公开(公告)号：US20170370011A1

公开(公告)日：2017-12-28

申请号：US15548110

申请日：2016-02-03

Applicant: SHELL OIL COMPANY

Inventor： Jan Hermen Hendrik MEURS

IPC: C25B3/04 ,  C01D7/10 ,  B01D61/42 ,  C07C29/149

CPC classification number: C25B3/04 ,  B01D61/422 ,  B01D2311/02 ,  B01D2311/263 ,  C01D1/04 ,  C01D7/10 ,  C07C29/149 ,  C07C51/02 ,  C07C51/41 ,  C07C53/06 ,  C07C55/07 ,  C07C55/06 ,  C07C31/202

Abstract: The present invention provides a method of preparing oxalic acid (H2C2O4), the method at least comprising the steps of: (a) providing a metal formate (HCO2M) containing stream, wherein the metal (M) of the metal formate (HCO2M) is a monovalent metal selected from the group consisting of Li, Na, K, Cs, Rb and a mixture thereof; (b) heating the metal formate (HCO2M) containing stream thereby obtaining a metal oxalate (M2C2O4) containing stream; (c) subjecting the metal oxalate (M2C2O4) containing stream to electrodialysis, thereby obtaining at least oxalic acid (M2C2O4) and a metal hydroxide (MOH).

公开(公告)号：US20170029585A1

公开(公告)日：2017-02-02

申请号：US15291121

申请日：2016-10-12

Applicant: Asahi Glass Company, Limited

Inventor： Hiromitsu KUSANO ,  Takayuki KANEKO ,  Yasushi YAMAKI ,  Takayuki ENDO

IPC: C08J5/22 ,  C25B13/08 ,  B01J39/20 ,  C25B1/16 ,  C01D1/04 ,  B01J39/04

CPC classification number: C08J5/225 ,  B01J39/04 ,  B01J39/20 ,  B01J47/12 ,  C01D1/04 ,  C08F8/44 ,  C08F214/262 ,  C08J2327/12 ,  C08J2327/14 ,  C08J2329/10 ,  C25B1/16 ,  C25B9/08 ,  C25B13/08

Abstract: To provide a cation exchange membrane which is less susceptible to swelling or elongation during electrolysis of a potassium chloride aqueous solution even without permitting water absorption or swelling immediately prior to mounting it in an electrolyzer, and a method whereby it possible to stably produce a potassium hydroxide aqueous solution without necessity to conduct an operation for water absorption or swelling immediately prior to mounting the membrane in the electrolyzer. A cation exchange membrane comprising a polymer having cation exchange groups, wherein in cations (100 mol %) contained in the cation exchange membrane, the total of potassium ions and sodium ions is at least 99 mol %, and in the total (100 mol %) of potassium ions and sodium ions contained in the cation exchange membrane, the potassium ions are 80-98 mol % and the sodium ions are 20-2 mol %,

Abstract translation: 提供一种阳离子交换膜，即使在电解槽中将氯化钾水溶液电解之前也不会立即吸水或溶胀，电解过程中不易溶胀或伸长的阳离子交换膜，以及可以稳定地生产氢氧化钾 水溶液，而不必在将膜安装在电解槽中之前立即进行吸水或溶胀的操作。 一种阳离子交换膜，其包含具有阳离子交换基团的聚合物，其中，阳离子交换膜中所含的阳离子（100摩尔％）中，钾离子和钠离子的总和为99摩尔％以上，总计（100摩尔％ ）阳离子交换膜中含有的钾离子和钠离子，钾离子为80-98mol％，钠离子为20-2mol％

公开(公告)号：US20160185704A1

公开(公告)日：2016-06-30

申请号：US14912372

申请日：2014-09-05

Applicant: PLAXICA LIMITED

Inventor： Stephen Donegan ,  Philip James Goodier ,  Edward Leslie Marshall ,  Urvish Rameshchandra Pandya ,  Ajitkumar Mukundrai Patel

IPC: C07C51/02 ,  C07C51/41 ,  C07C67/08

CPC classification number: C07C51/02 ,  A01N63/02 ,  A61K35/744 ,  C01B7/03 ,  C01D1/04 ,  C01D3/04 ,  C07C51/295 ,  C07C51/41 ,  C07C59/08 ,  C07C67/08 ,  C07C69/68

