Acyl- and bisacylphosphine derivatives
    2.
    发明授权
    Acyl- and bisacylphosphine derivatives 有权
    酰基和双酰基膦衍生物

    公开(公告)号:US07511084B2

    公开(公告)日:2009-03-31

    申请号:US10502658

    申请日:2003-02-04

    IPC分类号: C08F2/46

    摘要: The invention relates to the acyl- and bisacylphosphine derivatives according to formula (I), wherein Y represents O, S, NR3, N—OR3 or N—NR3R4, Z represents O, S, NR3, N—OR3, N—NR3R4 or a free pair of electrons, and FG represents a leaving group and the remaining groups are defined as in the description. The invention further relates to a method for the production of the inventive derivatives and to their use.

    摘要翻译: 本发明涉及式(I)的酰基和双酰基膦衍生物,其中Y代表O,S,NR3,N-OR3或N-NR3R4,Z代表O,S,NR3,N-OR3,N-NR3R4或 一对自由电子,FG表示离去基团,其余的基团如在说明书中所定义。 本发明还涉及本发明衍生物的制备方法及其用途。

    Method for extracting impurities using ionic liquids
    7.
    发明授权
    Method for extracting impurities using ionic liquids 失效
    使用离子液体提取杂质的方法

    公开(公告)号:US07605297B2

    公开(公告)日:2009-10-20

    申请号:US10565187

    申请日:2004-07-03

    IPC分类号: A62D3/36

    CPC分类号: C07B63/00 Y02P20/542

    摘要: The invention relates to a process for the extractive removal of phenols, alcohols, amines, phoshines, hydroxylamines, hydrazines, oximes, imines, water, carboxylic acids, amino acids, hydroxamic acids, sulfinic acids, sulfonic acids, peroxycarboxylic acids, phosphonous acids, phosphinous acids, phosphonic acids, phosphinic acids or phosphoric acids from aprotic solvents by means of ionic liquids of the formula [K]n+[A]n−, where n, [K]+ and An− are defined as in the description.

    摘要翻译: 本发明涉及一种用于萃取去除酚,醇,胺,磷,羟胺,肼,肟,亚胺,水,羧酸,氨基酸,异羟肟酸,亚磺酸,磺酸,过氧羧酸,膦酸, 通过式[K] n + [A] n-,其中n,[K] +和An-的离子液体由非质子传递溶剂中的膦酸,次膦酸或次膦酸或磷酸定义如说明书中所定义。

    Method of preparing ionic liquids
    9.
    发明申请
    Method of preparing ionic liquids 失效
    离子液体的制备方法

    公开(公告)号:US20070142646A1

    公开(公告)日:2007-06-21

    申请号:US10587248

    申请日:2005-01-26

    IPC分类号: C07D233/02 C07D213/06

    CPC分类号: C07D233/56

    摘要: In the process for preparing ionic liquids, an ionic liquid is firstly reacted with an alkoxide or with barium hydroxide and is subsequently neutralized with an acid. The ionic liquid contains a phosphonium and/or ammonium cation and an anion selected from the group consisting of halides, arylsulfonates, alkylsulfonates, sulfate, hydroxysulfate, alkylsulfates, hydrogencarbonate, carbonate. triflate and carboxylates. In this process, virtually any anions can be introduced into the ionic liquids.

    摘要翻译: 在制备离子液体的过程中,首先使离子液体与醇盐或氢氧化钡反应,随后用酸中和。 离子液体含有鏻和/或铵阳离子和选自卤化物,芳基磺酸盐,烷基磺酸盐,硫酸盐,羟基硫酸盐,烷基硫酸盐,碳酸氢盐,碳酸盐的阴离子。 三氟甲磺酸酯和羧酸盐。 在这个过程中,几乎可以将任何阴离子引入到离子液体中。

    Method for producing n-phosphonomethyl iminodiacetic acid
    10.
    发明授权
    Method for producing n-phosphonomethyl iminodiacetic acid 失效
    n-膦酰基甲基亚氨基二乙酸的制备方法

    公开(公告)号:US07084298B2

    公开(公告)日:2006-08-01

    申请号:US10451740

    申请日:2002-01-11

    IPC分类号: C07F9/22 C07F9/28

    CPC分类号: C07F9/3808

    摘要: The present invention relates to a process for the preparation of N-phosphonomethyliminodiacetic acid by reacting an alkali metal salt of iminodiacetic acid with phosphorus trichloride in aqueous solution with formation of the hydrochloride of iminodiacetic acid, phosphorous acid and of the corresponding alkali metal chloride, followed by reaction with a formaldehyde source and, if desired, recovery of the N-phosphonomethyliminodiacetic acid from the reaction mixture, in which water, which may comprise HCl, is removed from the reaction mixture during and/or after reacting the alkali metal salt of iminodiacetic acid with phosphorus trichloride until the concentration of iminodiacetic acid hydrochloride is at least 40% by weight, based on the weight of the reaction mixture minus the weight of alkali metal chloride.The process makes possible the preparation of N-phosphonomethyliminodiacetic acid in a simple fashion and in high yield.

    摘要翻译: 本发明涉及一种通过将亚氨基二乙酸的碱金属盐与三氯化磷在水溶液中反应制备N-膦酰甲基亚氨基二乙酸的方法,形成亚氨基二乙酸,亚磷酸和相应的碱金属氯化物的盐酸盐,随后 通过与甲醛源反应,并且如果需要,从反应混合物中回收N-膦酰甲基亚氨基二乙酸,其中可以包含HCl的水在反应混合物中和/或之后反应亚氨基二乙酸的碱金属盐 酸与三氯化磷直到亚氨基二乙酸盐酸盐的浓度为至少40重量%,基于反应混合物的重量减去碱金属氯化物的重量。 该方法可以以简单的方式以高产率制备N-膦酰基甲基亚氨基二乙酸。