公开(公告)号：US20050124717A1

公开(公告)日：2005-06-09

申请号：US11040880

申请日：2005-01-21

Applicant: Naiyong Jing ,  Tatsuo Fukushi ,  Attila Molnar ,  David Bilbrey ,  Mark Muggli ,  Andrew Hine ,  Kathryn Spurgeon ,  Christopher Haak

Inventor： Naiyong Jing ,  Tatsuo Fukushi ,  Attila Molnar ,  David Bilbrey ,  Mark Muggli ,  Andrew Hine ,  Kathryn Spurgeon ,  Christopher Haak

IPC: F16L11/04 ,  B32B27/08 ,  B32B27/28 ,  B32B27/30 ,  C08L27/12 ,  C08L27/16 ,  C08L27/18 ,  F16L11/127 ,  C08J3/18

CPC classification number: C08L27/16 ,  B32B27/08 ,  B32B27/28 ,  C08L27/18 ,  C08L2205/02 ,  Y10T428/1393 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31678 ,  C08L2666/04

Abstract: Disclosed are various fluoropolymer blend combinations and multilayer articles comprising a blend in a first layer and a second layer comprising a polymer bonded to the first layer. The invention also provides an article comprising a first layer comprising a blend of two or more fluoropolymers, and a second layer bonded to the first layer, the second layer comprising a partially-fluorinated thermoplastic polymer, a perfluorinated thermoplastic polymer, or a combination thereof. The invention also provides an article comprising a first layer comprising a blend of two or more fluoropolymers, at least one of which comprises a partially-fluorinated thermoplastic polymer, and optionally at least one perhalogenated polymer, and a second layer bonded to the first layer, the second layer comprising an at least partially-fluorinated thermoplastic polymer. The invention also provides processes for preparing blended fluoropolymers and multilayer articles comprising a fluoropolymer layer.

Abstract translation: 公开了各种含氟聚合物共混物组合和多层制品，其包含在第一层中的共混物和包含结合到第一层的聚合物的第二层。 本发明还提供了一种制品，其包括包含两种或更多种含氟聚合物的共混物的第一层和与第一层结合的第二层，第二层包含部分氟化的热塑性聚合物，全氟化的热塑性聚合物或其组合。 本发明还提供一种包含第一层的制品，该第一层包含两种或更多种含氟聚合物的共混物，其中至少一种包含部分氟化的热塑性聚合物和任选的至少一种全卤化聚合物，以及与第一层结合的第二层， 所述第二层包含至少部分氟化的热塑性聚合物。 本发明还提供了制备包含含氟聚合物层的混合含氟聚合物和多层制品的方法。

公开(公告)号：US06844030B2

公开(公告)日：2005-01-18

申请号：US10023271

申请日：2001-12-14

Applicant: Naiyong Jing ,  George Van Dyke Tiers

Inventor： Naiyong Jing ,  George Van Dyke Tiers

IPC: C08J7/00 ,  C08J5/12 ,  C08J7/12 ,  C08F2/46

CPC classification number: C08J7/12 ,  C08J5/124 ,  Y10T428/31504 ,  Y10T428/3154 ,  Y10T428/31616 ,  Y10T428/31623 ,  Y10T428/31645 ,  Y10T428/31721 ,  Y10T428/31786 ,  Y10T428/31938

Abstract: This invention concerns a process for modifying a polymeric substrate by contacting the surface with a photoreactive solution of an inorganic photochemical electron donor while irradiating the surface with actinic radiation. Patterns of modified and unmodified surfaces can be produced. Polymeric substrates with modified surfaces may be effectively bonded to polymer films to form composite articles. The process has particular applicability to the surface modification of fluorinated polymers.

Abstract translation: 本发明涉及一种通过使表面与无机光化学电子给体的光反应溶液接触，同时用光化辐射照射表面来改性聚合物基材的方法。 可以生产修饰和未改性表面的图案。 具有改性表面的聚合物基材可以有效地结合到聚合物膜上以形成复合制品。 该方法特别适用于氟化聚合物的表面改性。

公开(公告)号：US06737489B2

公开(公告)日：2004-05-18

申请号：US09861782

申请日：2001-05-21

Applicant: Jeffrey G. Linert ,  E. Steven McAlister ,  Lian S. Tan ,  Richard S. Buckanin ,  Naiyong Jing ,  Frans A. Audenaert ,  Thomas J. Blong ,  John C. Clark ,  Linda G. Coté ,  Harald Kaspar ,  Franz März

