ELECTROCHEMICAL CELLS INCLUDING SELECTIVELY PERMEABLE MEMBRANE AND SEMI-SOLID ELECTRODES, AND METHOD OF MANUFACTURING THE SAME

    公开(公告)号:US20250046860A1

    公开(公告)日:2025-02-06

    申请号:US18794233

    申请日:2024-08-05

    Abstract: Embodiments described herein relate generally to electrochemical cells including a selectively permeable membrane and systems and methods for manufacturing the same. In some embodiments, the selectively permeable membrane can include a solid-state electrolyte material. In some embodiments, electrochemical cells can include a cathode disposed on a cathode current collector, an anode disposed on an anode current collector, and the selectively permeable membrane disposed therebetween. In some embodiments, the cathode and/or anode can include a slurry of an active material and a conductive material in a liquid electrolyte. In some embodiments, a catholyte can be different from an anolyte. In some embodiments, the catholyte can be optimized to improve the redox electrochemistry of the cathode and the anolyte can be optimized to improve the redox electrochemistry of the anode. In some embodiments, the selectively permeable membrane can be configured to isolate the catholyte from the anolyte.

    ELECTROCHEMICAL CELLS WITH MULTIPLE SEPARATORS, AND METHODS OF PRODUCING THE SAME

    公开(公告)号:US20240372214A1

    公开(公告)日:2024-11-07

    申请号:US18777403

    申请日:2024-07-18

    Abstract: Embodiments described herein relate to electrochemical cells with multiple separators, and methods of producing the same. A method of producing an electrochemical cell can include disposing an anode material onto an anode current collector, disposing a first separator on the anode material, disposing a cathode material onto a cathode current collector, disposing a second separator onto the cathode material, and disposing the first separator on the second separator to form the electrochemical cell. The anode material and/or the cathode material can be a semi-solid electrode material including an active material, a conductive material, and a volume of liquid electrolyte. In some embodiments, less than about 10% by volume of the liquid electrolyte evaporates during the forming of the electrochemical cell. In some embodiments, the method can further include wetting the first separator and/or the second separator with an electrolyte solution prior to coupling the first separator to the second separator.

    SEMI-SOLID ELECTRODES WITH CARBON ADDITIVES, AND METHODS OF MAKING THE SAME

    公开(公告)号:US20220093929A1

    公开(公告)日:2022-03-24

    申请号:US17484687

    申请日:2021-09-24

    Abstract: Embodiments described herein relate to semi-solid electrodes with carbon additives, and methods of making the same. In some embodiments, a semi-solid electrode, can include about 35% to about 75% by volume of an active material, about 0.5% to about 8% by volume of a conductive material, and about 0.2% to about 5% by volume of a carbon additive. The carbon additive is different from the conductive material. The active material, the conductive material, and the carbon additive are mixed with a non-aqueous electrolyte to form the semi-solid electrode. In some embodiments, the carbon additive includes carbon nanofibers, vapor-grown carbon fibers (VCGF), carbon nanotubes (CNT's), single-walled carbon nanotubes (SWNT's), and/or multi-walled carbon nanotubes (MWNT's). In some embodiments, the semi-solid electrode can have a yield stress of less than about 100 kPa.

    SEMI-SOLID ELECTRODES WITH GEL POLYMER ADDITIVE

    公开(公告)号:US20210376380A1

    公开(公告)日:2021-12-02

    申请号:US17173420

    申请日:2021-02-11

    Abstract: Embodiments described herein relate generally to electrochemical cells having semi-solid electrodes that include a gel polymer additive such that the electrodes demonstrate longer cycle life while significantly retaining the electronic performance of the electrodes and the electrochemical cells formed therefrom. In some embodiments, a semi-solid electrode can include about 20% to about 75% by volume of an active material, about 0.5% to about 25% by volume of a conductive material, and about 20% to about 70% by volume of an electrolyte. The electrolyte further includes about 0.01% to about 1.5% by weight of a polymer additive. In some embodiments, the electrolyte can include about 0.1% to about 0.7% of the polymer additive.

    ELECTROCHEMICAL CELLS WITH MULTIPLE SEPARATORS, AND METHODS OF PRODUCING THE SAME

    公开(公告)号:US20240372212A1

    公开(公告)日:2024-11-07

    申请号:US18777389

    申请日:2024-07-18

    Abstract: Embodiments described herein relate to electrochemical cells with multiple separators, and methods of producing the same. A method of producing an electrochemical cell can include disposing an anode material onto an anode current collector, disposing a first separator on the anode material, disposing a cathode material onto a cathode current collector, disposing a second separator onto the cathode material, and disposing the first separator on the second separator to form the electrochemical cell. The anode material and/or the cathode material can be a semi-solid electrode material including an active material, a conductive material, and a volume of liquid electrolyte. In some embodiments, less than about 10% by volume of the liquid electrolyte evaporates during the forming of the electrochemical cell. In some embodiments, the method can further include wetting the first separator and/or the second separator with an electrolyte solution prior to coupling the first separator to the second separator.

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