公开(公告)号：US08816029B2

公开(公告)日：2014-08-26

申请号：US13380267

申请日：2010-08-26

Applicant: Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

Inventor： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

IPC: C08F26/00 ,  C08F12/30 ,  C08F118/02 ,  A61K6/00

CPC classification number: C08F28/02 ,  A61K6/083 ,  C07D233/58 ,  C07D233/60 ,  C07D233/61 ,  C08F22/22 ,  C08F26/02 ,  C08K5/3445 ,  C09D4/06 ,  C09D133/066 ,  C09D139/00 ,  C09D141/00 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

Abstract: Presently described are curable compositions comprising a mixture of at least one (e.g. free-radically) polymerizable ionic liquid and at least one other ethylenically unsaturated monomer, oligomer, or polymer. The polymerizable ionic liquid is characterized as having an air to nitrogen curing exotherm ratio of at least 0.70. Also described are articles and methods of making articles from such curable compositions. A monofunctional polymerizable ionic liquid is also described comprising a non-polymerizable substituted imidazolium cationic group and a polymerizable sulfonate anion.

Abstract translation: 目前描述的是包含至少一种（例如自由基）可聚合离子液体和至少一种其它烯属不饱和单体，低聚物或聚合物的混合物的可固化组合物。 可聚合离子液体的特征在于具有至少0.70的空气至氮固化放热比。 还描述了从这种可固化组合物制备制品的制品和方法。 还描述了单官能可聚合离子液体，其包含不可聚合的取代的咪唑鎓阳离子基团和可聚合的磺酸根阴离子。

公开(公告)号：US08592034B2

公开(公告)日：2013-11-26

申请号：US12814553

申请日：2010-06-14

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski ,  Michael D. Determan

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski ,  Michael D. Determan

IPC: C09J7/02

CPC classification number: B32B37/06 ,  B29C61/0608 ,  B29C61/0616 ,  B29C61/0625 ,  B32B37/1284 ,  C09J7/24 ,  C09J2201/32 ,  C09J2205/302 ,  C09J2423/006 ,  C09J2433/00 ,  H05B3/36 ,  Y10T156/10 ,  Y10T428/24355 ,  Y10T428/24612 ,  Y10T428/28 ,  Y10T428/2813

Abstract: An adhesive article is described that is debondable from substrates or adherends with the application of heat.

Abstract translation: 描述了从施加热量的基底或被粘物脱粘的粘合剂制品。

公开(公告)号：US20120270040A1

公开(公告)日：2012-10-25

申请号：US13514143

申请日：2010-12-14

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski

IPC: B29C33/38 ,  B32B27/32

CPC classification number: C08J5/12 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C08J2323/04 ,  C08J2323/10 ,  C08J2323/16 ,  C09J5/00 ,  C09J165/00 ,  C09J2423/00 ,  C09J2423/006 ,  Y10T428/269

Abstract: A method of bonding at least two articles together, the method includes forming a mold, wherein the mold is formed at least in part from the articles; and depositing a curable composition in the mold, wherein the curable composition polymerizes through metathesis polymerization to form a molded polymer joint that bonds the two articles together; and the article formed thereby. An article that includes a first portion; a second portion; and a molded polymer joint, wherein the molded polymer joint bonds the first portion to the second portion, the molded polymer joint has a thickness of at least about 1.3 mm, the molded polymer joint includes a metathesis polymer, and both the first and second portions have different compositions than the molded polymer joint.

Abstract translation: 一种将至少两个制品粘合在一起的方法，所述方法包括形成模具，其中所述模具至少部分地从所述制品形成; 以及在所述模具中沉积可固化组合物，其中所述可固化组合物通过易位聚合聚合以形成将所述两个制品粘合在一起的模制聚合物接头; 并由此形成物品。 包括第一部分的物品; 第二部分; 和模制的聚合物接头，其中所述模制的聚合物接头将所述第一部分结合到所述第二部分，所述模制的聚合物接头具有至少约1.3mm的厚度，所述模制的聚合物接头包括易位聚合物，并且所述第一和第二部分 具有与模制的聚合物接头不同的组成。

公开(公告)号：US20120211119A1

公开(公告)日：2012-08-23

申请号：US13504532

申请日：2010-11-11

Applicant: Joseph D. Rule ,  Michael A. Kropp ,  Kevin M. Lewandowski

Inventor： Joseph D. Rule ,  Michael A. Kropp ,  Kevin M. Lewandowski

IPC: F16L9/22 ,  B23P11/00

CPC classification number: F16L21/00 ,  F16B1/0014 ,  F16B3/00 ,  F16L21/03 ,  F16L47/20 ,  Y10T29/49865 ,  Y10T29/49908

Abstract: Methods of joining pipe section and joined pipe assemblies are described. The pipe sections, e.g., pipes and couplers, are joined by a mechanical interference bond formed using a shape memory polymer key. The key can be inserted into a first keyway of one pipe section, the pipes fitted to align first keyway with a second keyway of the second pipe section, and the shape memory polymer activated to at least partially fill both keyways.

