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公开(公告)号：US07482412B2
公开(公告)日：2009-01-27
申请号：US11869221
申请日：2007-10-09
申请人： Kenzo Ohkita , Nobuyuki Sakabe
发明人： Kenzo Ohkita , Nobuyuki Sakabe
摘要： A process for manufacturing a cycloolefin addition polymer includes polymerizing monomers containing a cycloolefin compound using a catalyst containing a nickel compound or a palladium compound by addition polymerization in the presence of a molecular weight controlling agent in two steps, that is a step of a initiating the polymerization reaction using the monomers in an amount of not more than 80 wt % of the total monomers and a step of supplying the remaining monomers to the reaction system during the polymerization reaction. A cycloolefin addition polymer with a uniform quality, having a narrow molecular weight distribution and a controlled molecular weight, and excellently balanced processability and mechanical strength can be obtained at a high polymerization conversion rate using the process. The process can be operated at a highly controlled polymerization temperature, and is thus suitable for industrially manufacturing a cycloolefin addition polymer.
摘要翻译： 制备环烯加成聚合物的方法包括使用含有镍化合物或钯化合物的催化剂在含有分子量控制剂的两步加成聚合中使含有环烯烃化合物的单体聚合，即， 使用单体的聚合反应的量不大于总单体的80重量％，以及在聚合反应期间将剩余的单体供应到反应体系的步骤。 使用该方法可以以高聚合转化率获得具有均匀质量的具有均匀质量的环烯烃加成聚合物，具有窄的分子量分布和受控的分子量，并且具有优异的加工性能和机械强度。 该方法可以在高度控制的聚合温度下操作，因此适用于工业生产环烯加成聚合物。
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12.发明申请公开(公告)号：US20050215735A1
公开(公告)日：2005-09-29
申请号：US11053811
申请日：2005-02-09
申请人： Brian Goodall , Lester McIntosh
发明人： Brian Goodall , Lester McIntosh
CPC分类号： C08F32/04 , C08F4/70 , C08F120/14 , C08F232/04 , C08F220/14
摘要： A process for polymerizing and copolymerizing cyclic olefins, such as, norbornene is disclosed. The disclosed process uses a catalyst complex that exhibit a high activity for the polymerization and co-polymerization of cyclic olefins and improved stability toward heat, oxygen and moisture.
摘要翻译： 公开了降冰片烯等环状烯烃的聚合和共聚方法。 所公开的方法使用对环烯烃的聚合和共聚具有高活性并提高对热，氧和水分的稳定性的催化剂络合物。
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13.发明授权
公开(公告)号：US5880231A
公开(公告)日：1999-03-09
申请号：US548445
申请日：1995-10-26
IPC分类号： B01J23/46 , B01J31/22 , C07C51/353 , C07C67/475 , C07F15/00 , C08F4/80 , C08F8/50 , C08F10/00 , C08F32/00 , C08F210/02 , C08G61/08 , C08G61/12 , C08F32/04
CPC分类号： B01J31/2265 , B01J31/24 , B01J31/2404 , C07C51/353 , C07C67/333 , C07C67/475 , C07F15/002 , C07F15/0046 , C08C19/08 , C08F10/00 , C08F32/00 , C08F8/50 , C08G61/08 , C08G61/128 , B01J2231/14 , B01J2231/543 , B01J23/462 , B01J23/466 , B01J2531/821 , B01J2531/825 , C07C2101/10 , C08C2019/09 , C08F210/02 , Y10S525/938
摘要： Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins. Specifically, the present invention relates to carbene compounds of the formula ##STR1## wherein: M is Os or Ru; R and R.sup.1 are independently selected from hydrogen and functional groups C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.2 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl; each optionally substituted with C.sub.1 -C.sub.5 alkyl, a halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with a halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are each trialkyl phosphine ligands where at least one of the alkyl groups on the phosphine is a secondary alkyl or a cycloalkyl. A broad array of metathesis reactions are enabled including ring-opening metathesis polymerization of cyclic olefins, ring closing metathesis of acyclic dienes, cross metathesis involving at least one acyclic or unstrained cyclic olefin, and depolymerization of unsaturated polymers.
