公开(公告)号：US20090139904A1

公开(公告)日：2009-06-04

申请号：US12091328

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

Inventor： Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

IPC: C10G45/04 ,  B01J23/883 ,  B01J23/882

CPC classification number: B01J23/88 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/8885 ,  B01J35/002 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  C10G45/12 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

Abstract: The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2θ. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5. The invention further relates to a process for the manufacture of the bulk catalyst, to the corresponding sulphided bulk catalyst and to the use of said catalyst or sulphided catalyst in the hydroprocessing, in particular the hydrodesulphurisation and hydrodenitrogenation, of a hydrocarbon feedstock.

Abstract translation: 本发明涉及一种本体催化剂，其包含至少60重量％的包含一种或多种第VIII族金属和VIB族金属钼的金属氧化物颗粒，其包含小于10摩尔％的第二族VIB金属（相对于VIB族的总量） 金属），并且包含少于10摩尔％（相对于第VIB族金属的总量）的第V族金属，该体积催化剂在低于六方晶系亚稳晶体结构变为不活泼的温度的温度下被煅烧 晶体结构，优选低于450℃，并且该体积催化剂具有亚稳态六方晶相，其特征在于具有在33-35和58-61°2θ之间的反射的X射线衍射图。 优选地，主反射具有小于2.5的半高宽（FWHM）。 本发明还涉及一种用于制造本体催化剂的方法，相应的硫化体积催化剂以及所述催化剂或硫化催化剂在烃原料的加氢处理，特别是加氢脱硫和加氢脱氮中的用途。

公开(公告)号：US08067331B2

公开(公告)日：2011-11-29

申请号：US12091322

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

IPC: C10G45/04

CPC classification number: B01J23/888 ,  B01J23/002 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/202 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/56

Abstract: The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.

Abstract translation: 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。

公开(公告)号：US08486259B2

公开(公告)日：2013-07-16

申请号：US12091328

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

Inventor： Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

IPC: C10G45/08 ,  B01J23/88

CPC classification number: B01J23/88 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/8885 ,  B01J35/002 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  C10G45/12 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

Abstract: The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2θ. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5. The invention further relates to a process for the manufacture of the bulk catalyst, to the corresponding sulphided bulk catalyst and to the use of said catalyst or sulphided catalyst in the hydroprocessing, in particular the hydrodesulphurisation and hydrodenitrogenation, of a hydrocarbon feedstock.

Abstract translation: 本发明涉及一种本体催化剂，其包含至少60重量％的包含一种或多种第VIII族金属和VIB族金属钼的金属氧化物颗粒，其包含小于10摩尔％的第二族VIB金属（相对于VIB族的总量） 金属），并且包含少于10摩尔％（相对于第VIB族金属的总量）的第V族金属，该体积催化剂在低于六方晶系亚稳晶体结构变为不活泼的温度的温度下被煅烧 晶体结构，优选低于450℃，并且该体积催化剂具有亚稳态六方晶相，其特征在于具有在33-35和58-61°2θ之间的反射的X射线衍射图。 优选地，主反射具有小于2.5的半高宽（FWHM）。 本发明还涉及一种用于制造本体催化剂的方法，相应的硫化体积催化剂以及所述催化剂或硫化催化剂在烃原料的加氢处理，特别是加氢脱硫和加氢脱氮中的用途。

公开(公告)号：US20120270728A1

公开(公告)日：2012-10-25

申请号：US13440619

申请日：2012-04-05

Applicant: Sona EIJSBOUTS-SPICKOVA ,  Jacobus Nicolaas LOUWEN ,  Frans L. PLANTENGA ,  Robertus Gerardus LELIVELD ,  Sabato MISEO ,  Stuart Leon SOLED

Inventor： Sona EIJSBOUTS-SPICKOVA ,  Jacobus Nicolaas LOUWEN ,  Frans L. PLANTENGA ,  Robertus Gerardus LELIVELD ,  Sabato MISEO ,  Stuart Leon SOLED

IPC: B01J23/88 ,  B01J23/16 ,  B01J23/882 ,  C10G45/08 ,  C07C7/12

CPC classification number: B01J23/88 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/8885 ,  B01J35/002 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  C10G45/12 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

Abstract: The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal and comprising a Group V metal in an amount less than 10 mole %, which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61 °2θ; and to a process for the manufacture of the bulk catalyst, to the corresponding sulphided bulk catalyst and to the use of said bulk catalyst or sulphided bulk catalyst in the hydroprocessing of a hydrocarbon feedstock.

Abstract translation: 本发明涉及一种本体催化剂，其包含至少60重量％的包含一种或多种第VIII族金属和VIB族金属钼的金属氧化物颗粒，其包含少于10摩尔％的第二族VIB金属，并且包含量为V 小于10摩尔％，该体积催化剂在低于六方晶系亚稳晶体结构变为无活性结晶结构的温度的温度下被煅烧，并且该体积催化剂具有亚稳态六方晶相，其特征在于具有反射的X射线衍射图 在33-35和58-61°2＆amp; 以及用于制造本体催化剂的方法，相应的硫化体积催化剂以及在烃原料的加氢处理中使用所述本体催化剂或硫化体积催化剂。

公开(公告)号：US20090127165A1

公开(公告)日：2009-05-21

申请号：US12091322

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

IPC: C10G45/04 ,  B01J23/888

CPC classification number: B01J23/888 ,  B01J23/002 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/202 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/56

Abstract: The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.

Abstract translation: 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。