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    Process for producing polyester with metal phosphonic acid complex catalysts
    10.
    发明申请
    Process for producing polyester with metal phosphonic acid complex catalysts 审中-公开
    用金属膦酸配合物催化剂生产聚酯的方法

    公开(公告)号：US20080108779A1

    公开(公告)日：2008-05-08

    申请号：US11901478

    申请日：2007-09-17

    申请人： Stephen Andrews ,  Jianzhao Wang ,  Thomas Thompson ,  Paragkumar Thanki ,  Deepak Rane ,  Suhas Sahasrabudhe ,  Preetam Ghogale ,  Paul Odorisio ,  Si Wu

    发明人： Stephen Andrews ,  Jianzhao Wang ,  Thomas Thompson ,  Paragkumar Thanki ,  Deepak Rane ,  Suhas Sahasrabudhe ,  Preetam Ghogale ,  Paul Odorisio ,  Si Wu

    IPC分类号： C08G63/02

    CPC分类号： C08G63/84 ,  C08G63/183 ,  C08G63/189

    摘要： Disclosed is a method for the preparation of a polyester, which method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester, where a metal phosphonic acid complex compound of the formula is employed in the first step, in the second step or in both the first and second steps as a reaction catalyst; and wherein n is 0, 1, 2, 3, 4, 5 or 6; p is an integer from 1 to 30; M is a metal selected from the group consisting of Li, Na, K, Cs, Be, Ca, Mg, Sr, Ba, Al, Sb, Cd, Mn, Fe, Co, Ni, Cu and Zn; v is the valency of the metal M and is 1, 2 or 3; q is an integer from 1 to 20 where q=2p/v; and R1 is hydrogen, straight or branched chain alkyl of 1 to 36 carbon atoms, straight or branched chain alkenyl of 1 to 36 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or aryl of 6 to 10 carbon atoms; or is said alkyl, alkenyl, cycloalkyl or aryl substituted by one to four hydroxyl, halogen, straight or branched chain alkoxy of 1 to 8 carbon atoms, straight or branched chain alkyl of 1 to 8 carbon atoms or amino groups. The metal complex catalyst compound is in particular

    摘要翻译： 公开了一种制备聚酯的方法，该方法包括在第一步中，使二羧酸或C 1 -C 4 - 二羧酸二酯与二醇反应 合适的温度和压力以进行酯化或酯交换以制备预缩合物，并且在第二步中，使预缩合物在合适的温度和压力下进行缩聚以制备高分子量聚酯，其中式 在第一步，第二步或第一步和第二步都用作反应催化剂; 并且其中n为0,1,2,3,4,5或6; p是1至30的整数; M是选自Li，Na，K，Cs，Be，Ca，Mg，Sr，Ba，Al，Sb，Cd，Mn，Fe，Co，Ni，Cu和Zn中的金属; v是金属M的化合价，为1,2或3; q是1至20的整数，其中q = 2p / v; R 1是氢，1至36个碳原子的直链或支链烷基，1至36个碳原子的直链或支链烯基，5至8个碳原子的环烷基或6至10个芳基 碳原子 或被1至4个羟基，卤素，1至8个碳原子的直链或支链烷氧基，1至8个碳原子的直链或支链烷基或氨基取代的烷基，链烯基，环烷基或芳基取代。 特别是金属络合物催化剂化合物