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11.发明授权Methods of synthesis of isotropically enriched borohydride and methods of synthesis of isotropically enriched boranes 有权各向同性富硼硼氢化合物的合成方法和各向同性富集的硼烷的合成方法公开(公告)号：US08084007B2
公开(公告)日：2011-12-27
申请号：US12650730
申请日：2009-12-31
申请人： Bernard Spielvogel , Kevin S. Cook
发明人： Bernard Spielvogel , Kevin S. Cook
摘要： The invention provides new methods for the synthesis of isotopically enriched metal borohydrides, metal tetrahydroundecaborate salts, and decaborane from isotopically enriched 10B-boric acid or 11B-boric acid. The invention is particularly useful for synthesis of isotopically enriched sodium or lithium borohydride, MB11H14 (where M is Li, Na, K, or alkylammonium), and decaborane.
摘要翻译： 本发明提供了从同位素富集的10B-硼酸或11B-硼酸合成同位素富集的金属硼氢化物，四氢十八硼酸盐金属和十硼烷的新方法。 本发明特别可用于合成同位素富集的硼氢化钠或硼氢化钠MB11H14（其中M为Li，Na，K或烷基铵）和十硼烷。
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12.发明授权Methods of synthesis of isotopically enriched borohydride and methods of synthesis of isotopically enriched boranes 失效同位素富集的硼氢化合物的合成方法和同位素富集的硼烷的合成方法公开(公告)号：US07641879B2
公开(公告)日：2010-01-05
申请号：US11047165
申请日：2005-01-28
申请人： Bernard Spielvogel , Kevin Cook
发明人： Bernard Spielvogel , Kevin Cook
摘要： The invention provides new methods for the synthesis of isotopically enriched metal borohydrides, metal tetrahydroundecaborate salts, and decaborane from isotopically enriched 10B-boric acid or 11B-boric acid. The invention is particularly useful for synthesis of isotopically enriched sodium or lithium borohydride, MB11H14 (where M is Li, Na, K, or alkylammonium), and decaborane.
摘要翻译： 本发明提供了从同位素富集的10B-硼酸或11B-硼酸合成同位素富集的金属硼氢化物，四氢十八硼酸盐金属和十硼烷的新方法。 本发明特别可用于合成同位素富集的硼氢化钠或硼氢化钠MB11H14（其中M为Li，Na，K或烷基铵）和十硼烷。
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公开(公告)号：US20080193356A1
公开(公告)日：2008-08-14
申请号：US11674186
申请日：2007-02-13
申请人： Gert Wolf , Felix Baitalow , Gerhard Roewer , Steffen Hausdorf , Gerd Arnold , Ulrich Eberle , Dieter Hasenauer , Florian O. Mertens
发明人： Gert Wolf , Felix Baitalow , Gerhard Roewer , Steffen Hausdorf , Gerd Arnold , Ulrich Eberle , Dieter Hasenauer , Florian O. Mertens
CPC分类号： C01B35/146 , Y10S502/526
摘要： A process for producing borazane from boron-nitrogen and boron-nitrogen-hydrogen containing BNH-waste products. The process includes reacting the BNH-waste products with a hydrogen halide, having the formula HX, wherein X is selected from the group consisting of F, Cl, Br, I, and combinations thereof, to form any of the following: a boron trihalide, having the formula BX3, an ammonium halide, having the formula NH4X, and hydrogen. The boron trihalide is then reacted with the hydrogen to form diborane, having the formula B2H6, and hydrogen halide. The ammonium halide is then converted to ammonia, having the formula NH3, and hydrogen halide. The diborane is then reacted with the ammonia to form borazane, having the formula BH3NH3.
摘要翻译： 一种从硼氮制备硼氮烷和含有BNH废物的含硼氮氢的方法。 该方法包括使BNH废物与具有式HX的卤化氢反应，其中X选自F，Cl，Br，I及其组合，形成以下任何一种：三卤化硼 具有式BX 3 N，具有式NH 4 X的卤化铵和氢。 然后将三卤化硼与氢反应形成具有式B 2 H 6 H 6的二硼烷，以及卤化氢。 然后将卤化铵转化成具有式NH 3的氨和卤化氢。 然后将乙硼烷与氨反应形成具有式BH 3 NH 3的硼氮烷。
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公开(公告)号：US20070286787A1
公开(公告)日：2007-12-13
申请号：US11807524
申请日：2007-05-29
IPC分类号： C01B6/15
CPC分类号： C01B3/065 , C01B6/04 , C01B6/21 , Y02E60/324 , Y02E60/362
摘要： A process is described for the preparation of magnesium borohydride having a high purity and crystallinity, which comprises the reaction of an orgenometallic compound of magnesium of the type MgX2, wherein X is an organic binder selected from alkyl, amide, alkoxide, cyclopentadienyl, aryl, with a derivative of a boron hydride, in a hydrocarbon solvent.
摘要翻译： 描述了一种制备具有高纯度和结晶度的硼氢化镁的方法，其包括MgX 2类型的镁的金属间化合物的反应，其中X是选自烷基的有机粘合剂， 酰胺，醇盐，环戊二烯基，芳基与硼氢化物的衍生物在烃溶剂中反应。
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公开(公告)号：US20070269360A1
公开(公告)日：2007-11-22
申请号：US11801056
申请日：2007-05-08
IPC分类号： C01B6/15
CPC分类号： C01B6/21
摘要： A method for preparing a metal borohydride salt, M(BH4)n, where n is 1 or 2, from a slurry of sodium borohydride and a sodium alkoxide in a liquid hydrocarbon, wherein M is Li, K, Rb, Cs, Mg, Ca, Sr or Ba.