Abstract: A process for producing lactic acid is provided. The process comprises (a) reacting a stream rich in saccharide with sodium hydroxide in the presence of water to produce a reaction mixture comprising sodium lactate; (b) reacting at least a portion of the sodium lactate with HCl to produce lactic acid and sodium chloride; (c) converting at least a portion of the sodium chloride to chlorine and sodium hydroxide; and (d) recycling at least a portion of the sodium hydroxide produced in step (c) to step (a). Also provided are processes for the production of alkyl lactate, oligomeric lactic acid, lactide, alkyl lactyllactate, poly-lactic acid, propylene glycol and acrylic acid.

Abstract translation: 提供了一种生产乳酸的方法。 该方法包括（a）在水的存在下使富含糖的物流与氢氧化钠反应，以产生包含乳酸钠的反应混合物; （b）使至少一部分乳酸钠与HCl反应生成乳酸和氯化钠; （c）将至少一部分氯化钠转化成氯和氢氧化钠; 和（d）将步骤（c）中产生的至少一部分氢氧化钠再循环到步骤（a）。 还提供了用于制备乳酸烷基酯，低聚乳酸，丙交酯，乳糖基乳酸烷基酯，聚乳酸，丙二醇和丙烯酸的方法。

公开(公告)号：US08829237B2

公开(公告)日：2014-09-09

申请号：US13039913

申请日：2011-03-03

Applicant: Robert J. Hanchar ,  Susanne Kleff ,  Michael V. Guettler

Inventor： Robert J. Hanchar ,  Susanne Kleff ,  Michael V. Guettler

IPC: C07C51/02 ,  C07C51/42 ,  C07C55/02 ,  C07C55/06 ,  C07C55/10 ,  C07C55/22 ,  C12P7/46 ,  C12P7/48 ,  C01F5/14 ,  C01C1/24 ,  C01D1/04 ,  C01F11/02

CPC classification number: C01C1/24 ,  C01D1/04 ,  C01F5/14 ,  C01F11/02 ,  C07C51/02 ,  C12P7/46 ,  C12P7/48 ,  C07C55/02 ,  C07C55/06 ,  C07C55/10 ,  C07C55/22 ,  C07C57/13 ,  C07C57/15

Abstract: This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C2-C12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

Abstract translation: 本发明提供了生产羧酸产物以及有用的盐的方法。 根据本发明制备的羧酸产物优选为C 2 -C 12羧酸。 在本发明方法中生产的盐是铵盐。

公开(公告)号：US08197664B2

公开(公告)日：2012-06-12

申请号：US12615437

申请日：2009-11-10

Applicant: Masataka Murahara

Inventor： Masataka Murahara

IPC: C25B1/34

CPC classification number: A01G31/00 ,  A01K63/042 ,  B01D61/025 ,  B01D61/48 ,  C01D1/04 ,  C01D1/40 ,  C02F1/42 ,  C02F1/441 ,  C02F1/461 ,  C02F1/66 ,  C02F9/00 ,  C02F2103/08 ,  C12C5/002 ,  C12F3/02 ,  C12G3/02 ,  C25B1/00 ,  F24S20/20 ,  Y02A20/131 ,  Y02A20/134 ,  Y02A20/141 ,  Y02A20/142 ,  Y02A20/144 ,  Y02E10/41 ,  Y02E60/368 ,  Y02P20/133 ,  Y02P20/134 ,  Y02P60/642 ,  Y02W10/33 ,  Y02W10/37

Abstract: Using electric power obtained by marine wind force and a tide, sea water is electrolyzed to produce fresh water, sodium, magnesium, calcium, potassium, caustic soda, chlorine, hydrochloric acid, sulfuric acid, hydrogen, oxygen or the like, at the same time, unloaded malts, saw dust and the like are fermented to brew ethanol, carbon dioxide generated here is used for photosynthesis to culture vegetables and oxygen generated here is supplied to a fish preserve and an under reef where fish live to culture fishes and also returned to sea water dropped in the concentration of oxygen to suppress the generation of a red tide.