摘要翻译： 公开了在各种官能团存在下稳定的钌和咔咔啉化合物，其可用于在未应变的环状和无环烯烃上催化烯烃复分解反应。 具体地说，本发明涉及下式的卡宾化合物：其中：M是Os或Ru; R和R 1独立地选自氢和官能团C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 2 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基， C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基或C 1 -C 20烷基亚磺酰基; 每个任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或任选被卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基取代; X和X 1独立地选自任何阴离子配体; L和L1各自为三烷基膦配体，其中膦上的至少一个烷基是仲烷基或环烷基。 复分解反应的范围广泛，包括环烯烃的开环易位聚合，无环二烯的闭环复分解，涉及至少一个无环或非应变的环烯烃的交叉复分解，以及不饱和聚合物的解聚。
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公开(公告)号：US5482993A
公开(公告)日：1996-01-09
申请号：US386181
申请日：1995-02-09
申请人： Hidenori Hiraoka
发明人： Hidenori Hiraoka
IPC分类号： A63B49/08 , A63B53/14 , A63B59/00 , B62K21/26 , C08F32/04 , C08K3/34 , C08L7/00 , C08L23/16 , C08L9/00 , C08F132/04
CPC分类号： C08F32/04 , C08K3/34 , C08L23/16 , C08L7/00 , A63B60/06 , A63B60/08 , A63B60/10 , C08L2312/00
摘要： A rubber composition suitable for use in grips of articles such as golf clubs, tennis rackets, bicycles and tools, comprising (1) a rubber component containing a blend of an ethylene-propylene-diene rubber (EPDM) and natural rubber, (2) 2 to 40 parts by weight of a transpolyoctenamer per 100 parts by weight of the rubber blend, and (3) a filler containing a hydrated aluminum silicate powder, which provides grips having good non-slipping property, good feeling of touch and good response to mis-shot of golf balls.
摘要翻译： 一种适合用于高尔夫球杆，网球拍，自行车和工具的制品的夹具的橡胶组合物，包括（1）含有乙烯 - 丙烯 - 二烯橡胶（EPDM）和天然橡胶的共混物的橡胶组分，（2） 相对于100重量份的橡胶共混物，为2〜40重量份的透明酸钠，和（3）含有水合硅酸铝粉末的填料，其提供具有良好的非滑动性，良好的触感和良好的反应性 高尔夫球的误射。
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公开(公告)号：US4418178A
公开(公告)日：1983-11-29
申请号：US427368
申请日：1982-09-29
申请人： Elmer J. DeWitt
发明人： Elmer J. DeWitt
IPC分类号： C08F4/00 , C08F4/06 , C08F4/24 , C08F32/00 , C08F32/04 , C08F32/08 , C08G61/00 , C08G61/06 , C08G61/08 , C08L23/06 , C08L9/00 , C08L23/12 , C08L45/00
CPC分类号： C08G61/08
摘要： Impact modified polycycloolefin is made by ring opening bulk polymerization of at least one monomer containing at least one norbornene group in presence of an organoammonium molybdate or tungstate catalyst and an alkoxyalkylaluminum halide cocatalyst as well as a sufficient amount of a polyolefin powder and a rubbery material to produce ductile polycycloolefin.
摘要翻译： 抗冲改性聚环烯烃是通过在有机钼酸铵或钨酸盐催化剂和烷氧基烷基铝卤化物助催化剂的存在下，至少含有至少一个降冰片烯基团的单体进行开环本体聚合制备的，以及足够量的聚烯烃粉末和橡胶材料， 生产延性聚环烯烃。
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公开(公告)号：US4020257A
公开(公告)日：1977-04-26
申请号：US589935
申请日：1975-06-24
申请人： Josef Witte , Gunther Lehnert
发明人： Josef Witte , Gunther Lehnert
CPC分类号： C08G61/08 , B01J31/143 , B01J31/2265 , C07C6/06 , B01J2231/543 , B01J2531/66 , C07C2527/132 , C07C2531/02 , C07C2531/14 , C07C2531/34
摘要： Catalysts obtained fromA. a reaction product of 1 mol tungsten hexachloride with from 1 to 4 mols of a mixture of 2-chloroethanol and 2,2,2-trichloroethanol in a molar ratio of from 1 : 3 to 3 : 1; andB. from 1 to 20 mol, per mol of tungsten in component (A), of an organometallic aluminium for disproportionation and metathesis of olefin and for ring opening polymerization of cyclic olefins.
