摘要:
Heat-curable epoxy resin compositions and the use thereof, for example, in motor vehicle construction and sandwich panel construction, are disclosed. Exemplary heat-curable epoxy resin compositions include, in addition to epoxy resin components A1, optionally A2, a hardener component B, a carboxylic acid C and a hydroxyalkylamide or hydroxyalkylurea H, an accelerator E for activation of the conversion of components A1, A2 and B. The compositions and the structural foams produced therefrom are notable for high mechanical strength, high glass strength and good adhesion capacity on metallic and nonmetallic substrates, and it is possible at the same time to dispense with the use of toxic or inflammable blowing agents.
摘要:
An epoxy resin composition is disclosed. The composition comprises a polyepoxide and a curing amount of a bis(hydrogen maleate) derivative of a polyoxypropylenediamine. This composition when cured produces unexpectedly superior encapsulations which are more flexible and less brittle than those of the prior art.
摘要:
A reactive hardenable binder composition based on(A) at least one aliphatic, cycloaliphatic or aliphatic-cycloaliphatic polyepoxide wherein at least 2 epoxidized cycloaliphatic radicals are bound via an aliphatic bridge,(B) at least one polycarboxylic acid unit of formula ##STR1## having an acid number between 30 and 400 whereinR.sup.1 is a radical of an at least oligomer product selected from the group consisting of polyesters and polymers having initially free OH-groups,R.sup.2 is a radical of a dicarboxylic carbocyclic acid having a COOH-group in ortho-position to its ester bond and(C) a catalyst component of the formula ##STR2## wherein R.sup.3 is a radical of a homo- or copolymer or combination of both of an unsaturated carboxylic acid with a statistically distributed number of COOH side groups or the radical of a polyester having initially free COOH-groups andMe is one equivalent of an alkaline or an alkaline earth metal, thus being present in its salt form, a process for the preparation of hardened products from said composition and a coated article having a coating based on said composition.
摘要:
A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I): wherein each R is independently H or CH2CH2CH2NH2; R1 is H, CH3CH2CH2N—, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.
摘要:
A method of preparing a shaped article having a photochromic coating thereon, and curable photochromic powder coating compositions are described. The method includes: applying at least one curable powder coating composition to at least a portion of the interior of a mold, e.g., a lens mold, wherein at least one of the applied powder coating compositions includes a photochromic amount of photochromic material; curing at least partially the applied photochromic powder coating; charging a polymerizable organic casting composition into the mold; polymerizing the casting composition; and removing a shaped article having a photochromic coating on at least a portion of its surface from the mold.
摘要:
An anhydride-cured epoxy resin (epoxy resin+anhydride curing agent+catalyst) may be fortified (i.e. increased in strength and modulus without being made brittle) by the addition of a carboxylic acid and the reaction product of a carboxylic acid anhydride and a substituted aromatic amine. Strengths as high as 125 MPa and moduli as high as 3500 MPa have been attained, as well as elongations up to 6% and an increase in the ability of the plastic to yield before fracture (ductility), compared to 80 MPa strength, 3000 MPa modulus and 2.4% elongation for the unfortified system (strengths and moduli are tensile).
摘要:
Novel thermosetting compositions, including a polyimide/N-vinylpyrrolidone prepolymer, optionally comprising an unsaturated polyester, and an epoxy resin, are well adapted for the molding of a variety of useful shaped articles.
摘要:
New imidyl-benzene-dicarboxylic and -tricarboxylic acid derivatives, in particular 5-maleimidyl-trimellitic acid derivatives and 3,5-bis-(maleimidyl)-phthalic acid derivatives, and a process for their manufacture are described. These imidyl-benzene-dicarboxylic and -tricarboxylic acid derivatives are suitable for the manufacture of crosslinkable polymers, above all polycondensation and polymerization products, which are distinguished by good processability and good solubility in customary organic solvents. Imidyl compounds, according to the definition, which have anhydride groups can also be used as curing agents for optionally modified epoxide resins.
摘要:
Resistance to thermal shock of certain anhydride cured epoxy resins is unexpectedly enhanced by addition of certain polyether diureide additives. This superior resistance does not appreciably compromise heat deflection properties. The resins comprise a vicinal polyepoxide, a curing amount of a certain bicyclic anhydride and an effective amount of a polyether diureide having terminal ureido groups and a molecular weight of from about 2,000 to about 3,000.