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公开(公告)号：US08519035B2
公开(公告)日：2013-08-27
申请号：US12676495
申请日：2008-09-03
申请人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
发明人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
IPC分类号： C08K5/49
CPC分类号： C08K5/50 , C08G79/06 , C08K5/0066 , C08L67/02 , C08L69/00 , C08L85/02 , C08L101/00 , C08L2666/22 , C08L85/00 , C08L2666/02 , C08L2666/18
摘要： The present invention is related to the use of specific cyclic and/or polymeric aryl-phosphines as flame retardants and to a method for reducing the flammability of organic material by incorporating into the material these specific cyclic and/or polymeric phosphines. Moreover, the invention is related to a polymeric composition containing a polymeric material and at least one of the specific cyclic and/or polymeric phosphines in an amount of from 1 to 15% by weight, based on the weight of the polymeric material. The invention also relates to a composition comprising at least one of the specific cyclic and/or polymeric phosphines and at least one polymerizable monomer.
摘要翻译： 本发明涉及特定的环状和/或聚合芳基膦作为阻燃剂的用途，以及通过将这些特定的环状和/或聚合膦掺入到材料中来降低有机材料的可燃性的方法。 此外，本发明涉及聚合物组合物，该聚合物组合物含有基于聚合物材料重量的1至15重量％的聚合物材料和至少一种特定环和/或聚合膦。 本发明还涉及包含至少一种特定的环和/或聚合膦和至少一种可聚合单体的组合物。
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公开(公告)号：US08053546B2
公开(公告)日：2011-11-08
申请号：US12601890
申请日：2008-06-06
IPC分类号： C08G65/04
CPC分类号： C08G59/686 , C08G59/4215 , C08J5/24
摘要： The use of 1,3-substituted imidazolium salts of the formula I in which R1 and R3 independently of one another are an organic radical having 1 to 20 C atoms, R2, R4, and R5 independently of one another are an H atom or an organic radical having 1 to 20 C atoms, it also being possible for R4 and R5 together to form an aliphatic or aromatic ring, X is an anion having a pKb of less than 13 (measured at 25° C., 1 bar in water or dimethyl sulfoxide), and n is 1, 2 or 3, with the exception as imidazolium salts of 1-ethyl-2,3-dimethylimidazolium acetate and 1-ethyl-2,3-dimethylimidazolium acetate-acetic acid complex, as latent catalysts for curing compositions comprising epoxy compounds.
摘要翻译： 其中R 1和R 3彼此独立地是具有1至20个C原子的有机基团，R 2，R 4和R 5彼此独立的式I的1,3-取代咪唑盐是H原子或 具有1至20个C原子的有机基团，R4和R5可以一起形成脂族或芳族环，X是pKb小于13的阴离子（在25℃下测量，在水中1巴或 二甲基亚砜），n为1,2或3，除了乙酸1-乙基-2,3-二甲基咪唑鎓和1-乙基-2,3-二甲基咪唑乙酸盐 - 乙酸络合物的咪唑鎓盐作为潜在催化剂 包含环氧化合物的固化组合物。
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公开(公告)号：US20110263764A1
公开(公告)日：2011-10-27
申请号：US12676495
申请日：2008-09-03
申请人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
发明人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
CPC分类号： C08K5/50 , C08G79/06 , C08K5/0066 , C08L67/02 , C08L69/00 , C08L85/02 , C08L101/00 , C08L2666/22 , C08L85/00 , C08L2666/02 , C08L2666/18
摘要： The present invention is related to the use of specific cyclic and/or polymeric aryl-phosphines as flame retardants and to a method for reducing the flammability of organic material by incorporating into the material these specific cyclic and/or polymeric phosphines. Moreover, the invention is related to a polymeric composition containing a polymeric material and at least one of the specific cyclic and/or polymeric phosphines in an amount of from 1 to 15% by weight, based on the weight of the polymeric material. The invention also relates to a composition comprising at least one of the specific cyclic and/or polymeric phosphines and at least one polymerizable monomer.