摘要翻译： 从A.得到的催化剂是1摩尔六氯化钨与1至4摩尔2-氯乙醇和2,2,2-三氯乙醇的摩尔比为1:3至3:1的混合物的反应产物，
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公开(公告)号：US11667731B2
公开(公告)日：2023-06-06
申请号：US17854026
申请日：2022-06-30
发明人： Shun Hayakawa , Guodong Deng , Larry F Rhodes
摘要： Embodiments in accordance with the present invention encompass compositions comprising a long shelf stabilized organopalladium compound of formula (I) as described herein. The composition further contains a photoacid generator, a photosensitizer and one or more olefinic monomers as described herein. The shelf life of the compositions can further be extended by employing a stabilizer, such as for example, a hindered amine. The composition undergoes vinyl addition polymerization when it is exposed to a suitable actinic radiation to form a substantially transparent film or a three dimensional object. More specifically, the compositions of this invention are stable at room temperature for several days to several months and can also be stored at higher temperatures from about 40° C. to 60° C. for several days and undergo mass polymerization only when subjected to suitable actinic radiation. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films and/or three dimensional objects having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, sealants, adhesives, among others.
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公开(公告)号：US20220258146A1
公开(公告)日：2022-08-18
申请号：US17577510
申请日：2022-01-18
摘要： A tetraanionic OCO pincer ligand metal-oxo-alkylidene complex is prepared from a trianionic pincer ligand supported metal-alkylidyne. The metal can be tungsten or other group 5-7 transition metal. The tetraanionic pincer ligand metal-oxo-alkylidene complex, a trianionic OCO pincer ligand metal complex, or a trianionic ONO pincer ligand metal complex can be used to polymerize cycloalkenes. The poly(cycloalkene)s are predominantly cis-alkene macrocyclics.
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公开(公告)号：US10723836B2
公开(公告)日：2020-07-28
申请号：US15565334
申请日：2016-04-05
申请人： Bostik SA
IPC分类号： C08G61/08 , C07D317/38 , C08G61/12 , C08G71/04 , C08G61/06 , C08F2/42 , C08G61/04 , C08F2/40 , C08F2/38 , C08F32/04
摘要： The invention relates to a hydrocarbon polymer comprising two exo-vinylene cyclic carbonate terminal groups, of formula (1), production method thereof and use of same for the production of coating, mastic and adhesive compositions.
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公开(公告)号：US20180037677A1
公开(公告)日：2018-02-08
申请号：US15547942
申请日：2016-02-11
申请人： MATERIA, INC.
CPC分类号： C08F4/70 , C07F15/02 , C08F32/04 , C08F285/00 , C08G18/7671 , C08G61/08 , C08G2261/135 , C08G2261/3325 , C08G2261/418 , C08G2261/62 , C08G2261/76 , C08J5/24 , C08J2365/04 , C08K5/205 , C08K5/32 , C08K7/06 , C08K7/14 , C08L51/04 , C08L53/025 , C08L65/00
摘要： This invention relates to compositions and methods for improving the impact properties of polymer-matrix composites and to improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the impact properties of ring opening metathesis polymerization (ROMP) polymer-matrix composites and to improving the adhesion of ROMP compositions to substrate materials using adhesion promoters containing at least two isocyanate groups and functional elastomers comprising a maleic anhydride grafted styrene-ethylene/butylene-styrene hydrogenated copolymer in a resin composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.
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