Inventor： Jeffrey G. Linert ,  E. Steven McAlister ,  Lian S. Tan ,  Richard S. Buckanin ,  Naiyong Jing ,  Frans A. Audenaert ,  Thomas J. Blong ,  John C. Clark ,  Linda G. Coté ,  Harald Kaspar ,  Franz März

IPC: C08F11418

CPC classification number: D06M15/568 ,  C08L27/12 ,  D06M13/395 ,  D06M13/432 ,  D06M15/256 ,  D06M15/263 ,  D06M15/277 ,  D06M15/353 ,  D06M15/3562 ,  D06M15/3566 ,  D06M2200/11 ,  D06M2200/12 ,  C08L2666/04

Abstract: A fluorochemical composition for rendering a fibrous substrate oil and/or water repellent which comprises a solution or dispersion of a fluoropolymer having a partially or fully fluorinated backbone and comprising one or more repeating units corresponding to the general formula: wherein Rf represents a perfluorinated organic group having a chain length of at least 2 atoms and having at least one carbon atom and optional auxiliary components.

Abstract translation: 一种用于提供纤维基质油和/或防水剂的含氟组合物，其包含具有部分或全部氟化骨架的含氟聚合物的溶液或分散体，并且包含一个或多个对应于以下通式的重复单元：其中Rf表示全氟化有机基团 具有至少2个原子的链长并且具有至少一个碳原子和任选的辅助成分。

公开(公告)号：US06706796B2

公开(公告)日：2004-03-16

申请号：US10244708

申请日：2002-09-16

Applicant: Prabhakara Satyauolu Rao ,  Naiyong Jing

Inventor： Prabhakara Satyauolu Rao ,  Naiyong Jing

IPC: C08K502

CPC classification number: G03G9/132 ,  B01F17/005 ,  C07C271/16 ,  C08F220/24 ,  C08F290/12

Abstract: The present invention provides a compound according to the formula: CH2═C(R1)—C(O)—R6—NHCO2(CH2)p(CF2)q—O—((CF2)8CFXO)m(CF2)r—Z wherein each R1 is independently selected from —H, —CH3, —F and —Cl, wherein each R6 is independently selected from substituted or unsubstituted C1-C10 alkyl, cyclic alkyl, or aryl groups, wherein each a is independently selected from 0-3, wherein each X is independently selected from —F, —CF3 or —CF2CF3, wherein each p is independently selected from 1-4, each q is independently selected from 1-5, each r is independently selected from 1-5, each m is independently selected from 1-50, each Z is independently selected from —F and —(CH2)5OH, and each s is independently selected from 1-4. The present invention also provides for the use of this compound as a surfactant in highly fluorinated liquid solvents. Latexes of dispersed particles utilizing this surfactant are provided.

Abstract translation: 本发明提供下式的化合物：CH 2 = C（R 1）-C（O）O 6 -NHCO 2（CH 2）p（CF 2）q O - （（CF 2）ACF X O）m（CF 2） 其中每个R 1独立地选自-H，-CH 3，-F和-Cl，其中每个R 6独立地选自取代或未取代的C 1 -C 10烷基，环烷基或芳基，其中每个 a独立地选自0-3，其中每个X独立地选自-F，-CF 3或-CF 2 CF 3，其中每个p独立地选自1-4，每个q独立地选自1-5，每个r独立地 选自1-5，每个m独立地选自1-50，每个Z独立地选自-F和 - （CH 2）SOH，并且各自独立地选自1-4。 本发明还提供在高度氟化的液体溶剂中使用该化合物作为表面活性剂。 提供了使用该表面活性剂的分散颗粒的乳胶。

公开(公告)号：US06562911B2

公开(公告)日：2003-05-13

申请号：US10033485

申请日：2001-12-28

Applicant: Naiyong Jing ,  Brant U. Kolb ,  Robert E. Kolb

Inventor： Naiyong Jing ,  Brant U. Kolb ,  Robert E. Kolb

IPC: C08L2722

CPC classification number: C07C69/63 ,  C07C69/36 ,  C08K5/09 ,  C08L75/00

Abstract: In one aspect, the invention provides curable fluoropolymer compositions comprising fluoropolymer, onium, and alkyl or aryl oxalate-blocked compound as a crosslinking agent. In other aspects, the invention provides methods of making curable fluoropolymer compositions and provides alkyl or aryl oxalate-blocked compounds.

