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1.发明授权Curable mixtures of diepoxy compounds,disecondary amines,and polyamines containing at least 3 active hydrogen atoms linked to nitrogen 失效含有至少三种连接氮的活性氢原子的二羟基化合物，异二胺和聚氨酯的可固化混合物
公开(公告)号：US3519603A
公开(公告)日：1970-07-07
申请号：US3519603D
申请日：1968-05-28
Applicant: CIBA LTD
Inventor： LOHSE FRIEDRICH , SCHMID ROLF , BATZER HANS
IPC: C08F4/68 , C08G59/50 , C08G65/322 , C08G65/333 , C08L63/00 , H01B3/40 , C08G30/08 , C08G30/14
CPC classification number: H01B3/40 , C08G59/5026 , C08G65/322 , C08G65/33372 , C08L63/00 , C08L2666/22
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2.发明授权Curable mixtures comprising a compound containing at least two beta-methylene-propiolactone groups and a cross-linking agent 失效包含至少两个β-亚甲基丙酸酯基团和交联剂的化合物的可固化混合物
公开(公告)号：US3442870A
公开(公告)日：1969-05-06
申请号：US42338765
申请日：1965-01-04
Applicant: CIBA LTD
Inventor： LOHSE FRIEDRICH , BATZER HANS
IPC: C08G63/08 , C08G67/00 , C08G17/017 , C08G17/02
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3.发明授权Storage stable heat-currable soluble and fusible precondenates based on polyepoxide compounds acid polyesters and anhydride curing agents 失效基于多环氧化合物的储存稳定的热可溶性可溶性和可食用的预聚物酸性聚酯和无机固化剂
公开(公告)号：US3642938A
公开(公告)日：1972-02-15
申请号：US3642938D
申请日：1969-08-04
Applicant: CIBA LTD
Inventor： SCHMID ROLF , LOHSE FRIEDRICH , FISCH WILLY , BATZER HANS
CPC classification number: H01B3/42 , C08G63/199 , C08L63/00 , C08L67/00 , H01B3/307 , H01B3/40 , C08L2666/18
Abstract: CURABLE B-STAGE FROM (1) A POLYEPOXIDE WITH AT LEAST ONE CARBOCYCLIC OR HETEROCYCLIC RING (FOR EXAMPLE ARALDIT CY 175, TRIGLYCIDYL ISOCYANURATE OR CASTING RESIN F), (2) A POLYESTER CONTAINING AT LEAST ONE CARBOCYCLIC OR HETEROCYCLIC RING, WITH TERMINAL CARBOXYL GROUPS, WITH THE RATIO OF THE TOTAL CHAIN MEMBERS ZG TO RING MEMBERS ZR HAVING TO BE 2 TO 13, AND WITH THE CHAIN POSSESSING 2-10 RECURRING STRUCTURAL ELEMENTS (FOR EXAMPLE POLYESTERS FROM PHTHALIC ANHYDRIDE AND ETHYLENE GLYCOL 11:10 OR FROM SUCCINIC ACID AND 1,1-BIS(HYDROXYMETHYL)-CYCLOHEXANE 5:4) IN AMOUNTS OF 0.2-0.8 EQUIVALENT PER 1 EPOXIDE EQUILVALENT, AND (3) A POLYCARBOXYLIC ACID ANHYDRIDE CONTAINING A CARBOCYCLIC RING (PHTHALIC ANHYDRIDE, HEXAHYDROPHTALIC ANHYDRIDE) IN AN AMOUNT OF 0.8-0.2 EQUIVALENT PER 1 EPOXIDE EQUIVALENT.