摘要翻译： 本发明涉及特定的环状和/或聚合芳基膦作为阻燃剂的用途，以及通过将这些特定的环状和/或聚合膦掺入到材料中来降低有机材料的可燃性的方法。 此外，本发明涉及聚合物组合物，该聚合物组合物含有基于聚合物材料重量的1至15重量％的聚合物材料和至少一种特定环和/或聚合膦。 本发明还涉及包含至少一种特定的环和/或聚合膦和至少一种可聚合单体的组合物。
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公开(公告)号：US20110065926A1
公开(公告)日：2011-03-17
申请号：US12951726
申请日：2010-11-22
申请人： Matthias Maase , Klemens Massonne , Laszlo Szarvas
发明人： Matthias Maase , Klemens Massonne , Laszlo Szarvas
IPC分类号： C07F5/02
CPC分类号： C07D233/56
摘要： In the process for preparing ionic liquids, an ionic liquid is firstly reacted with an alkoxide or with barium hydroxide and is subsequently neutralized with an acid. The ionic liquid contains a phosphonium and/or ammonium cation and an anion selected from the group consisting of halides, arylsulfonates, alkylsulfonates, sulfate, hydroxysulfate, alkylsulfates, hydrogencarbonate, carbonate. triflate and carboxylates. In this process, virtually any anions can be introduced into the ionic liquids.
摘要翻译： 在制备离子液体的过程中，首先使离子液体与醇盐或氢氧化钡反应，随后用酸中和。 离子液体含有鏻和/或铵阳离子和选自卤化物，芳基磺酸盐，烷基磺酸盐，硫酸盐，羟基硫酸盐，烷基硫酸盐，碳酸氢盐，碳酸盐的阴离子。 三氟甲磺酸酯和羧酸盐。 在这个过程中，几乎可以将任何阴离子引入到离子液体中。
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公开(公告)号：US07858802B2
公开(公告)日：2010-12-28
申请号：US10587248
申请日：2005-01-26
申请人： Matthias Maase , Klemens Massonne , Laszlo Szarvas
发明人： Matthias Maase , Klemens Massonne , Laszlo Szarvas
IPC分类号： C07D233/58 , C25B9/10 , H01G9/02
CPC分类号： C07D233/56
摘要： In the process for preparing ionic liquids, an ionic liquid is firstly reacted with an alkoxide or with barium hydroxide and is subsequently neutralized with an acid. The ionic liquid contains a phosphonium and/or ammonium cation and an anion selected from the group consisting of halides, arylsulfonates, alkylsulfonates, sulfate, hydroxysulfate, alkylsulfates, hydrogencarbonate, carbonate. triflate and carboxylates. In this process, virtually any anions can be introduced into the ionic liquids.
摘要翻译： 在制备离子液体的过程中，首先使离子液体与醇盐或氢氧化钡反应，随后用酸中和。 离子液体含有鏻和/或铵阳离子和选自卤化物，芳基磺酸盐，烷基磺酸盐，硫酸盐，羟基硫酸盐，烷基硫酸盐，碳酸氢盐，碳酸盐的阴离子。 三氟甲磺酸酯和羧酸盐。 在这个过程中，几乎可以将任何阴离子引入到离子液体中。
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公开(公告)号：US20100187715A1
公开(公告)日：2010-07-29
申请号：US12601890
申请日：2008-06-06
CPC分类号： C08G59/686 , C08G59/4215 , C08J5/24
摘要： The use of 1,3-substituted imidazolium salts of the formula I in which R1 and R3 independently of one another are an organic radical having 1 to 20 C atoms, R2, R4, and R5 independently of one another are an H atom or an organic radical having 1 to 20 C atoms, it also being possible for R4 and R5 together to form an aliphatic or aromatic ring, X is an anion having a pKb of less than 13 (measured at 25° C., 1 bar in water or dimethyl sulfoxide), and n is 1, 2 or 3, with the exception as imidazolium salts of 1-ethyl-2,3-dimethylimidazolium acetate and 1-ethyl-2,3-dimethylimidazolium acetate-acetic acid complex, as latent catalysts for curing compositions comprising epoxy compounds.
