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公开(公告)号：US20080286430A1
公开(公告)日：2008-11-20
申请号：US12221005
申请日：2008-07-30
CPC分类号： A21D2/08 , A23K30/00 , A23L3/3463 , A23L3/3499 , A23L3/3526 , A23L3/3544 , A23V2002/00 , C11B5/0092 , A23V2200/02
摘要： A combination of one or more compounds selected from the group consisting of 3-arylbenzofuranones, long chain N,N-dialkylhydroxylamines, substituted hydroxylamines, nitrones, and amine oxides are highly effective antioxidants for use with edible organic substances subject to deterioration by oxidation.
摘要翻译： 一种或多种选自3-芳基苯并呋喃酮，长链N，N-二烷基羟胺，取代羟胺，硝酮和氧化胺的化合物的组合是用于经受氧化劣化的可食用有机物质的高效抗氧化剂。
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公开(公告)号：US20060051478A1
公开(公告)日：2006-03-09
申请号：US10538891
申请日：2003-12-08
IPC分类号： A23D9/013
CPC分类号： A21D2/08 , A23K30/00 , A23L3/3463 , A23L3/3499 , A23L3/3526 , A23L3/3544 , A23V2002/00 , C11B5/0092 , A23V2200/02
摘要： A combination of one or more compounds selected from the group consisting of 3-arylbenzofuranones, long chain N,N-dialkylhydroxylamines, substituted hydroxylamines, nitrones, and amine oxides are highly effective antioxidants for use with edible organic substances subject to deterioration by oxidation.
摘要翻译： 一种或多种选自3-芳基苯并呋喃酮，长链N，N-二烷基羟胺，取代羟胺，硝酮和氧化胺的化合物的组合是用于经受氧化劣化的可食用有机物质的高效抗氧化剂。
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23.发明授权Composition and process for controlled radical polymerization using multifunctional initiator/regulator compounds 失效使用多功能引发剂/调节剂化合物控制自由基聚合的组成和方法公开(公告)号：US06573347B1
公开(公告)日：2003-06-03
申请号：US09461927
申请日：1999-12-15
IPC分类号： C08F404
CPC分类号： C08F2/38 , C08F4/00 , C08K5/34926
摘要： The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b1) at least one multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl and a free radical initiator or b2) at least one multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl-ether. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, the (co)polymers obtainable by this process and the use of multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyls in combination with a free radical initiator, or a multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl-ethers for controlled polymerization. In a particularly preferred embodiment at least one additional heating step at a temperature from 140 to 280° C. is applied after polymerization is completed.
摘要翻译： 本发明涉及一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b1）至少一种多官能三嗪基2,2,6,6四甲基哌啶-1-氧基和自由基引发剂或b2）至少一种多官能 三嗪基2,2,6,6四甲基哌啶-1-氧基醚。 本发明的其它方面是聚合烯键式不饱和单体的方法，可通过该方法获得的（共）聚合物和使用多官能三嗪基基2,2,6,6四甲基哌啶-1-氧基与自由基引发剂 ，或用于受控聚合的多官能三嗪基2,2,6,6四甲基哌啶-1-氧基醚。 在特别优选的实施方案中，在聚合完成后，施加140-180℃温度下的至少一个另外的加热步骤。
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24.发明授权Derivatives of 1-oxyl-4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers 失效1-氧基-4-氨基-2,2,6,6-四甲基哌啶的衍生物作为（甲基）丙烯酸酯单体的聚合抑制剂
公开(公告)号：US5928558A
公开(公告)日：1999-07-27
申请号：US65271
申请日：1998-04-23
IPC分类号： C07D211/94 , C09K15/30 , C09K3/00 , C07D211/58
CPC分类号： C09K15/30 , C07D211/94
摘要： Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-4-aminopiperidine are surprisingly effective as inhibitors to prevent the premature polymerization of acrylic and methacrylic acids, their esters, their amides, vinyl acetate and acrylonitrile in the presence of water.
摘要翻译： 1-氧基-2,2,6,6-四甲基-4-氨基哌啶的选择性衍生物在防止丙烯酸和甲基丙烯酸，其酯，它们的酰胺，乙酸乙烯酯和丙烯腈过早聚合的抑制剂中是有意义的， 水。
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公开(公告)号：US5877344A
公开(公告)日：1999-03-02
申请号：US876017
申请日：1997-06-13
申请人： Matthew E. Gande , Glen T. Cunkle , Leslie R. Gatechair , Stephen D. Pastor , Raymond Seltzer , Roland A.E. Winter
发明人： Matthew E. Gande , Glen T. Cunkle , Leslie R. Gatechair , Stephen D. Pastor , Raymond Seltzer , Roland A.E. Winter
IPC分类号： C07D211/94 , C07C51/50 , C07C57/07 , C07C57/075 , C07C67/62 , C07C69/54 , C07C253/32 , C07C255/08 , C07C69/52
CPC分类号： C07C253/32 , C07C51/50 , C07C67/62
摘要： Ethylenically unsaturated carboxyl monomers, such as acrylic or methacrylic acid or their esters, are protected from premature polymerization during manufacture and storage in the presence or absence of water by the incorporation therein of an effective stabilizing amount of a blend two or more nitroxides. Some of these blends provide synergistic stabilization efficacy much superior to the stabilization results obtained by use of either nitroxide alone.