公开(公告)号：US06452038B1

公开(公告)日：2002-09-17

申请号：US09605211

申请日：2000-06-28

Applicant: Prabhakara Satyauolu Rao ,  Naiyong Jing

Inventor： Prabhakara Satyauolu Rao ,  Naiyong Jing

IPC: C07C27100

CPC classification number: G03G9/132 ,  B01F17/005 ,  C07C271/16 ,  C08F220/24 ,  C08F290/12

Abstract: The present invention provides a compound according to the formula: CH2═C(R1)—C(O)—R6—NHCO2(CH2)p(CF2)q—O—((CF2)aCFXO)m(CF2)r—Z wherein each R1 is independently selected from —H, —CH3, —F and —Cl, wherein each R6 is independently selected from substituted or unsubstituted C1-C10 alkyl, cyclic alkyl, or aryl groups, wherein each a is independently selected from 0-3, wherein each X is independently selected from —F, —CF3 or —CF2CF3, wherein each p is independently selected from 1-4, each q is independently selected from 1-5, each r is independently selected from 1-5, each m is independently selected from 1-50, each Z is independently selected from —F and —(CH2)sOH, and each s is independently selected from 1-4. The present invention also provides for the use of this compound as a surfactant in highly fluorinated liquid solvents. Latexes of dispersed particles utilizing this surfactant are provided.

Abstract translation: 本发明提供了下列化合物：CH 2 = C（R 1）-C（O）-R 6 -NHCO 2（CH 2）p（CF 2）q O - （（CF 2）a CFXO）m（CF 2） 独立地选自-H，-CH 3，-F和-Cl，其中每个R 6独立地选自取代或未取代的C 1 -C 10烷基，环烷基或芳基，其中每个a独立地选自0-3，其中每个 X独立地选自-F，-CF 3或-CF 2 CF 3，其中每个p独立地选自1-4，每个q独立地选自1-5，每个r独立地选自1-5，每个m独立地选自 从1-50，每个Z独立地选自-F和 - （CH 2）s OH，并且各个s独立地选自1-4。 本发明还提供在高度氟化的液体溶剂中使用该化合物作为表面活性剂。 提供了使用该表面活性剂的分散颗粒的乳胶。

公开(公告)号：US06359166B1

公开(公告)日：2002-03-19

申请号：US09415552

申请日：1999-10-08

Applicant: Naiyong Jing ,  Brant U. Kolb ,  Robert E. Kolb

Inventor： Naiyong Jing ,  Brant U. Kolb ,  Robert E. Kolb

IPC: C07C6936

CPC classification number: C07C69/63 ,  C07C69/36 ,  C08K5/09 ,  C08L75/00

Abstract: In one aspect, the invention provides curable fluoropolymer compositions comprising fluoropolymer, onium, and alkyl or aryl oxalate-blocked compound as a crosslinking agent. In other aspects, the invention provides methods of making curable fluoropolymer compositions and provides alkyl or aryl oxalate-blocked compounds.

Abstract translation: 一方面，本发明提供包含含氟聚合物，鎓和作为交联剂的草酸烷基或芳基酯化合物的可固化含氟聚合物组合物。 在其它方面，本发明提供了制备可固化含氟聚合物组合物并提供草酸或芳基草酸酯封端化合物的方法。

公开(公告)号：US5654375A

公开(公告)日：1997-08-05

申请号：US655356

申请日：1996-05-24

Applicant: Naiyong Jing ,  Robert E. Kolb ,  Trang D. Pham

Inventor： Naiyong Jing ,  Robert E. Kolb ,  Trang D. Pham

IPC: C08J3/24 ,  C08F8/00 ,  C08F8/44 ,  C08K5/00 ,  C08K5/06 ,  C08K5/16 ,  C08K5/49 ,  C08K5/59 ,  C08L27/12 ,  C08L57/08 ,  C08F8/42

CPC classification number: C08K5/0025

Abstract: This invention provides a curable fluoroelastomer composition comprising:(a) a fluorine-containing polymer or blend of fluorine-containing polymers each comprising interpolymerized units derived from one or more fluorine-containing ethylenically-unsaturated monomers;(b) a crosslinking agent; and(c) an acid functional organo-onium compound.

Abstract translation: 本发明提供了一种可固化的含氟弹性体组合物，其包含：（a）含氟聚合物或含氟聚合物的共混物，其各自包含衍生自一种或多种含氟烯属不饱和单体的共聚单元; （b）交联剂; 和（c）酸官能的有机鎓化合物。