摘要:
The invention relates to the acyl- and bisacylphosphine derivatives according to formula (I), wherein Y represents O, S, NR3, N—OR3 or N—NR3R4, Z represents O, S, NR3, N—OR3, N—NR3R4 or a free pair of electrons, and FG represents a leaving group and the remaining groups are defined as in the description. The invention further relates to a method for the production of the inventive derivatives and to their use.
摘要翻译:本发明涉及式(I)的酰基和双酰基膦衍生物,其中Y代表O,S,NR 3,N-OR 3或N-NR 3, S 3 S 4 S 4,Z表示O,S,NR 3,N-OR 3,N-NR O 或者一对空电子,FG表示离去基团,其余的基团如说明书所定义。 本发明还涉及本发明衍生物的制备方法及其用途。
摘要:
The invention relates to the acyl- and bisacylphosphine derivatives according to formula (I), wherein Y represents O, S, NR3, N—OR3 or N—NR3R4, Z represents O, S, NR3, N—OR3, N—NR3R4 or a free pair of electrons, and FG represents a leaving group and the remaining groups are defined as in the description. The invention further relates to a method for the production of the inventive derivatives and to their use.
摘要:
Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.
摘要:
Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.
摘要:
A process for removing acids from reaction mixtures using an auxiliary base, in which the auxiliary base: combines with the acid to form a salt which is liquid at temperatures at which the product of value does not significantly decompose during the removal of the liquid salt, and the salt of the auxiliary base with the product of value or the solution of the product of value in a suitable solvent forms two immiscible liquid phases.
摘要:
Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.
摘要:
The invention relates to a process for the extractive removal of phenols, alcohols, amines, phoshines, hydroxylamines, hydrazines, oximes, imines, water, carboxylic acids, amino acids, hydroxamic acids, sulfinic acids, sulfonic acids, peroxycarboxylic acids, phosphonous acids, phosphinous acids, phosphonic acids, phosphinic acids or phosphoric acids from aprotic solvents by means of ionic liquids of the formula [K]n+[A]n−, where n, [K]+ and An− are defined as in the description.
摘要翻译:本发明涉及一种用于萃取去除酚,醇,胺,磷,羟胺,肼,肟,亚胺,水,羧酸,氨基酸,异羟肟酸,亚磺酸,磺酸,过氧羧酸,膦酸, 通过式[K] n + [A] n-,其中n,[K] +和An-的离子液体由非质子传递溶剂中的膦酸,次膦酸或次膦酸或磷酸定义如说明书中所定义。
摘要:
The present invention relates to a process for preparing quaternary ammonium compounds, which comprises reacting compounds comprising an sp3-hybridized nitrogen atom with a dialkyl sulfate or trialkyl phosphate and subjecting the resulting ammonium compound to an anion exchange.
摘要:
In the process for preparing ionic liquids, an ionic liquid is firstly reacted with an alkoxide or with barium hydroxide and is subsequently neutralized with an acid. The ionic liquid contains a phosphonium and/or ammonium cation and an anion selected from the group consisting of halides, arylsulfonates, alkylsulfonates, sulfate, hydroxysulfate, alkylsulfates, hydrogencarbonate, carbonate. triflate and carboxylates. In this process, virtually any anions can be introduced into the ionic liquids.
摘要:
The present invention relates to a process for the preparation of N-phosphonomethyliminodiacetic acid by reacting an alkali metal salt of iminodiacetic acid with phosphorus trichloride in aqueous solution with formation of the hydrochloride of iminodiacetic acid, phosphorous acid and of the corresponding alkali metal chloride, followed by reaction with a formaldehyde source and, if desired, recovery of the N-phosphonomethyliminodiacetic acid from the reaction mixture, in which water, which may comprise HCl, is removed from the reaction mixture during and/or after reacting the alkali metal salt of iminodiacetic acid with phosphorus trichloride until the concentration of iminodiacetic acid hydrochloride is at least 40% by weight, based on the weight of the reaction mixture minus the weight of alkali metal chloride.The process makes possible the preparation of N-phosphonomethyliminodiacetic acid in a simple fashion and in high yield.