摘要翻译： 其中R 1和R 3彼此独立地是具有1至20个C原子的有机基团，R 2，R 4和R 5彼此独立的式I的1,3-取代咪唑盐是H原子或 具有1至20个C原子的有机基团，R4和R5可以一起形成脂族或芳族环，X是pKb小于13的阴离子（在25℃下测量，在水中1巴或 二甲基亚砜），n为1,2或3，除了乙酸1-乙基-2,3-二甲基咪唑鎓和1-乙基-2,3-二甲基咪唑乙酸盐 - 乙酸络合物的咪唑鎓盐作为潜在催化剂 包含环氧化合物的固化组合物。
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公开(公告)号：US07749318B2
公开(公告)日：2010-07-06
申请号：US11908969
申请日：2006-04-07
申请人： Matthias Maase , Veit Stegmann
发明人： Matthias Maase , Veit Stegmann
CPC分类号： C08B1/003 , C08J3/091 , C08J2301/02 , Y02P20/542 , Y10T428/2989
摘要： The present invention relates to a solution comprising cellulose and an ionic liquid comprising anions and cations as solvent, wherein the cations comprise at least one atom selected from the group consisting of nitrogen, oxygen, sulfur and phosphorus which is present in protonated form, its preparation and use for physical and chemical treatment.
摘要翻译： 本发明涉及包含纤维素和包含阴离子和阳离子作为溶剂的离子液体的溶液，其中阳离子包含至少一个选自以质子化形式存在的氮，氧，硫和磷的原子，其制备方法 并用于物理和化学处理。
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公开(公告)号：US20100137643A1
公开(公告)日：2010-06-03
申请号：US12598934
申请日：2008-05-07
申请人： Alexander Tishkov , Klemens Massonne , Daniela Mirk , Jochem Henkelmann , Matthias Maase , Thomas Wettling
发明人： Alexander Tishkov , Klemens Massonne , Daniela Mirk , Jochem Henkelmann , Matthias Maase , Thomas Wettling
IPC分类号： C07F9/02
CPC分类号： C07F9/5027
摘要： The present invention relates to a process for preparing cyclohexyl-substituted phosphines. The invention further relates to a process for preparing cyclohexyl-substituted phosphine oxides which can be used as intermediates in the preparation of cyclohexyl-substituted phosphines.
摘要翻译： 本发明涉及环己基取代的膦的制备方法。 本发明还涉及可用作制备环己基取代的膦的中间体的环己基取代的氧化膦的制备方法。
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公开(公告)号：US07511084B2
公开(公告)日：2009-03-31
申请号：US10502658
申请日：2003-02-04
申请人： Ralf Noe , Andreas Henne , Matthias Maase
发明人： Ralf Noe , Andreas Henne , Matthias Maase
IPC分类号： C08F2/46
CPC分类号： C07F9/3294 , C07F9/3252 , C07F9/34 , C07F9/36 , C07F9/4065 , C07F9/409 , C07F9/4093 , C07F9/4096 , C07F9/425 , G03F7/029
摘要： The invention relates to the acyl- and bisacylphosphine derivatives according to formula (I), wherein Y represents O, S, NR3, N—OR3 or N—NR3R4, Z represents O, S, NR3, N—OR3, N—NR3R4 or a free pair of electrons, and FG represents a leaving group and the remaining groups are defined as in the description. The invention further relates to a method for the production of the inventive derivatives and to their use.
摘要翻译： 本发明涉及式（I）的酰基和双酰基膦衍生物，其中Y代表O，S，NR3，N-OR3或N-NR3R4，Z代表O，S，NR3，N-OR3，N-NR3R4或 一对自由电子，FG表示离去基团，其余的基团如在说明书中所定义。 本发明还涉及本发明衍生物的制备方法及其用途。
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公开(公告)号：US20080190321A1
公开(公告)日：2008-08-14
申请号：US11908969
申请日：2006-04-07
申请人： Matthias Maase , Veit Stegmann
发明人： Matthias Maase , Veit Stegmann
IPC分类号： C08B1/00
CPC分类号： C08B1/003 , C08J3/091 , C08J2301/02 , Y02P20/542 , Y10T428/2989
摘要： The present invention relates to a solution comprising cellulose and an ionic liquid comprising anions and cations as solvent, wherein the cations comprise at least one atom selected from the group consisting of nitrogen, oxygen, sulfur and phosphorus which is present in protonated form, its preparation and use for physical and chemical treatment.
摘要翻译： 本发明涉及包含纤维素和包含阴离子和阳离子作为溶剂的离子液体的溶液，其中阳离子包含至少一个选自以质子化形式存在的氮，氧，硫和磷的原子，其制备方法 并用于物理和化学处理。
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