Abstract translation: 使用海洋风力和潮汐获得的电力，电解电解产生淡水，钠，镁，钙，钾，苛性钠，氯，盐酸，硫酸，氢气，氧气等 时间，卸载麦芽，锯屑等发酵酿造乙醇，这里生成的二氧化碳用于培养蔬菜的光合作用，此处产生的氧气供应给鱼类和鱼类生活在鱼类之下的礁石，并返回 到海水中氧浓度下降，以抑制红潮的产生。

公开(公告)号：US20100034724A1

公开(公告)日：2010-02-11

申请号：US12488230

申请日：2009-06-19

Applicant: David Keith ,  Maryam Mahmoudkhani

Inventor： David Keith ,  Maryam Mahmoudkhani

IPC: C01B31/20 ,  C01B6/04

CPC classification number: B01D53/62 ,  B01D53/77 ,  B01D53/78 ,  B01D53/96 ,  B01D2251/304 ,  B01D2251/604 ,  B01D2257/504 ,  C01D1/04 ,  C01D7/07 ,  C01D7/37 ,  Y02C10/04 ,  Y02C10/06 ,  Y02P20/152

Abstract: A method of carbon dioxide capture is disclosed. In a step (a) anhydrous sodium carbonate is separated from a first aqueous solution formed by reacting carbon dioxide and an aqueous solution of sodium hydroxide. In step (b) the anhydrous sodium carbonate is treated by causticization to generate carbon dioxide and sodium hydroxide. The first aqueous solution of step (a) is formed by scrubbing a gas containing carbon dioxide with an aqueous solution of sodium hydroxide.

Abstract translation: 公开了一种捕获二氧化碳的方法。 在步骤（a）中，将无水碳酸钠与通过二氧化碳和氢氧化钠水溶液反应形成的第一水溶液分离。 在步骤（b）中，通过苛化处理无水碳酸钠以产生二氧化碳和氢氧化钠。 通过用氢氧化钠水溶液洗涤含二氧化碳的气体来形成步骤（a）的第一水溶液。

公开(公告)号：US07326822B1

公开(公告)日：2008-02-05

申请号：US10921930

申请日：2004-08-20

Applicant: Ignacio Cisneros

Inventor： Ignacio Cisneros

IPC: C07C7/20

CPC classification number: C01B6/04 ,  C01D1/04 ,  C10G29/06 ,  C10G29/16

Abstract: Metal hydride compounds, which are prepared by mixing together from about 1 to about 10 parts by molecular weight of at least one metal selected from the group consisting of silicon, aluminum, tin, and zinc; from about 1 to about 3 parts by molecular weight of an alkali metal hydroxide; and from about 5 to about 10 parts by molecular weight of water and allowing this mixture to stand for a time sufficient to form a metal hydride, can be used for making fuel additives, treating sour gas, enhancing oil refining, extracting oil from tar sands and shale, increasing production of hydrogen from a hydrogen plant, treating oil and gas wells to enhance production, eliminate PCBs, cleaning soil contaminated by hydrocarbons and/or heavy metals, controlling odors, cleaning polluting stack emissions, extracting edible and essential oils, and eliminating bacteria, fungicides, and parasites from vegetation.

Abstract translation: 金属氢化物，其通过将约1至约10份分子量的至少一种选自硅，铝，锡和锌的金属混合在一起制备; 约1至约3份分子量的碱金属氢氧化物; 和约5至约10份的水分子，并允许该混合物放置足以形成金属氢化物的时间，可用于制备燃料添加剂，处理酸性气体，增强炼油，从焦油砂中提取油 增加生产氢气，增加生产量，消除PCBs，清除被碳氢化合物和/或重金属污染的土壤，控制异味，清洗污染堆排放物，提取食用油和精油，以及 从植被中消除细菌，杀真菌剂和寄生虫。

公开(公告)号：US5545385A

公开(公告)日：1996-08-13

申请号：US403809

申请日：1995-05-03

Applicant: Heiko Wunder ,  Robert E. Scott-Young ,  Kenneth N. Maddern ,  Mark C. Corrigan

Inventor： Heiko Wunder ,  Robert E. Scott-Young ,  Kenneth N. Maddern ,  Mark C. Corrigan