摘要翻译： 乙烯基不饱和羧基单体如丙烯酸或甲基丙烯酸或其酯在制备和储存期间在水存在或不存在下通过其中加入有效稳定量的两种或更多种氮氧化物的混合物来防止过早聚合。 这些混合物中的一些提供了协同稳定效果，远优于单独使用硝基氧而获得的稳定结果。
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公开(公告)号：US5521237A
公开(公告)日：1996-05-28
申请号：US254203
申请日：1994-06-06
申请人： Raymond Seltzer , Wha Chen , Roswell E. King, III , Paul Odorisio , Rita Pitteloud , Sai P. Shum
发明人： Raymond Seltzer , Wha Chen , Roswell E. King, III , Paul Odorisio , Rita Pitteloud , Sai P. Shum
IPC分类号： C09K15/32 , C07B63/04 , C07F9/141 , C07F9/145 , C08K5/52 , C08K5/524 , C08K5/526 , C08L101/00 , C10M137/02 , C10M137/04 , C10N30/10
CPC分类号： C10M137/02 , C07B63/04 , C07F9/1411 , C07F9/145 , C08K5/526 , C10M2223/04 , C10M2223/042
摘要： Selected alkanolamine esters of acyclic phosphites are particularly effective as process stabilizers for polyolefins providing for melt flow stabilization and resistance to discoloration during said processing.
摘要翻译： 非极性亚磷酸酯的选择的链烷醇胺酯作为聚烯烃的工艺稳定剂是特别有效的，其提供熔融流动稳定性和在所述加工过程中耐变色性。
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27.发明授权Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions 失效用于稳定烯属不饱和化合物和稳定的单体组合物的方法
公开(公告)号：US5258138A
公开(公告)日：1993-11-02
申请号：US956436
申请日：1992-10-02
IPC分类号： C07C7/20 , C07C51/50 , C07C57/075 , C07C67/62 , C09K15/22 , C07C61/16 , C07C69/52 , C09K15/16
摘要： A process for stabilizing an ethylenically unsaturated monomer or oligomer from premature polymerization is disclosed whereby a stabilizing amount of an amine, preferably a substituted hindered amine, in combination with phenothiazine or other related heterocyclic moiety is added to said polymerizable monomer or oligomer. The ethylenically unsaturated monomer or oligomer encompass vinyl monomers or oligomers bearing at least one polymerizable moiety. The combination of substituted hindered amine plus phenothiazine inhibits premature polymerization in the liquid and/or vapor phase.
摘要翻译： 公开了一种从过早聚合中稳定烯属不饱和单体或低聚物的方法，其中将稳定量的胺，优选取代的受阻胺与吩噻嗪或其它相关杂环部分结合加入到所述可聚合单体或低聚物中。 烯键式不饱和单体或低聚物包含具有至少一个可聚合部分的乙烯基单体或低聚物。 取代的受阻胺加吩噻嗪的组合抑制液体和/或气相中的过早聚合。
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28.发明授权Peroxide free radical initiators containing hindered amine moieties with low basicity 失效含有碱度低的受阻胺部分的过氧化物自由基引发剂
公开(公告)号：US5051511A
公开(公告)日：1991-09-24
申请号：US479910
申请日：1990-02-14
IPC分类号： C07D211/46 , C07D211/94 , C08K5/3435
CPC分类号： C07D211/46 , C07D211/94 , C08K5/3435
摘要： Compounds which contain peroxide linkages as well as a hindered amine light stabilizer moiety of low basicity function as free radical polymerization initiators and provide a polymer containing a hindered amine stabilizer chemically bonded to said polymer. The low basicity of the instant compounds prevents interaction with acid catalysts used in some polymerization systems.
摘要翻译： 含有过氧化物键的化合物以及低碱度的受阻胺光稳定剂部分作为自由基聚合引发剂起作用并提供含有与所述聚合物化学结合的受阻胺稳定剂的聚合物。 本化合物的低碱度防止与一些聚合体系中使用的酸催化剂的相互作用。
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29.发明授权Stabilizers derived from N-hydroxy hindered amines by Michael addition reactions 失效通过迈克尔加成反应衍生自N-羟基受阻胺的稳定剂
公开(公告)号：US5015678A
公开(公告)日：1991-05-14
申请号：US480177
申请日：1990-02-14
IPC分类号： C07D211/94 , C07D401/12 , C07D401/14 , C07F9/59 , C08K5/3435 , C08K5/5373
CPC分类号： C07D401/14 , C07D211/94 , C07D401/12 , C07F9/591 , C08K5/3435 , C08K5/5373
摘要： The Michael addition products of N-hydroxy hindered amines with alpha,beta-unsaturated carbonyl compounds including derivatives of esters, amids, imides and anhydrides are effective stabilizers for protecting organic polymers from the deleterious effects of actinic light.
摘要翻译： N-羟基受阻胺与α，β-不饱和羰基化合物（包括酯，酰胺，酰亚胺和酸酐的衍生物）的迈克尔加成产物是保护有机聚合物免受光化光的有害影响的有效稳定剂。
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30.发明授权Alkylated N,N-dibenzylhydroxylamines and polyolefin compositions stabilized therewith 失效烷基化N，N-二苄基羟胺和用其稳定的聚烯烃组合物
公开(公告)号：US4703073A
公开(公告)日：1987-10-27
申请号：US908930
申请日：1986-09-15
IPC分类号： C08K5/32 , C08K5/3435 , C08K5/3462 , C08K5/17
CPC分类号： C08K5/3435 , C08K5/32 , C08K5/3462
摘要： Alkylated N,N-dibenzylhydroxylamine derivatives are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosyner-gists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.
摘要翻译： 烷基化的N，N-二苄基羟胺衍生物在稳定聚烯烃组合物中是有效的，所述聚烯烃组合物含有选自酚类抗氧化剂，受阻胺光稳定剂，烷基化羟基苯甲酸酯光稳定剂，紫外光吸收剂，有机磷 化合物，脂肪酸和硫代聚合物的碱金属盐，防止在高温挤出时的降解，暴露于天然气的燃烧产物，γ照射或长时间储存。
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