Polymerization of phosphaalkenes
    1.
    发明授权
    Polymerization of phosphaalkenes 失效
    磷杂环烯烃的聚合

    公开(公告)号:US07728091B2

    公开(公告)日:2010-06-01

    申请号:US10539397

    申请日:2003-12-16

    IPC分类号: C08F30/02

    CPC分类号: C08F220/18 C08G79/06

    摘要: Methods for polymerization of phosphaalkenes using initiators are provided. Also provided are polymers and co-polymers in which the polymer backbone contains tracts of carbon and phosphorous atoms in approximately equimolar amounts. C—P bonds in the polymers of this invention may be predominantly in a head-to-tail arrangement or mixed arrangements. Co-polymers may comprise polyolefin monomer units.

    摘要翻译: 提供了使用引发剂聚合亚磷酰烯的方法。 还提供聚合物和共聚物,其中聚合物主链含有近似等摩尔量的碳和磷原子。 本发明聚合物中的C-P键可以主要以头 - 尾排列或混合布置。 共聚物可以包含聚烯烃单体单元。

    Process for the manufacture of polycondensation products containing phosphorus, the products and their use as flameproofing agents
    2.
    发明授权
    Process for the manufacture of polycondensation products containing phosphorus, the products and their use as flameproofing agents 失效
    用于制造含磷的缩聚产物的方法,该产品及其用作防火剂

    公开(公告)号:US3907898A

    公开(公告)日:1975-09-23

    申请号:US39957673

    申请日:1973-09-21

    申请人: CIBA GEIGY AG

    摘要: The subject of the invention is a process for the manufacture of polycondensation products from hydroxymethylphosphonium compounds, characterised in that at least one anhydrous tetrakis(hydroxymethyl)-phosphonium salt or tetrakis(hydroxymethyl)phosphonium hydroxide is condensed with itself in an anhydrous medium, optionally using an acid catalyst and optionally in the presence of at least one inert organic solvent, at 100* to 150*C, preferably 120* to 150*C, the condensation being continued until 0.5 to 1.5 mols of water have been eliminated per 1 mol of phosphonium compound employed, free hydroxyl groups are, if appropriate, at least partially etherified with at least one alkanol with 1 to 4 carbon atoms, and that the salt of the polycondensation products are, where relevant, converted into the corresponding hydroxides. The polycondensation products are used for the flameproofing of organic fibre material, especially textiles. Appropriately, the procedure followed is that an aqueous preparation is applied to these materials which contains at least (1) a polycondensation product of the indicated type and (2) a polyfunctional compound, and that the material thus treated are dried and subjected to a heat treatment.

    摘要翻译: 本发明的主题是由羟甲基鏻化合物制造缩聚产物的方法,其特征在于至少一种无水四(羟甲基)鏻盐或四(羟甲基) - 鏻氢氧化物与自身在无水介质中冷凝, 任选地使用酸催化剂和任选地在至少一种惰性有机溶剂的存在下,在100-150℃,优选120-150℃下,继续进行缩合,直至每1次消除0.5至1.5摩尔的水 使用的鏻化合物的摩尔数,如果合适,游离羟基与至少一种具有1至4个碳原子的链烷醇至少部分醚化,并且缩聚产物的盐在相关时转化为相应的氢氧化物。