公开(公告)号：US20140030609A1

公开(公告)日：2014-01-30

申请号：US14111451

申请日：2012-03-26

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Yuichi Kotou

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Yuichi Kotou

IPC: H01M10/0569 ,  H01M10/0525

CPC classification number: H01M10/0569 ,  H01G11/06 ,  H01G11/60 ,  H01G11/64 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/48 ,  H01M2200/20 ,  H01M2220/20 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

Abstract: The present invention is to provide a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the nonaqueous solvent includes 0.01 to 40% by volume of an ester having two alkyl groups at the α-position carbon of the carbonyl group and being represented by the following general formula (I), and an energy storage device. (in the above formula, R1 is an alkyl group, an alkenyl group or an alkynyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, R2 and R3 are an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, and R2 and R3 may be linked to each other to form a ring. However, when R2 and R3 do not form a ring, R3 is an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom.)

Abstract translation: 本发明提供一种通过将电解质盐溶解在非水溶剂中制备的非水电解液，其中非水溶剂包括0.01至40体积％的在羰基的α位碳上具有两个烷基的酯，和 由以下通式（I）表示，以及储能装置。 （在上式中，R 1是其中至少一个氢原子可以被卤素原子取代的烷基，烯基或炔基，R 2和R 3是烷基，其中至少一个 氢原子可以被卤素原子取代，R2和R3可以彼此连接形成环，但是当R2和R3不形成环时，R3是烷基，其中至少一个氢 原子可以被卤原子取代。）

公开(公告)号：US20120189919A1

公开(公告)日：2012-07-26

申请号：US13386841

申请日：2010-08-12

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Kazuyuki Kawabe

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Kazuyuki Kawabe

IPC: H01M10/056

CPC classification number: H01M10/052 ,  H01M4/505 ,  H01M4/52 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

Abstract: Disclosed are a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which contains a sulfonate compound having a specific structure in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and an electrochemical device containing the nonaqueous electrolytic solution. The nonaqueous electrolytic solution is excellent in the effect of improving the storage property of primary batteries and improving the cycle property of secondary batteries in use thereof at high temperatures and the low-temperature property thereof after high-temperature cycles.

Abstract translation: 公开了溶解在非水溶剂中的电解质盐的非水电解液，其含有非水电解液的0.01〜10质量％的特定结构的磺酸盐化合物，含有非水电解质的电化学装置 解。 非水电解液在高温下的一次电池的储存性提高，二次电池的循环性提高，高温循环后的低温性优异。

公开(公告)号：US08053109B2

公开(公告)日：2011-11-08

申请号：US12271045

申请日：2008-11-14

Applicant: Masato Iwanaga ,  Noriko Yamashita ,  Koji Abe ,  Kazuhiro Miyoshi

Inventor： Masato Iwanaga ,  Noriko Yamashita ,  Koji Abe ,  Kazuhiro Miyoshi

IPC: H01M6/04

CPC classification number: H01M10/0567 ,  H01M10/052

Abstract: A non-aqueous electrolyte secondary battery has a high initial capacity and excels in cycle characteristics and storage characteristics even when charged until the potential of the positive electrode active material exceeds as high as 4.3V versus lithium. The non-aqueous electrolyte of the secondary battery contains both 1,3-dioxane and a sulfonic acid ester compound.

Abstract translation: 非水电解质二次电池具有高的初始容量，并且即使在充电直到正极活性物质的电位比锂高达4.3V的电位时，其循环特性和存储特性也优异。 二次电池的非水电解质含有1,3-二恶烷和磺酸酯化合物。

公开(公告)号：US20110223490A1

公开(公告)日：2011-09-15

申请号：US13042543

申请日：2011-03-08

Applicant: Kazushi Andou ,  Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

Inventor： Kazushi Andou ,  Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC: H01M10/0564 ,  H01M10/056

CPC classification number: H01M10/0567 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0034 ,  H01M2300/0037 ,  H01M2300/004

Abstract: In the nonaqueous electrolyte secondary battery, the positive electrode active material is composed of a mixture of a lithium-cobalt composite oxide containing at least both zirconium and magnesium, and a lithium-manganese-nickel composite oxide containing at least both manganese and nickel. The nonaqueous electrolyte includes fluoroethylene carbonate and dimethyl carbonate as a nonaqueous solvent and further includes an additive expressed by General Formula (1), which having a capability to form an SEI surface film, and a higher oxidation resistance than that of VC. Thus, the negative electrode active material is unlikely to react with the organic solvent. Therefore, decomposition of the organic solvent is suppressed. Thus the battery having a long cycling life even when it is charged at a positive electrode charging potential of 4.4 to 4.6 V based on lithium and having a high residual capacity after storage at high temperature in a charged state is provided.

