公开(公告)号：US08067331B2

公开(公告)日：2011-11-29

申请号：US12091322

申请日：2006-10-25

申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

IPC分类号： C10G45/04

CPC分类号： B01J23/888 ,  B01J23/002 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/202 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/56

摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.

摘要翻译： 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。

公开(公告)号：US20090127165A1

公开(公告)日：2009-05-21

申请号：US12091322

申请日：2006-10-25

申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Marinus Bruce Cerfontain ,  Frans L. Plantenga ,  Eelco Titus Carel Vogt ,  Jacobus Nicolaas Louwen ,  Stuart Leon Soled ,  Sabato Miseo ,  Kenneth L. Riley

IPC分类号： C10G45/04 ,  B01J23/888

CPC分类号： B01J23/888 ,  B01J23/002 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/202 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/56

摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.

摘要翻译： 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。

公开(公告)号：US07964528B2

公开(公告)日：2011-06-21

申请号：US12091362

申请日：2006-10-25

申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

IPC分类号： C10G45/00

CPC分类号： B01J23/85 ,  B01J23/002 ,  B01J23/881 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/02 ,  C10G47/04 ,  C10G2300/202 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

摘要： The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VIII metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.

摘要翻译： 本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒，其包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族 金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成 氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。 本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

公开(公告)号：US08476184B2

公开(公告)日：2013-07-02

申请号：US12091679

申请日：2006-10-25

申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Bob Gerardus Oogjen ,  Marinus Bruce Cerfontain ,  Johannes Cornelis Sitters

发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Bob Gerardus Oogjen ,  Marinus Bruce Cerfontain ,  Johannes Cornelis Sitters

IPC分类号： C10G45/04

CPC分类号： B01J23/85 ,  B01J23/002 ,  B01J23/881 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/02 ,  C10G47/04 ,  C10G2300/202 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

摘要： The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition.

摘要翻译： 本发明涉及包含包含一种或多种VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒的本体催化剂组合物，该主体催化剂组合物包含包含一种或多种第一VIII族金属的第一金属氧化物颗粒和一种或多种第一族 VIB金属和单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属氧化物颗粒中的VIB族和第VIII族金属的组成不同，其中第一 和第二氧化体积颗粒 - 被分开成形以分离第一和第二成型体积催化剂颗粒，其优选组合成均匀的共混物以形成本体催化剂组合物。 本发明还涉及一种制备本体催化剂组合物的方法，并且使用本体催化剂组合物对烃进料进行加氢处理。

公开(公告)号：US20090014356A1

公开(公告)日：2009-01-15

申请号：US12091362

申请日：2006-10-25

申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

IPC分类号： C10G45/00

CPC分类号： B01J23/85 ,  B01J23/002 ,  B01J23/881 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/02 ,  C10G47/04 ,  C10G2300/202 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

摘要： The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VIII metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.

摘要翻译： 本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒，其包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族 金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成 氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。 本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

公开(公告)号：US07229548B2

公开(公告)日：2007-06-12

申请号：US10677697

申请日：2003-10-02

申请人： Kenneth L. Riley ,  Stuart L. Soled ,  Sabato Miseo ,  Frans L. Plantenga ,  Marinus Bruce Cerfontain ,  Sonja Eijsbouts ,  Eelko Brevoord

发明人： Kenneth L. Riley ,  Stuart L. Soled ,  Sabato Miseo ,  Frans L. Plantenga ,  Marinus Bruce Cerfontain ,  Sonja Eijsbouts ,  Eelko Brevoord

IPC分类号： C10G45/00 ,  C10G65/02

CPC分类号： C10G65/12 ,  B01J23/002 ,  B01J23/85 ,  B01J23/88 ,  B01J23/883 ,  B01J23/8878 ,  B01J23/888 ,  B01J23/8885 ,  B01J37/03 ,  B01J37/082 ,  C07C29/16 ,  C08F8/00 ,  C08F8/04 ,  C08F8/50 ,  C10G45/08 ,  C10G45/16 ,  C10G47/04 ,  C10G65/04 ,  C10G65/08 ,  C10G2400/10 ,  C10G2400/14 ,  C08F240/00

摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.

摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。

公开(公告)号：US06635599B1

公开(公告)日：2003-10-21

申请号：US09482811

申请日：2000-01-13

申请人： Sonja Eijsbouts ,  Bob Gerardus Oogjen ,  Hermannus Willem Homan Free ,  Marinus Bruce Cerfontain ,  Kenneth Lloyd Riley ,  Stuart Leon Soled ,  Sabato Miseo

发明人： Sonja Eijsbouts ,  Bob Gerardus Oogjen ,  Hermannus Willem Homan Free ,  Marinus Bruce Cerfontain ,  Kenneth Lloyd Riley ,  Stuart Leon Soled ,  Sabato Miseo

IPC分类号： B01J2300

CPC分类号： B01J23/8885 ,  B01J23/85 ,  B01J23/883 ,  B01J37/0009 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/082 ,  B01J37/20 ,  C10G45/08 ,  C10G49/04

摘要： The present invention relates to a process for the preparation of a hydroprocessing catalyst, to the catalyst composition obtainable by said process, and to the use of said catalyst composition in hydroprocessing applications. The process comprises the steps of combining and reacting at least one Group VIII non-noble metal component in solution and at least two Group VIB metal components in solution in a reaction mixture to obtain an oxygen-stable precipitate, and sulfiding the precipitate.

