公开(公告)号：US4351755A

公开(公告)日：1982-09-28

申请号：US195081

申请日：1980-10-08

Applicant: Darryl W. Brixius ,  John A. Simms

Inventor： Darryl W. Brixius ,  John A. Simms

IPC: C08F220/36 ,  C08G18/72 ,  C09D133/14 ,  C08K5/10 ,  B32B17/10 ,  C08F26/02

CPC classification number: C08G18/728 ,  C08F220/36 ,  C09D133/14 ,  Y10T428/31551 ,  Y10T428/31645 ,  Y10T428/31699

Abstract: Low molecular weight polydisperse isocyanate-functional acrylic polymers are provided which contain terminal monosulfide groups on at least 10% by number of polymer molecules but are substantially free of toxic monomeric isocyanates.The polymers are prepared by direct reaction of the monomers, e.g., 2-isocyanatoethyl methacrylate and butyl acrylate, in the presence of a mercaptan chain-transfer agent and a polymerization initiator but in the substantial absence of water and of Lewis-type bases. They can be crosslinked and are useful in a variety of applications such as moisture-curing coating compositions.

Abstract translation: 提供低分子量多分散异氰酸酯官能的丙烯酸聚合物，其含有至少10％数量的聚合物分子的末端单硫基，但基本上不含有毒单体异氰酸酯。 通过单体例如甲基丙烯酸2-异氰酸根合乙酯和丙烯酸丁酯在硫醇链转移剂和聚合引发剂的存在下，但基本上不存在水和路易斯碱的碱直接反应来制备聚合物。 它们可以交联并且可用于各种应用中，例如湿固化涂料组合物。

公开(公告)号：US4255298A

公开(公告)日：1981-03-10

申请号：US87463

申请日：1979-10-19

Applicant: John A. Simms

Inventor： John A. Simms

IPC: C08F251/02 ,  C08F265/06 ,  C08F291/14 ,  C08G18/64 ,  C08G18/80 ,  C08G81/02 ,  C09D151/02 ,  C09D187/00 ,  C08L1/14 ,  C08L1/10

CPC classification number: C09D187/005 ,  C08F251/02 ,  C08G18/6484 ,  C08G18/8054 ,  C09D151/02

Abstract: A graft copolymer having a polymeric backbone with pendent hydroxyl groups; wherein the hydrogen atom of at least the one the hydroxyl groups is replaced by the formula ##STR1## where R is an aliphatic group, a cycloaliphatic group or an aromatic group; R.sup.1 is an alkylene group having 2-6 carbon atoms; R.sup.2 is a polymer segment of a vinyl addition polymer, such as butyl acrylate/hydroxyethyl acrylate; coating compositions of this copolymer can be cross-linked with conventional cross-linking agents such as an alkylated melamine formaldehyde resin or an organic polyisocyanate and coating compositions useful for flexible elastomeric substrates can be prepared from this copolymer.

公开(公告)号：US4222909A

公开(公告)日：1980-09-16

申请号：US917283

申请日：1978-06-20

Applicant: Darryl W. Brixius ,  John A. Simms

Inventor： Darryl W. Brixius ,  John A. Simms

IPC: C08F20/36 ,  C08G18/72 ,  C08G18/77 ,  C08L33/06 ,  C09D7/45 ,  C09D125/14 ,  C08L75/02 ,  C08L91/00

CPC classification number: C09D7/02 ,  C08F20/36 ,  C08G18/728 ,  C08G18/775 ,  C09D125/14 ,  C08L33/062

Abstract: Low molecular weight isocyanate-functional acrylic polymers are provided, which contain at least 10% by weight of copolymerized isocyanatoalkyl (meth)acrylate, are substantially free of toxic monomeric isocyanates, and have the following general structure: ##STR1## where R is alkyl or aryl,R.sub.1 is hydrogen or methyl;X is COO--A--NCO or a mixture of COO--A--NCO and at least one of phenyl, COOR.sub.2, ##STR2## Cl, H; where A is an alkylene group having 2-6 carbon atoms, andR.sub.2 is an alkyl group having 1-18 carbon atoms;and n is 2-400.These polymers can be crosslinked and are useful in a variety of applications such as finishes, pigment surface treatments and dispersants, and rheology control agents.