Abstract translation: 在非水电解质二次电池中，正极活性物质由至少含有锆和镁两者的锂 - 钴复合氧化物和至少含有锰和镍两者的锂 - 锰 - 镍复合氧化物的混合物构成。 非水电解质包括氟代碳酸亚乙酯和作为非水溶剂的碳酸二甲酯，并且还包括具有形成SEI表面膜的能力和比VC更高的抗氧化性的由通式（1）表示的添加剂。 因此，负极活性物质不可能与有机溶剂发生反应。 因此，有机溶剂的分解被抑制。 因此，电池具有长的循环寿命，即使在基于锂的正极充电电位为4.4〜4.6V下充电，并且在充电状态下在高温下保存后具有高剩余容量。

公开(公告)号：US20100291437A1

公开(公告)日：2010-11-18

申请号：US12740122

申请日：2008-10-24

Applicant: Koji Abe ,  Kazuhiro Miyoshi

Inventor： Koji Abe ,  Kazuhiro Miyoshi

IPC: H01M10/26 ,  C07C317/14

CPC classification number: H01M10/0567 ,  C07C309/65 ,  C07C309/66 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525 ,  H01M2300/004 ,  Y02T10/7011

Abstract: Provided are (1) a novel phenyl sulfonate compound, (2) a nonaqueous electrolytic solution comprising an electrolyte salt dissolved in a nonaqueous solvent and containing a phenyl sulfonate compound of the following general formula (II) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and (3) a lithium battery containing the nonaqueous electrolytic solution and excellent in low-temperature cycle property. (wherein X1 to X5 each independently represents a fluorine atom or a hydrogen atom, and from one to four of these are fluorine atoms; R2 represents a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkyl group having from 1 to 6 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or an aryl group having from 6 to 9 carbon atoms).

Abstract translation: 提供了（1）一种新的苯基磺酸盐化合物，（2）一种非水电解液，其包含溶解在非水溶剂中的电解质盐，并含有0.01至10％的下列通式（II）的苯基磺酸盐化合物： 的非水电解液，（3）含有非水电解液的锂电池，低温循环性优异。 （其中X1至X5各自独立地表示氟原子或氢原子，并且其中1至4个为氟原子; R2表示具有1至6个碳原子的直链或支链烷基，直链或支链烷基具有 1至6个碳原子，其中至少一个氢原子被卤素原子取代，或具有6至9个碳原子的芳基）。

公开(公告)号：US20080241704A1

公开(公告)日：2008-10-02

申请号：US10592702

申请日：2005-03-18

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC: H01M10/40

CPC classification number: H01M10/0567 ,  H01M4/1391 ,  H01M4/587 ,  H01M10/0525 ,  H01M2300/0025

Abstract: The present invention provides a lithium secondary battery having excellent battery characteristics such as battery cycling property, electrical capacity and storage property.The present invention relates to a nonaqueous electrolytic solution for lithium secondary batteries in which an electrolyte salt is dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution comprising a formic ester compound having a specific structure in an amount of 0.01 to 10% by weight of the nonaqueous electrolytic solution, and a lithium secondary battery using the same.

Abstract translation: 本发明提供具有优异的电池特性如锂电池循环特性，电容量和储存性能的锂二次电池。 本发明涉及一种锂二次电池的非水电解液，其中电解质盐溶解在非水溶剂中，该非水电解液包含具有特定结构的甲酸酯化合物，其量为0.01-10重量％ 非水电解液和使用其的锂二次电池。

公开(公告)号：US06673492B2

公开(公告)日：2004-01-06

申请号：US09861729

申请日：2001-05-21

Applicant: Shigeru Yao ,  Shyusei Ohya ,  Yukihiko Asano ,  Toshikazu Hamamoto ,  Kazuhiro Miyoshi

Inventor： Shigeru Yao ,  Shyusei Ohya ,  Yukihiko Asano ,  Toshikazu Hamamoto ,  Kazuhiro Miyoshi

IPC: H01M458

CPC classification number: H01M4/587 ,  H01M2004/021

Abstract: An electrode material for a secondary cell comprising as its essential component a powder of graphite having a crystallinity of 90% or more obtained by graphitizing a highly heat resistant polymer compact in an anaerobic atmosphere and crushing into a powder, and a process for the production of an electrode material for a secondary cell comprising heating and graphitizing a composition in which 0-10 wt % of a boron compound is added to a highly heat-resistant polymer to produce a powder of graphite having crystallinity of 90% or more contained as its essential component. An electrode material for a secondary cell having excellent charge/discharge cycle life and discharge voltage performance is provided.

