Abstract:
HEAT-CURABLE EPOXIDE RESIN MIXTUREES OF (1) A CYCLOALIPHATIC POLYGLYCIDYL COMPOUND WHICH POSSESSES AT LEAST ONE ALICYCLIC FIVE-MEMBERED OR SIX-MEMBERED RING, (2) A POLYCARBOXYLIC ACID ANHYDRIDE (0.2-1.1 ANHYDRIDE GROUPS PER 1 EQUIVALENT OF EPOXIDE GROUPS) AND (3) A POLYESTER CONTAINING TERMINAL CARBOXYL GROUPS AND/OR HYDROXYL GROUPS, WHICH IS OBTAINED BY ESTERIFICATION OF ALIPHATIC-CYCLOALIPHATIC HIGHER DICARBOXYLIC ACIDS (MANUFACTURED BY DIMERIZATION OF UNSATURATED MONOMERIC FATTY ACID WITH 14-24 CARBON ATOMS IN THE MOLECULE, PREFERABLY 16-18, AND OPTIONALLY SUBSEQUENT HYDROGENATION OF SUCH A DIMERIC FATTY ACID) WITH ALIPHATIC DIOLS (0.02-0.4 MOL OF POLYESTER PER 1 EQUIVALENT OF EPOXIDE GROUPS). THE CURING OF THE MIXTURE YIELDS FLEXIBLE, IMPACT-RESISTANT MOULDINGS THE PHYSICAL PROPERTIES OF WHICH SHOW LITTLE TEMPERATURE-DEPENDENCE, AND WHICH POSSESS HIGH FLEXIBILITY AT LOW TEMPERATURES.
Abstract:
CURABLE MIXTURES, WHICH ARE SUITABLE FOR THE MANUFACTURE OF SHAPED ARTICLES, COATINGS AND ADHESIVE BONDS, AND WHICH COMPRISE (A) A POLYEPOXIDE COMPOUND CONTAINING AT LEAST 2 EPOXIDE GROUPS, (B) AN UNSUBSTITUTED OR SUBSTITUTED N-GLYCIDYL- OR N-B-METHYLGLYCIDYL-OXAZOLIDIN-2-ONE COMPOUND, AND (C) A CURING AGENT FOR EPOXIDE RESINS, SUCH AS POLYAMINE OR A POLYCARBOXYLIC ANHYDRIDE.
Abstract:
EPOXIDE RESIN MIXTURES, WHICH ARE STORAGE-STABLE AND NONCRYSTALLISING AT ROOM TEMPERATURE, OF (A) DIGLYCIDYL ETHERS OF MONONUCLEAR, FIVE-MEMBERED OR SIX-MEMBERED, UNSUBSTITUTED OR SUBSTITUTED, OXYALKYLATED N-HETEROCYCLIC COMPOUNDS WHICH CONTAIN TWO NH GROUPS IN THE MOLECULE (FOR EXAMPLE 1,3-(2''-GLYCIDYLOXY-N-PROPYL)-5,5-DIMETHYL-HYDANTION) AND (B) POLYGYCIDYL COMPOUNDS OF THE N-HETEROCYCLIC SERIES, WHICH CONTAIN AT LEAST ONE HETEROCYCLIC RING WHICH POSSESSES THE GROUPING
-NH-CO-
AT LEAST ONCE, AND WHEREIN AT LEAST TWO GLYCIDYL GROUPS OR B-METHYLGLYCIDYL GROUPS IN THE POLYGLYCIDYL COMPOUNDS ARE DIRECTLY LINKED TO ENDOCYCLIC NITROGEN ATOMS (FOR EXAMPLE 1,3-DIGLYCIDYL-5,5-DIMETHYLHYDANTION). THESE EPOXIDE RESIN MIXTURES HAVE NOT BEEN SPECIFICALLY DESCRIBED IN THE MAIN PATENT.
Abstract:
NEW DIGLYCIDYL ETHERS OF MONONUCLEAR, FIVE-MEMBERED OR SIX-MEMBERED, UNSUBSTITUTED OR SUBSTITUTED, OXYALKYLATED N-HETEROCYCLIC COMPOUNDS WHICH CONTAIN TWO NHGROUPS IN THE MOLECULE, BY REACTION OF MONONUCLEAR, FIVEMEMBERED OR SIX-MEMBERED, UNSUBSTITUTED OR SUBSTITUTED N-HETEROCYCLIC COMPOUNDS, FOR EXAMPLE HYDANTOIN, BARBITURIC ACID, URACIL, DIHYDROURACIL, PARABANIC ACID AND THE CORRESPONDING DERIVATIVES, WITH ALKYLENE OXIDE, FOR EXAMPLE ETHYLENE OXIDE OR PROPYLENE OXIDE, TO GIVE MONOALCOHOLS OR DIALCOHOLS, AND SUBSEQUENT GLYCIDYLATION OF THE OH- GROUPS OR OF THE OH- AND NH- GROUP TO GIVE THE CORRESPONDING GLYCIDYL ETHERS. THE COMPOUNDS ARE RESIN PRESURSORS.
Abstract:
The new compound tri-( Beta -methylglycidyl)-isocyanurate is manufactured by a reaction, which is in itself known, of cyanuric acid with Beta -methylepichlorhydrin in the presence of tertiary amines or quaternary ammonium salts, and subsequent dehydrohalogenation with alkali. In comparison with the known tri-(glycidyl)-isocyanurate, tri-( Beta -methyglycidyl)isocyanurate can be more easily processed, on the one hand because of the lower melting point and on the other hand because of the lesser reactivity. Apart from compression moulding compositions, the material is therefore also excellently suited to being used as a casting resin. Suitable curing agents are above all polysebacic anhydride, and also aliphatic polyamines. Using the latter, it is surprisingly possible to manufacture a stable B-stage which is for example suitable for the manufacture of compression moulding compositions.