Abstract translation: 提供低分子量异氰酸酯官能的丙烯酸聚合物，其含有至少10重量％的共聚的（甲基）丙烯酸异氰酸烷基酯，基本上不含有毒单体异氰酸酯，并具有以下通用结构：其中R是烷基或 芳基，R 1是氢或甲基; X是COO-A-NCO或COO-A-NCO与苯基，COOR2，Cl，H， 其中A是具有2-6个碳原子的亚烷基，R2是具有1-18个碳原子的烷基; n为2-400。 这些聚合物可以是交联的，并且可用于各种应用，如表面处理，颜料表面处理和分散剂，以及流变控制剂。

公开(公告)号：US4219632A

公开(公告)日：1980-08-26

申请号：US17073

申请日：1979-03-02

Applicant: John A. Simms

Inventor： John A. Simms

IPC: C08F20/00 ,  C08F20/34 ,  C08F220/36 ,  C08G18/00 ,  C08G18/72 ,  C08G18/81 ,  C09D175/00 ,  C08F4/04 ,  C08F4/32 ,  C08F226/00

CPC classification number: C08G18/728 ,  C08F220/36

Abstract: Isocyanatoethyl methacrylate/acrylate (or other vinyl monomer) copolymers of controlled low molecular weight are produced by copolymerizing the monomers with initiators, usually peroxides, at temperatures above 120.degree. C. The copolymers are particularly useful as curing agents for urethane coating compositions.

Abstract translation: 通过在高于120℃的温度下将单体与引发剂（通常是过氧化物）共聚来制备控制低分子量的异氰酸酯乙酯/丙烯酸酯（或其它乙烯基单体）共聚物。该共聚物特别可用作聚氨酯涂料组合物的固化剂。

公开(公告)号：US6037414A

公开(公告)日：2000-03-14

申请号：US145656

申请日：1998-09-02

Applicant: John A. Simms ,  Aleksandr Sorser

Inventor： John A. Simms ,  Aleksandr Sorser

IPC: B01F17/42 ,  B01F17/52 ,  C08F8/44 ,  C08G20060101 ,  C08G59/32 ,  C08G59/40 ,  C08G59/42 ,  C08G81/02 ,  C09D17/00 ,  C09D163/00

CPC classification number: C08G81/027 ,  C09C1/56 ,  C01P2006/22

Abstract: A polymeric pigment dispersant of a graft polymer having an acrylic polymer backbone and pending from the backbone, polyester side chains, cyclic imide groups and quaternary ammonium groups and the polymer having a calculated number average molecular weight of 8,000-50,000; wherein the graft copolymer is composed of(a) 10-50%, by weight of the of the graft polymer, of an acrylic copolymer backbone having a number average molecular weight of 2500-10,000 which, before reaction, contains 25-75% by weight of polymerized oxirane containing monomers;(b) 20-85%, by weight of the graft polymer, of a polyester copolymer, or mixture of different polyester copolymers, having a number average molecular weight of 500-10,000 which polyester copolymer is carboxylic-acid functional and is attached to the backbone by a reaction of the carboxylic acid functional group with oxirane group of the backbone;(c) 1-16%, by weight of the graft polymer, of cyclic imide groups attached to the backbone by a reaction of the imide group with the oxirane group of the backbone and(d) 0.2-17%, by weight of the graft polymer, of quaternary ammonium groups.

Abstract translation: 具有丙烯酸聚合物主链并且可以从骨架，聚酯侧链，环状酰亚胺基团和季铵基团悬挂的接枝聚合物的聚合颜料分散剂，并且所述聚合物具有计算的数均分子量为8,000-50,000; 其中所述接枝共聚物由（a）10-50重量％的所述接枝聚合物的数均分子量为2500-10,000的丙烯酸共聚物主链组成，其在反应之前含有25-75％的 聚合环氧乙烷单体的重量; （b）接枝聚合物的20-85重量％的聚酯共聚物或不同聚酯共聚物的混合物，其数均分子量为500-10,000，该聚酯共聚物是羧酸官能的并且连接到 骨架通过羧酸官能团与骨架的环氧乙烷基团的反应; （c）接枝聚合物重量的1-16％，通过酰亚胺基团与主链的环氧乙烷基团的反应连接到主链上的环状酰亚胺基团，和（d）0.2-17％重量的 接枝聚合物，季铵基团。

