摘要:
A fuel cell system that employs a technique for reducing MEA degradation during system shut-down that occurs as a result of the hydrogen and air being present in the fuel cell stack flow channels. The fuel cell system includes a non-linear load element, such as a positive temperature coefficient resistor, electrically coupled to each fuel cell in the fuel cell stack. The non-linear element operates such that it has high electrical conduction at low cell voltages and low electrical conduction at high cell voltages. During system shut-down, the voltage that is generated as a result of the hydrogen and air interaction in the fuel cells that creates a low cell voltage is drawn from the fuel cell and dissipated by the element. During system operation, the fuel cell potentials are relatively high and the resistance of the element goes up so that less current flows through the element, thus reducing electrical losses.
摘要:
A fuel cell system is provided that includes a fuel cell stack with a plurality of fuel cells and a power converter in electrical communication with the fuel cell stack. The power converter is configured to selectively regulate a power of the fuel cell stack and short circuit the fuel cell stack, as desired. A method for starting the fuel cell stack is also described including the steps of causing a short circuit of the fuel cell stack by placing the power converter in a short circuit mode; introducing a hydrogen to the anodes of the fuel cell stack to displace a quantity of air on the anodes; and placing the power converter in a power regulation mode. A degradation of the fuel cell stack during start-up is thereby militated against.
摘要:
A method for reconditioning a fuel cell stack. The method includes periodically increasing the relative humidity level of the cathode input airflow to the stack to saturate the cell membrane electrode assemblies to be greater than the relative humidity levels during normal stack operating conditions. The method also includes providing hydrogen to the anode side of the fuel cell stack at system shut down while the membrane electrode assemblies are saturated without stack loads being applied so that the hydrogen crosses the cell membranes to the cathode side and reacts with oxygen to reduce stack contaminants.
摘要:
A system and method for increasing the temperature of a fuel cell stack quickly, especially at cold stack start-up. The method includes determining whether the fuel cell stack is below a first predetermined temperature threshold, and, if so, starting a cooling fluid flow through the stack and engaging a shorting circuit across the stack to short circuit the stack and cause the stack to operate inefficiently. The method then determines a desired heating rate of the fuel cell stack and calculates a cathode airflow to the fuel cell stack based on the desired heating rate. The method reduces the flow of cathode air to the stack if a minimum cell voltage is below a predetermined minimum cell voltage threshold and disengages the shorting circuit and applies vehicle loads to the stack when the stack temperature reaches a predetermined second temperature threshold.
摘要:
A system for oxidizing contaminants on both the cathode and anode electrodes in a fuel cell stack by applying a suitable voltage potential across the electrodes that causes the oxidation. The system includes a battery and an electrical converter electrically coupled to the battery. The electrical converter is configured to assist in providing an oxidation potential to the fuel cell stack by converting electrical power from the battery at a time effective to oxidize contaminants on the cathode or anode electrodes in the stack. The electrical converter provides a positive potential to the fuel cell stack to oxidize contaminants on the cathode electrodes and provides a negative potential to the fuel cell stack to oxidize contaminants on the anode electrodes. If the battery is a high voltage battery, then the converter is a power converter and if the battery is a low voltage battery, then the converter is boost converter.
摘要:
A system and method for removing contaminants from a fuel cell stack. The method includes exposing the cathode and anode of the stack to an air purge, then exposing the cathode and anode of the stack to a water flush and then again exposing the cathode and anode of the stack to an air purge to dry the stack. In one technique, the stack is removed from the vehicle at a maintenance facility to perform the air purge and water flush, and in another technique, the stack remains in the vehicle and appropriate hoses are connected to the stack for the air purges and water flush.
摘要:
A method for reducing the probability of an air/hydrogen front in a fuel cell stack is disclosed that includes closing anode valves for an anode side of the fuel cell stack to permit a desired quantity of hydrogen to be left in the anode side upon shutdown and determining a schedule to inject hydrogen during the time the fuel cell stack is shutdown. The pressure on an anode input line is determined and a discrete amount of hydrogen is injected into the anode side of the stack according to the determined schedule by opening anode input line valves based on the determined pressure along the anode input line so as to inject the hydrogen into the anode side of the stack.
摘要:
An algorithm for determining a polarization curve of a fuel cell stack. When the fuel cell stack is running and certain data validity criteria have been met, the algorithm goes into a data collection mode where it collects stack data, such as stack current density, average cell voltage and minimum cell voltage. When the stack is shut down, the algorithm uses a cell voltage model to solve a least squares problem to estimate predetermined parameters that define the polarization curve. If the estimated parameters satisfy certain termination criteria, then the estimated parameters are stored to be used by a system controller to calculate the polarization curve of the stack.
摘要:
A fuel cell system is provided having a fuel cell stack including a plurality of fuel cells. The fuel cell system includes an anode supply manifold in fluid communication with the plurality of fuel cells, the anode supply manifold adapted to deliver a anode supply stream to the plurality of fuel cells; an anode exhaust manifold in fluid communication with the anodes of the plurality of fuel cells, the anode exhaust manifold adapted to receive an anode exhaust stream from the plurality of fuel cells; a first valve in fluid communication with the anode supply manifold; and a second valve in fluid communication with the anode exhaust manifold. A method of starting the fuel cell system is also provided. The fuel cell system and method militates against a non-uniform distribution of the anode supply stream to the anodes of the plurality of fuel cells.