摘要翻译： 从硼氢化钠和醇钠溶液在液体中制备金属硼氢化物盐的方法，其中n为1或2，M（BH 4）n N 烃，其中M为Li，K，Rb，Cs，Mg，Ca，Sr或Ba。
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公开(公告)号：US20100178228A1
公开(公告)日：2010-07-15
申请号：US12653716
申请日：2009-12-16
申请人： Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
发明人： Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
CPC分类号： C01B6/21
摘要： A method for preparing M2B12H12, wherein M is an alkali metal, from an alkali metal borohydride and an amine borane. The method includes a step of allowing the alkali metal borohydride to react with excess amine borane in contact with a complexing agent.
摘要翻译： 从碱金属硼氢化物和胺硼烷制备M2B12H12（其中M为碱金属）的方法。 该方法包括使碱金属硼氢化物与与络合剂接触的过量胺硼烷反应的步骤。
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17.发明申请COMPOSITIONS COMPRISING MAGNESIUM BOROHYDRIDE AND MAGNESIUM HYDRIDOBOROHYDRIDE AND METHOD FOR MANUFACTURING THE SAME 审中-公开包含镁硼氢化镁和氢氧化镁水溶液的组合物及其制造方法公开(公告)号：US20070297964A1
公开(公告)日：2007-12-27
申请号：US11425603
申请日：2006-06-21
IPC分类号： C01B6/15
CPC分类号： C01B6/21 , C01B3/04 , Y02E60/364
摘要： Disclosed herein is a method comprising reacting a metal borohydride with a metal chloride composition in a solvent to form a reaction mixture, wherein the metal chloride composition comprises magnesium chloride; wherein the metal borohydride and the metal chloride composition are insoluble in the solvent; grinding the reaction mixture to produce a composition that comprises magnesium hydridoborohydride; and removing the solvent from the composition. Disclosed herein too is a composition comprising magnesium hydridoborohydride having the formula MgnH(BH4)2n-1 where n is about 3 to about 7. Disclosed herein too is a method of manufacturing hydrogen comprising heating a composition comprising magnesium hydridoborohydride.
摘要翻译： 本文公开的方法包括使金属硼氢化物与金属氯化物组合物在溶剂中反应以形成反应混合物，其中金属氯化物组合物包含氯化镁; 其中金属硼氢化物和金属氯化物组合物不溶于溶剂; 研磨反应混合物以产生包含氢化二氢化镁的组合物; 并从组合物中除去溶剂。 本文还公开了一种组合物，其包含具有式MgH 2 H（BH 4）2 n-1的氢化氢硼氢化镁，其中n为约3至约 本文还公开了一种制造氢的方法，其包括加热包含氢化二氢硼氢化镁的组合物。
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公开(公告)号：US20050207959A1
公开(公告)日：2005-09-22
申请号：US09778997
申请日：2001-02-08
申请人： Yu Zhou
发明人： Yu Zhou
摘要： A process for synthesizing metal borohydride especially sodium borohydride directly from borax by the use of proton H at room temperature and pressure. Said process comprising the steps of: Providing proton H by the use of metals or alloys that can form hydrides with hydrogen. In this case, the metals or alloys are the carriers of proton H Proton H also can be provided from hydrogen gas by the use of catalysts located on the surface of carriers. Making the proton H enters the lattice of boron oxides Removing the oxygen from the lattice of boron oxides by the use of the carriers.
摘要翻译： 通过在室温和压力下使用质子H从硼砂直接合成金属硼氢化物，特别是硼氢化钠的方法。 所述方法包括以下步骤：通过使用可与氢形成氢化物的金属或合金来提供质子H. 在这种情况下，金属或合金是质子H的载体。质子H也可以通过使用位于载体表面上的催化剂由氢气提供。 使质子H进入氧化硼的晶格通过使用载体从氧化硼晶格中除去氧。
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公开(公告)号：US5298037A
公开(公告)日：1994-03-29
申请号：US954647
申请日：1992-09-30
申请人： Donald W. Murphy , Brijesh Vyas
发明人： Donald W. Murphy , Brijesh Vyas
CPC分类号： H01M4/383 , C23C22/60 , Y10T29/49108
摘要： Metals useful in the formation of hydrides for applications such as batteries are advantageously activated by a low temperature low pressure process. This process which is useful at room temperature and atmospheric pressure involves treating the metal such as LaNi.sub.5 with boron reducing agents such as NaBH.sub.4.
摘要翻译： 用于形成用于诸如电池的应用的氢化物的金属有利地通过低温低压法进行活化。 在室温和大气压下有用的该方法包括用诸如NaBH 4的硼还原剂处理诸如LaNi 5的金属。
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公开(公告)号：US5154860A
公开(公告)日：1992-10-13
申请号：US760307
申请日：1991-09-16
摘要： Disclosed is a method of inhibiting the electrochemical corrosion of stainless steel immersed in an aqueous solution of about 20 to about 40 wt % alkali metal hydroxide at a temperature of less than 100.degree. C. About 2 to about 500 ppm of sodium borohydride, hydrazine, or a mixture thereof is added to the aqueous solution.
摘要翻译： 公开了一种在小于100℃的温度下抑制浸入约20至约40重量％的碱金属氢氧化物的水溶液中的不锈钢的电化学腐蚀的方法。约2至约500ppm的硼氢化钠，肼， 或其混合物加入到水溶液中。
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