Abstract:
The present invention is based upon the unexpected finding that lignin can be incorporated into wire coat stock composition to improve metal to rubber adhesion. It has been further found that lignin can be used as a replacement in whole or in part for conventional rubber-to-metal adhesion promoters, such as cobalt materials which are conventionally used in wire coat stocks to attain and maintain needed rubber-to-wire adhesion properties. In fact, wire coat stocks that contain lignin provide more that adequate rubber-to-metal adhesion characteristics for typical applications, such as in tires, and maintain needed levels of adhesion over long periods of product service. For instance, high levels of rubber-to-metal adhesion are maintained under harsh conditions, such as exposure to elevated temperatures and high levels of humidity. The utilization of lignin in wire coat stock formulations in accordance with this invention is also economically advantageous since lignin is a low cost alternative to most conventional adhesion promoting agents. Lignin is also environmentally friendly and does not present any known health hazards. Lignin is derived from wood and constitutes about 25 percent to 33 percent of the dry mass of wood. Accordingly, lignin is an abundant naturally occurring organic polymer which is a renewable resource since it is derived from trees. Accordingly, lignin represents a low cost, abundant, environmentally friendly, and highly effective alternative to conventional rubber-to-metal adhesion promoters. The present invention more specifically discloses a wire coat stock composition which is comprised of (1) a rubbery polymer, (2) about 40 phr to about 80 phr of carbon black, and (3) about 2 phr to about 30 phr of lignin.
Abstract:
The present invention is directed to a method of processing a rubber composition, comprising the steps of mixing at least one diene base elastomer with at least one additive selected from the group consisting of fillers, to a final temperature of about 150 to about 160° C. in a first non-productive mix step to form a first non-productive mix; cooling the first non-productive mix to a temperature of about 60 to about 90° C.; mixing the first non-productive mix with 0.1 to 10 parts by weight, per 100 parts by weight of elastomer, of a treated short aramid fiber having a length ranging from 1 to 10 mm and having a thickness ranging from 5 to 15 microns and comprising 3 to 40 percent by weight of a peroxide radical initiator in a second non-productive mix step to a final temperature of about 150 to about 160° C. to form a second non-productive mix; and mixing the second non-productive mix with curatives in a productive mix step to form a productive mix.
Abstract:
The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 30 parts by weight, per 100 parts by weight of elastomer (phr), of a polyketone short fiber having a length ranging from 0.5 to 20 mm having a weight ranging from 0.5 to 5 decitex, and from 1 to 15 phr of a polyethyleneimine having an average molecular weight of 800 to 2000000.
Abstract:
A pneumatic tire including at least one component having a rubber composition including at least one diene based elastomer and a silica that prior to mixing with said elastomer is prehydrophobated with a fluorinated silane of the following formula: Rf—R1—SiX3-x—R2x I wherein Rf is a perfluorinated group optionally containing one or more heteroatoms; R1 is a divalent alkylene group, arylene group or mixture thereof, substituted with one or more heteroatoms or functional groups, containing about 1 to about 16 carbon atoms; R2 is a lower alkyl group; X is a halide, a lower alkoxy group or an acyloxy group; and x is 0 or 1.
Abstract translation:一种充气轮胎,其包括至少一种具有橡胶组合物的组分,所述橡胶组合物包含至少一种二烯基弹性体和二氧化硅,在与所述弹性体混合之前,用下式的氟化硅烷进行预疏水处理: 在线公式“end =”lead“?> Rf-R1-SiX3-x-R2x I <?in-line-formula description =”In-line formula“end =”tail“?>其中Rf是全氟化基团 任选地含有一个或多个杂原子; R 1是被一个或多个含有约1至约16个碳原子的杂原子或官能团取代的二价亚烷基,亚芳基或其混合物; R2是低级烷基; X是卤素,低级烷氧基或酰氧基; x为0或1。
Abstract:
The present invention relates to pneumatic tire having a component including exfoliated graphite intercalated with an elastomer, and at least one additional diene based elastomer.
Abstract:
The present invention is directed to a pneumatic tire comprising at least one component selected from the group consisting of apexes, flippers and chippers, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 30 parts by weight, per 100 parts by weight of elastomer (phr), of a polybenzobisoxazole (PBO) short fiber having a length ranging from 0.5 to 20 mm having a thickness ranging from 10 to 30 microns, and from 1 to 50 phr of an epoxidized polyisoprene having a number-average molecular weight of 5000 to 100000.
Abstract:
The present invention is directed to a pneumatic tire comprising at least one component selected from the group consisting of apexes, flippers and chippers, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 30 parts by weight, per 100 parts by weight of elastomer (phr), of a polybenzobisoxazole (PBO) short fiber having a length ranging from 0.5 to 20 mm having a thickness ranging from 10 to 30 microns, and from 1 to 50 phr of an epoxidized polyisoprene having a number-average molecular weight of 5000 to 100000.
Abstract:
The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 30 parts by weight, per 100 parts by weight of elastomer, of a polybenzobisoxazole (PBO) short fiber having a length ranging from 0.5 to 20 mm and a thickness ranging from 10 to 30 microns, and from 1 to 30 parts by weight, per 100 parts by weight of elastomer, of an epoxidized palm oil.
Abstract:
The present invention is directed to a method of processing a rubber composition, comprising the steps of mixing at least one diene base elastomer with at least one additive selected from the group consisting of fillers, to a final temperature of about 150 to about 160° C. in a first non-productive mix step to form a first non-productive mix; cooling the first non-productive mix to a temperature of about 60 to about 90° C.; mixing the first non-productive mix with 0.1 to 10 parts by weight, per 100 parts by weight of elastomer, of a treated short aramid fiber having a length ranging from 1 to 10 mm and having a thickness ranging from 5 to 15 microns and comprising 3 to 40 percent by weight of a peroxide radical initiator in a second non-productive mix step to a final temperature of about 150 to about 160° C. to form a second non-productive mix; and mixing the second non-productive mix with curatives in a productive mix step to form a productive mix.
Abstract:
A pneumatic tire includes an axis of rotation, a carcass, a tread disposed radially outward of the carcass, a belt structure disposed radially between the carcass and the tread, and a reinforcing structure providing a buffer for absorbing shear strain. The reinforcing structure includes a layer of a knitted fabric. The layer includes first yarns and second yarns.