公开(公告)号：US5286782A

公开(公告)日：1994-02-15

申请号：US937281

申请日：1992-08-31

Applicant: Douglas M. Lamb ,  John A. Simms

Inventor： Douglas M. Lamb ,  John A. Simms

IPC: C08F8/30 ,  C08G18/32 ,  C08G18/62 ,  C08G18/65 ,  C08L75/04

CPC classification number: C08G18/6511 ,  C08F8/30 ,  C08G18/3221 ,  C08G18/6229

Abstract: A coating composition primarily used as a clear coat of a clearcoat/color coat automotive finish; the composition has a film forming binder solids content of about 30-70% by weight contains about(A) 50-80% by weight, based on the weight of the binder, of an acrylic polymer of polymerized monomers of styrene, and two methacrylate monomers and a hydroxy alkyl methacrylate or acrylate each having 1-4 carbon atoms in the alkyl group and the polymer has a number average molecular weight of about 1,000-12,000 and a calculated Tg of at least 40.degree. C. and(B) 1-20% by weight, based on the weight of the binder, of a polyol component and(C) 10-49% by weight, based on the weight of the binder, of an organic polyisocyanate.

Abstract translation: 主要用作透明涂层/彩色涂层汽车漆的涂料组合物; 该组合物具有约30-70重量％的成膜粘合剂，固体含量为约（A）50-80重量％，基于粘合剂的重量，苯乙烯聚合单体的丙烯酸聚合物和两个甲基丙烯酸酯 单体和烷基中具有1-4个碳原子的羟基烷基甲基丙烯酸酯或丙烯酸酯，并且聚合物的数均分子量为约1,000-12,000，计算的Tg为至少40℃，（B）1- 20重量％，基于粘合剂的重量，多元醇组分和（C）10-49重量％，基于粘合剂重量的有机多异氰酸酯。

公开(公告)号：US4632964A

公开(公告)日：1986-12-30

申请号：US717160

申请日：1985-03-28

Applicant: Lili W. Altschuler ,  John A. Simms

Inventor： Lili W. Altschuler ,  John A. Simms

IPC: C08G18/42 ,  C09D175/06 ,  C08F283/04 ,  C08F20/00 ,  C08G18/38

CPC classification number: C08G18/4241 ,  C09D175/06

Abstract: A coating composition that forms a flexible finish and is used primarily as a clear finish over a colored or pigmented finish that are applied to flexible substrates of automobile and truck bodies; the composition contains as the film forming binder (1) a branched aliphatic polyester urethane which is the reaction product of a polyisocyanate and a branched aliphatic polyester and (2) preferably a methylated and butylated melamine formaldehyde crosslinking agent.

Abstract translation: 一种涂层组合物，其形成柔性光洁度，并且主要用作施加到汽车和卡车车身的柔性基底上的着色或着色涂层上的透明光洁度; 组合物含有成膜粘合剂（1）支链脂族聚酯氨基甲酸酯，它是多异氰酸酯和支链脂族聚酯的反应产物和（2）优选甲基化和丁基化的三聚氰胺甲醛交联剂。

公开(公告)号：US4255541A

公开(公告)日：1981-03-10

申请号：US87464

申请日：1979-10-19

Applicant: John A. Simms

Inventor： John A. Simms

IPC: C08F299/04 ,  C08G63/688 ,  C08F283/02 ,  C08G63/76 ,  C08L67/02

CPC classification number: C08G63/6888 ,  C08F299/04

Abstract: A graft copolymer having a polymeric backbone with pendent hydroxyl groups; wherein the hydrogen atom of at least the one the hydroxyl groups is replaced by the formula ##STR1## where R is an aliphatic group, a cycloaliphatic group or an aromatic group; R.sup.1 is an alkylene group having 2-6 carbon atoms; R.sup.2 is a polymer segment of a vinyl addition polymer, such as butyl acrylate/hydroxyethyl acrylate; coating compositions of this copolymer can be cross-linked with conventional cross-linking agents such as an alkylated melamine formaldehyde resin or an organic polyisocyanate and coating compositions useful for flexible elastomeric substrates can be prepared from this copolymer.