公开(公告)号：US20090211945A1

公开(公告)日：2009-08-27

申请号：US12091327

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

IPC: B01J23/755 ,  B01J27/049 ,  C10G45/00

CPC classification number: B01J37/20 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/10 ,  C10G45/08 ,  C10G2300/202

Abstract: The invention relates to a bulk catalyst having improved activity in hydrodesulphurisation, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock.

Abstract translation: 本发明涉及具有改进的加氢脱硫活性的本体催化剂，特别是在VIB族金属摩尔比相对较低的第VIII族。 本体催化剂包含包含一种或多种VIB族金属和一种或多种VIII族金属的金属氧化物颗粒，该金属氧化物颗粒可通过包括以下步骤的方法获得，所述方法包括使包含一种或多种VIB族金属的化合物与包含一种或多种 反应温度高于质子液体沸点温度的水热条件下，优选在反应压力高于大气压的高压釜中。 本发明还涉及相应的硫化催化剂，制备所述本体催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。

公开(公告)号：US20090127165A1

公开(公告)日：2009-05-21

申请号：US12091322

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

IPC: C10G45/04 ,  B01J23/888

CPC classification number: B01J23/888 ,  B01J23/002 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/202 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/56

Abstract: The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.

Abstract translation: 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。