摘要翻译： 本发明涉及一种制备加氢处理催化剂的方法，可通过所述方法获得的催化剂组合物以及所述催化剂组合物在加氢处理应用中的用途。 该方法包括以下步骤：将至少一种溶液中的第VIII族非贵金属组分和至少两种VIB族金属组分混合并在反应混合物中溶解，得到氧稳定的沉淀物，并使沉淀物硫化。

公开(公告)号：US06534437B2

公开(公告)日：2003-03-18

申请号：US09836101

申请日：2001-04-17

申请人： Sonja Eijsbouts ,  Bob Gerardus Oogjen ,  Harmannus Willem Homan Free ,  Marinus Bruce Cerfontain ,  Kenneth Lloyd Riley ,  Stuart Leon Soled ,  Sabato Miseo

发明人： Sonja Eijsbouts ,  Bob Gerardus Oogjen ,  Harmannus Willem Homan Free ,  Marinus Bruce Cerfontain ,  Kenneth Lloyd Riley ,  Stuart Leon Soled ,  Sabato Miseo

IPC分类号： B01J27043

CPC分类号： B01J35/002 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/0053 ,  B01J35/008 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/20 ,  C10G49/04

摘要： The invention pertains to a process for preparing a catalyst composition comprising bulk catalyst particles comprising at least one Group VIII non-noble metal and at least two Group VIB metals. The process comprises combining and reacting at least one Group VIII non-noble metal component with at least two Group VIB metal components in the presence of a protic liquid, with at least one of the metal components remaining at least partly in the solid state during the entire process. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of said bulk catalyst particles, with the solubility of those of the metal components which are at least partly in the solid state during the reaction being less than 0.05 mol/100 ml water at 18° C. The invention also covers a catalyst composition made by that process and a process for the hydroprocessing of a hydrocarbon feedstock by contacting the feedstock with that catalyst at hydroprocessing conditions.

公开(公告)号：US06652738B2

公开(公告)日：2003-11-25

申请号：US10346018

申请日：2003-01-16

申请人： Sonja Eijsbouts ,  Bob Gerardus Oogjen ,  Harmannus Willem Homan Free ,  Marinus Bruce Cerfontain ,  Kenneth Lloyd Riley ,  Stuart Leon Soled ,  Sabato Miseo

发明人： Sonja Eijsbouts ,  Bob Gerardus Oogjen ,  Harmannus Willem Homan Free ,  Marinus Bruce Cerfontain ,  Kenneth Lloyd Riley ,  Stuart Leon Soled ,  Sabato Miseo

IPC分类号： C10G4504

CPC分类号： B01J35/002 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/0053 ,  B01J35/008 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/20 ,  C10G49/04

摘要： The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.

摘要翻译： 本发明涉及烃原料的加氢处理方法，其中所述原料在加氢处理条件下与催化剂组合物接触，所述催化剂组合物包含包含至少一种VIII族非贵金属和至少两种VIB族金属的本体催化剂颗粒。 VIII族和VIB族金属包含约50wt。 ％至约100重量％ 以体积催化剂颗粒的总重量计算的氧化物％。 金属以其氧化和/或硫化态存在于催化剂组合物中。 催化剂组合物具有X射线衍射图，其中当VIB族金属为钼，钨和任选的铬时，半峰的特征全宽度不超过2.5°，当VIB族VIB金属为不超过4.0°时 金属是钼和铬或钨和铬。

公开(公告)号：US20080308462A1

公开(公告)日：2008-12-18

申请号：US12091679

申请日：2006-10-25

申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardos Leliveld ,  Bob Gerardus Oogjen ,  Marinus Bruce Cerfontain ,  Johannes Cornelis Sitters

发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardos Leliveld ,  Bob Gerardus Oogjen ,  Marinus Bruce Cerfontain ,  Johannes Cornelis Sitters

IPC分类号： C10G45/04 ,  B01J23/24 ,  B01J23/652 ,  B01J23/85

CPC分类号： B01J23/85 ,  B01J23/002 ,  B01J23/881 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/02 ,  C10G47/04 ,  C10G2300/202 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

摘要： The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition.

摘要翻译： 本发明涉及包含包含一种或多种VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒的本体催化剂组合物，该主体催化剂组合物包含包含一种或多种第一VIII族金属的第一金属氧化物颗粒和一种或多种第一族 VIB金属和单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属氧化物颗粒中的VIB族和第VIII族金属的组成不同，其中第一 和第二氧化体积颗粒 - 被分开成形以分离第一和第二成型体积催化剂颗粒，其优选组合成均匀的共混物以形成本体催化剂组合物。 本发明还涉及一种制备本体催化剂组合物的方法，并且使用本体催化剂组合物对烃进料进行加氢处理。