C08F220/12

    Abstract: The invention provides a novel metal complex which, when used with an activating cocatalyst, provides a novel catalyst composition. The invention also provides a polymerization method which utilizes the catalyst composition to produce polymers and copolymers containing polar monomer groups. More specifically, the invention comprises a composition comprising the formula LMXZn wherein X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert. M is selected from the group consisting of Cu, Ag, and Au. L is a nitrogen-containing bidentate ligand having more than two nitrogen atoms. Z is a neutral coordinating ligand and n equals 0, 1, or 2.

    Abstract translation: 本发明提供了一种新型金属络合物，当与活化助催化剂一起使用时，提供了新的催化剂组合物。 本发明还提供一种利用催化剂组合物制备含有极性单体基团的聚合物和共聚物的聚合方法。 更具体地说，本发明包括一种包含式LMXZn的组合物，其中X选自卤化物，氢化物，三氟甲磺酸酯，乙酸酯，硼酸酯，C 1至C 12烷基，C 1至C 12烷氧基，C 3至C 12环烷基，C 3至C 12环烷氧基 ，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和单体可以插入的任何其它部分。 M选自Cu，Ag和Au。 L是具有两个以上氮原子的含氮二齿配位体。 Z是中性配位配体，n等于0,1或2。

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