HIGH ENERGY-DENSITY COMPOSITION-GRADIENT ELECTRODES AND METHODS OF MAKING THE SAME

    公开(公告)号:US20240088355A1

    公开(公告)日:2024-03-14

    申请号:US18233411

    申请日:2023-08-14

    Abstract: Embodiments described herein relate generally to devices, systems and methods of producing high energy density electrodes including a first electrode material disposed on a current collector and having a first porosity, and a second electrode material disposed on the first electrode material and having a second porosity less than the first porosity. In some embodiments, the second electrode material includes a mixture of an active material and a conductive material in a liquid electrolyte. In some embodiments, the first electrode materials can have a different composition than the second electrode material. In some embodiments, the first electrode material can include a high-capacity material such as tin, silicon antimony, aluminum, or titanium oxide. In some embodiments, a lithium-containing material can be disposed between the first electrode material and the second electrode material.

    APPARATUSES AND PROCESSES FOR FORMING A SEMI-SOLID ELECTRODE HAVING HIGH ACTIVE SOLIDS LOADING AND ELECTROCHEMICAL CELLS INCLUDING THE SAME

    公开(公告)号:US20230178707A1

    公开(公告)日:2023-06-08

    申请号:US17895229

    申请日:2022-08-25

    CPC classification number: H01M4/0433

    Abstract: Embodiments described herein relate generally to apparatuses and processes for forming semi-solid electrodes having high active solids loading by removing excess electrolyte. In some embodiments, the semi-solid electrode material can be formed by mixing an active material and, optionally, a conductive material in a liquid electrolyte to form a suspension. In some embodiments, the semi-solid electrode material can be disposed onto a current collector to form an intermediate electrode. In some embodiments, the semi-solid electrode material can have a first composition in which the ratio of electrolyte to active material is between about 10:1 and about 1:1. In some embodiments, a method for converting the semi-solid electrode material from the first composition into the second composition includes removing a portion of the electrolyte from the semi-solid electrode material. In some embodiments, the method includes mechanically compressing the intermediate electrode to remove the portion of electrolyte from the semi-solid electrode material.

    ELECTROCHEMICAL CELLS WITH SEPARATOR SEALS, AND METHODS OF MANUFACTURING THE SAME

    公开(公告)号:US20220263193A1

    公开(公告)日:2022-08-18

    申请号:US17729793

    申请日:2022-04-26

    Abstract: Embodiments described herein relate to electrochemical cells having a separator with a separator seal. In some embodiments, an electrochemical cell includes an anode disposed on an anode current collector, a cathode disposed on a cathode collector, a separator disposed between the anode and the cathode, and a separator seal coupled to the separator. The separator seal is impermeable to the movement of electroactive species therethrough. In some embodiments, the separator seal can include a tape and/or an adhesive. In some embodiments, the separator seal can include a material that permeates into pores of a portion of the separator. In some embodiments, the separator seal can be thermally bonded to the separator. In some embodiments, the electrochemical cell can include a pouch. In some embodiments the separator can be coupled to the pouch. In some embodiments, the separator seal can be coupled to the pouch.

    SEMI-SOLID ELECTRODES WITH CARBON ADDITIVES, AND METHODS OF MAKING THE SAME

    公开(公告)号:US20220093929A1

    公开(公告)日:2022-03-24

    申请号:US17484687

    申请日:2021-09-24

    Abstract: Embodiments described herein relate to semi-solid electrodes with carbon additives, and methods of making the same. In some embodiments, a semi-solid electrode, can include about 35% to about 75% by volume of an active material, about 0.5% to about 8% by volume of a conductive material, and about 0.2% to about 5% by volume of a carbon additive. The carbon additive is different from the conductive material. The active material, the conductive material, and the carbon additive are mixed with a non-aqueous electrolyte to form the semi-solid electrode. In some embodiments, the carbon additive includes carbon nanofibers, vapor-grown carbon fibers (VCGF), carbon nanotubes (CNT's), single-walled carbon nanotubes (SWNT's), and/or multi-walled carbon nanotubes (MWNT's). In some embodiments, the semi-solid electrode can have a yield stress of less than about 100 kPa.

    APPARATUSES AND PROCESSES FOR FORMING A SEMI-SOLID ELECTRODE HAVING HIGH ACTIVE SOLIDS LOADING AND ELECTROCHEMICAL CELLS INCLUDING THE SAME

    公开(公告)号:US20250054939A1

    公开(公告)日:2025-02-13

    申请号:US18818410

    申请日:2024-08-28

    Abstract: Embodiments described herein relate generally to apparatuses and processes for forming semi-solid electrodes having high active solids loading by removing excess electrolyte. In some embodiments, the semi-solid electrode material can be formed by mixing an active material and, optionally, a conductive material in a liquid electrolyte to form a suspension. In some embodiments, the semi-solid electrode material can be disposed onto a current collector to form an intermediate electrode. In some embodiments, the semi-solid electrode material can have a first composition in which the ratio of electrolyte to active material is between about 10:1 and about 1:1. In some embodiments, a method for converting the semi-solid electrode material from the first composition into the second composition includes removing a portion of the electrolyte from the semi-solid electrode material. In some embodiments, the method includes mechanically compressing the intermediate electrode to remove the portion of electrolyte from the semi-solid electrode material.

    ELECTROCHEMICAL CELLS WITH MULTIPLE SEPARATORS, AND METHODS OF PRODUCING THE SAME

    公开(公告)号:US20240372214A1

    公开(公告)日:2024-11-07

    申请号:US18777403

    申请日:2024-07-18

    Abstract: Embodiments described herein relate to electrochemical cells with multiple separators, and methods of producing the same. A method of producing an electrochemical cell can include disposing an anode material onto an anode current collector, disposing a first separator on the anode material, disposing a cathode material onto a cathode current collector, disposing a second separator onto the cathode material, and disposing the first separator on the second separator to form the electrochemical cell. The anode material and/or the cathode material can be a semi-solid electrode material including an active material, a conductive material, and a volume of liquid electrolyte. In some embodiments, less than about 10% by volume of the liquid electrolyte evaporates during the forming of the electrochemical cell. In some embodiments, the method can further include wetting the first separator and/or the second separator with an electrolyte solution prior to coupling the first separator to the second separator.

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