IPC: B01J2/14 ,  C01D1/04 ,  C01G49/00 ,  C01G49/02 ,  D21C11/00 ,  D21C11/04 ,  D21C11/12 ,  C22B26/10 ,  C01D1/32

CPC classification number: B01J2/14 ,  C01D1/04 ,  C01G49/0027 ,  D21C11/0085 ,  D21C11/04 ,  D21C11/12 ,  C01P2002/32 ,  C01P2004/61 ,  F23G2209/101 ,  Y10S423/03

Abstract: The specification describes a process for recovering alkali metal hydroxides from an organic liquor such as black liquors derived from pulping wood chips. The organic liquor is burned in a fluidised bed combustion furnace containing fluidised particles of an iron rich mixed oxide of an alkali metal and iron. Particles of alkali metal ferrite are extracted from the furnace and dissolved in a solution of alkali metal hydroxide to form a more concentrated solution of alkali metal hydroxide and a precipitate of the iron rich mixed oxides of alkali metal and iron. A mixed oxide disclosed in the specification generally has the following formula: NaFe.sub.5 O.sub.8.4H.sub.2 O.

Abstract translation: PCT No.PCT / AU93 / 00499 Sec。 371日期：1995年5月3日 102（e）日期1995年5月3日PCT提交1993年9月30日PCT公布。 公开号WO94 / 07797 日期1994年4月14日该说明书描述了从有机液体中回收碱金属氢氧化物的方法，如来自制浆木片的黑液。 有机液体在包含碱金属和铁的富铁混合氧化物的流化颗粒的流化床燃烧炉中燃烧。 从炉中提取碱金属铁氧体的颗粒，溶解在碱金属氢氧化物溶液中，形成碱金属氢氧化物的浓缩溶液和碱金属和铁的富铁混合氧化物的沉淀物。 本说明书中公开的混合氧化物通常具有下式：NaFe 5·8·4H 2 O。

公开(公告)号：US5154860A

公开(公告)日：1992-10-13

申请号：US760307

申请日：1991-09-16

Applicant: Tilak V. Bommaraju ,  Robert G. Adams

Inventor： Tilak V. Bommaraju ,  Robert G. Adams

IPC: C01B6/15 ,  C01D1/04 ,  C23F11/06

CPC classification number: C01D1/04 ,  C01B6/15 ,  C23F11/06

Abstract: Disclosed is a method of inhibiting the electrochemical corrosion of stainless steel immersed in an aqueous solution of about 20 to about 40 wt % alkali metal hydroxide at a temperature of less than 100.degree. C. About 2 to about 500 ppm of sodium borohydride, hydrazine, or a mixture thereof is added to the aqueous solution.

Abstract translation: 公开了一种在小于100℃的温度下抑制浸入约20至约40重量％的碱金属氢氧化物的水溶液中的不锈钢的电化学腐蚀的方法。约2至约500ppm的硼氢化钠，肼， 或其混合物加入到水溶液中。

公开(公告)号：US4643846A

公开(公告)日：1987-02-17

申请号：US673176

申请日：1984-11-19

Applicant: Makoto Kanai ,  Hideaki Aikawa ,  Eiichi Inada ,  Katsuyuki Ohtsuka

Inventor： Makoto Kanai ,  Hideaki Aikawa ,  Eiichi Inada ,  Katsuyuki Ohtsuka

IPC: G21F9/06 ,  C01D1/04 ,  G21F9/00 ,  G21F9/30

CPC classification number: C01D1/04 ,  G21F9/30 ,  G21F9/305

Abstract: A process for the treatment of radioactive sodium is provided which comprises the steps of forming radioactive sodium amalgam by mixing radioactive sodium with mercury; reacting the radioactive sodium amalgam with water to form mercury and radioactive sodium hydroxide; recycling the mercury into the step of forming radioactive sodium amalgam to be mixed with the radioactive sodium; and solidifying the radioactive sodium hydroxide in the presence of a solidifying material to be confined in a stable solidified body.

Abstract translation: 提供了一种处理放射性钠的方法，包括通过将放射性钠与汞混合形成放射性钠汞齐的步骤; 使放射性钠汞齐与水反应形成汞和放射性氢氧化钠; 将汞循环到形成放射性钠汞齐以与放射性钠混合的步骤中; 并在固化材料的存在下固化放射性氢氧化钠以被限制在稳定的凝固体中。