Abstract translation: 一种二次电池用电极材料，其特征在于，将具有90％以上的结晶度的石墨粉末作为其主要成分，通过将耐高温聚合物成形体在无氧气氛中石墨化并粉碎成粉末而获得， 用于二次电池的电极材料包括加热和石墨化其中0-10重量％的硼化合物的组合物加入到高耐热性聚合物中以产生具有90％或更高结晶度的石墨粉末作为其基本要素 零件。 提供了具有优异的充放电循环寿命和放电电压性能的二次电池用电极材料。

公开(公告)号：US06413677B1

公开(公告)日：2002-07-02

申请号：US09466332

申请日：1999-12-17

Applicant: Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori ,  Kazuhiro Miyoshi ,  Akira Ueki

Inventor： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori ,  Kazuhiro Miyoshi ,  Akira Ueki

IPC: H01M1040

CPC classification number: H01M10/052 ,  H01M10/0567

Abstract: A lithium secondary battery electrolyte comprising a non-aqueous solvent and a lithium salt dissolved therein, said electrolyte containing at least one compound having the formula (I) or (II): wherein, R1 and R2 independently indicate, a C1 to C12 alkyl group, a C3 to C6 cycloalkyl group, or an aryl group, x indicates an oxygen atom or a sulfur atom, and n indicates an integer of 1 or 2; R3—S—M  (II) wherein, R3 indicates a C1 to C15 alkyl group or a C3 to C12 cycloalkyl group which may be substituted with at least one C1 to C4 alkyl group, a C7 to C15 benzyl group which may be substituted with at least one C1 to C4 alkyl group, or a C6 to C15 aryl group, which may be substituted with at least one C1 to C4 alkyl group, M indicates an alkali metal, and R3 may be substituted with at least one halogen atom; and a lithium secondary battery using the same.

Abstract translation: 包含溶解在其中的非水溶剂和锂盐的锂二次电池电解质，所述电解质含有至少一种具有式（I）或（II）的化合物：其中，R 1和R 2独立地表示C1-C12烷基 ，C3〜C6环烷基或芳基，x表示氧原子或硫原子，n表示1或2的整数;其中，R3表示C1〜C15烷基或C3〜C12环烷基 其可以被至少一个C 1至C 4烷基，可被至少一个C 1至C 4烷基取代的C 7至C 15苄基或C 6至C 15芳基取代，其可被至少一个 C1至C4烷基，M表示碱金属，R3可以被至少一个卤素原子取代; 和使用该二次电池的锂二次电池。

公开(公告)号：USD445823S1

公开(公告)日：2001-07-31

申请号：US29120952

申请日：2000-03-30

Applicant: Manabu Kawahara ,  Yoshihiro Tatara ,  Masahiko Kobayashi ,  Kazuhiro Miyoshi ,  Hiromi Shishiuchi ,  Keisuke Inoue ,  Takeo Kishida

Designer： Manabu Kawahara ,  Yoshihiro Tatara ,  Masahiko Kobayashi ,  Kazuhiro Miyoshi ,  Hiromi Shishiuchi ,  Keisuke Inoue ,  Takeo Kishida

公开(公告)号：USD441395S1

公开(公告)日：2001-05-01

申请号：US29120951

申请日：2000-03-30

Applicant: Manabu Kawahara ,  Yoshihiro Tatara ,  Masahiko Kobayashi ,  Kazuhiro Miyoshi ,  Hiromi Shishiuchi ,  Keisuki Inoue ,  Takeo Kishida

Designer： Manabu Kawahara ,  Yoshihiro Tatara ,  Masahiko Kobayashi ,  Kazuhiro Miyoshi ,  Hiromi Shishiuchi ,  Keisuki Inoue ,  Takeo Kishida