Abstract translation: 描述了连接管段和连接管组件的方法。 管道部分，例如管道和耦合器，通过使用形状记忆聚合物键形成的机械干涉结合。 钥匙可以插入到一个管段的第一键槽中，管道装配成将第一键槽与第二管段的第二键槽对齐，并且形状记忆聚合物被激活以至少部分地填充两个键槽。

公开(公告)号：US20120101184A1

公开(公告)日：2012-04-26

申请号：US13380267

申请日：2010-08-26

Applicant: Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

Inventor： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

IPC: C09D135/02 ,  C08F222/24 ,  C08F222/22 ,  C07C229/38 ,  C07D233/61 ,  C07C305/04 ,  C07C229/34 ,  C08F226/06 ,  C08F2/46

CPC classification number: C08F28/02 ,  A61K6/083 ,  C07D233/58 ,  C07D233/60 ,  C07D233/61 ,  C08F22/22 ,  C08F26/02 ,  C08K5/3445 ,  C09D4/06 ,  C09D133/066 ,  C09D139/00 ,  C09D141/00 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

Abstract: Presently described are curable compositions comprising a mixture of at least one (e.g. free-radically) polymerizable ionic liquid and at least one other ethylenically unsaturated monomer, oligomer, or polymer. The polymerizable ionic liquid is characterized as having an air to nitrogen curing exotherm ratio of at least 0.70. Also described are articles and methods of making articles from such curable compositions. A monofunctional polymerizable ionic liquid is also described comprising a non-polymerizable substituted imidazolium cationic group and a polymerizable sulfonate anion.

Abstract translation: 目前描述的是包含至少一种（例如自由基）可聚合离子液体和至少一种其它烯属不饱和单体，低聚物或聚合物的混合物的可固化组合物。 可聚合离子液体的特征在于具有至少0.70的空气至氮固化放热比。 还描述了从这种可固化组合物制备制品的制品和方法。 还描述了单官能可聚合离子液体，其包含不可聚合的取代的咪唑鎓阳离子基团和可聚合的磺酸根阴离子。

公开(公告)号：US20120017422A1

公开(公告)日：2012-01-26

申请号：US13260581

申请日：2010-04-07

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski ,  Jason D. Clapper

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski ,  Jason D. Clapper

IPC: F16B1/00 ,  B23P11/00

CPC classification number: F16B1/0014 ,  Y10T29/49865 ,  Y10T29/49954 ,  Y10T403/557

Abstract: Fasteners for producing double blind joints where the fastener is not visible or accessible are provided. The fasteners comprise a shape memory polymer that may be used to fasten workpieces by heating the fasteners, inducing recovery of the original, permanent shape of the fasteners

Abstract translation: 提供紧固件不可见或可接近的用于生产双盲接头的紧固件。 紧固件包括形状记忆聚合物，其可以用于通过加热紧固件来紧固工件，从而引起紧固件的原始永久形状的恢复

公开(公告)号：US07915436B2

公开(公告)日：2011-03-29

申请号：US12263704

申请日：2008-11-03

Applicant: Lisa S. Lim ,  Eumi Pyun ,  Joseph D. Rule

Inventor： Lisa S. Lim ,  Eumi Pyun ,  Joseph D. Rule

IPC: C07F9/02 ,  C08F283/00 ,  C08G77/04

CPC classification number: C07F9/4012 ,  C08G77/30 ,  C08L63/00 ,  C08L2666/14

Abstract: A phosphorus-containing silsesquioxane is represented by the formula [R13SiO1/2]m[R2SiO3/2]n[R3SiO3/2]p[(R4O)2PO(CH2)xSiO3/2]q wherein each of R1, R2, R3, and R4 independently represents a hydrocarbyl group; x represents an integer of from 1 to 8; m is a positive number less than 1.5; n and q are positive numbers greater than 0 and less than 1; and p is a number greater than or equal to 0 and less than 1. Further, (n+p)/q is in a range of from 0.5 to 99, and (n+p+q)=1. Curable and cured compositions comprising the phosphorus-containing silsesquioxane are disclosed.

Abstract translation: 含磷的倍半硅氧烷由式[R13SiO1 / 2] m [R2SiO3 / 2] n [R3SiO3 / 2] p [（R4O）2PO（CH2）xSiO3 / 2] q表示，其中R1，R2，R3， 并且R 4独立地表示烃基; x表示1〜8的整数， m是小于1.5的正数; n和q是大于0且小于1的正数; 并且p是大于或等于0且小于1的数字。此外，（n + p）/ q在0.5至99的范围内，并且（n + p + q）= 1。 公开了包含含磷倍半硅氧烷的可固化和固化的组合物。