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公开(公告)号：US3557036A
公开(公告)日：1971-01-19
申请号：US3557036D
申请日：1969-06-30
Applicant: CIBA LTD
Inventor： SCHMID ROLF , LOHSE FRIEDRICH , FISCH WILLY , BATZER HANS
IPC: C07D303/44 , C08G59/24 , C08G63/199 , C08L63/00 , C08L67/00 , H01B3/30 , H01B3/40 , H01B3/42 , C08G17/18 , C08G30/12
CPC classification number: H01B3/42 , C07D303/44 , C08G59/24 , C08G63/199 , C08L63/00 , C08L67/00 , H01B3/307 , H01B3/40 , C08L2666/18
Abstract: HEAT-CURABLE EPOXIDE RESIN MIXTURES OF (1) A CYCLOALIPHATIC POLYEPOXIDE COMPOUND WHICH POSSESS AT LEAST ONE 1,2-EPOXIDE GROUP LOCATED ON A CARBOCYCLIC FIVEMEMBERED OR SIX-MEMBERED RING, (2) A POLYCARBOXYLIC ACID ANHYDRIDE (0.2-1.1 ANHYDRIDE GROUPS PER 1 EQUIVALENT OF EPOXIDE GROUPS) AND (3) A POLYESTER CONTAINING TERMINAL CARBOXYL AND/OR HYDROXYL GROUPS WHICH IS OBTAINED BY ESTERIFICATION OF ALIPHATIC-CYCLOALIPHATIC HIGHER DICARBOXYLIC ACIDS (MANUFACTURED BY DIMERIZATION OF UNSATURATED MONOMERIC FATTY ACID HAVING 14-24 CARBON ATOMS IN THE MOLECULE, PREFERABLY 16-18, AND OPTIONALLY SUBSEQUENT HYDROGENATION OF SUCH A DIMERIC FATTY ACID) WITH ALIPHATIC DIOLS (0.02-0.4 MOL OF POLYESTER PER 1 EQUIVALENT OF EPOXIDE GROUPS). THE CURING OF THE MIXTURES YIELDS FLEXIBLE, IMPACT-RESISTANT MOULDING, THE MECHANICAL PROPERTIES OF WHICH ARE LARGELY TEMPERATURE-INDEPENDENT.
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公开(公告)号：US3455949A
公开(公告)日：1969-07-15
申请号：US3455949D
申请日：1966-03-16
Applicant: CIBA LTD
Inventor： PORRET DANIEL , LOHSE FRIEDRICH , LEUMANN ERNST , NIKLES ERWIN , BATZER HANS
CPC classification number: C08G59/26 , C08G59/24 , C10M1/08 , C10M2215/086 , C10M2215/28 , C10N2240/08 , C10N2240/201 , C10N2240/202 , C10N2250/121
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Patent Agency Ranking6.发明授权Adducts containing epoxide groups from polyepoxide compounds and acid polyesters of aliphatic cycloaliphatic dicarboxylic acids 失效来自多环氧化合物的环氧化物组合物和脂环族二羧酸的酸性聚酯
公开(公告)号：US3642674A
公开(公告)日：1972-02-15
申请号：US3642674D
申请日：1969-06-10
Applicant: CIBA LTD
Inventor： SCHMID ROLF , LOHSE FRIEDRICH , FISCH WILLY , BATZER HANS
IPC: C08G59/00 , C08G59/12 , C08G63/00 , C08G63/199 , C08G63/91 , C08L63/00 , H01B3/30 , H01B3/40 , H01B3/42 , C08F21/04 , C08G17/16 , C08H9/00 , C09D3/64
CPC classification number: C08G63/199 , C08G59/12 , H01B3/307 , H01B3/40 , H01B3/42
Abstract: NEW ADDUCTS CONTAINING EPOXIDE GROUPS ARE FORMED WHEN (1) CYCLOALIPHATIC POLYEPOXIDE COMPOUNDS WHICH POSSES AT LEAST ONE 1,2-EPOXIDE GROUP LOCATED ON A CARBOCYCLIC FIVE-MEMBERED OR SIX-MEMBERED RNG, AND (2) ACID POLYESTERS, OBTAINED BY ESTERIFICATION WITH ALIPHATIC DIOLS, OF ALIPHATIC-CYCLOALIPHATIC HIGHER DICARBOXYLIC ACIDS (PREPARED BY DIMERIZATION OF UNSATURATED MEONOMERIC FATTY ACID HAVING 14 TO 24 CARBON ATOMS IN THE MOELCULE, PREFERABLY 16 TO 18, AND, IF DESIRED OR REQUIRED, SUBSEQUENT HYDROGENATION OF SUCH A DIMERIC FATTY ACID), ARE REACTED AT A ELEVATED TEMPERATURE TO FORM AN ADDUCT 0.1 TO 0.5 AN ELEVATED TEMPERATURE TO FORM AN ADDUCT 0.1 TO 0.5 CARBOXYL GROUP EQUIVALENTS OF THE ACID POLYESTER ARE USED PER 1 EPOXIDE GROUP EQUIVALENT OF THE POLYPOXIDE COMPOUND. CURING OF THESE ADVANCED EPOXIDE COMPOUNDS WITH CARBOXYLIC ACID ANHYDRIDES GIVES FLEXIBLE, IMPACT-RESITANT SHARPED BODIES THE MECHANICAL PROPERTIES OF WHICH ARE LARGELY INDEPENDENT OF THE TEMPERATURE.
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公开(公告)号：US3629226A
公开(公告)日：1971-12-21
申请号：US3629226D
申请日：1969-01-27
Applicant: CIBA LTD
Inventor： LOHSE FRIEDRICH , SCHMID ROLF , BATZER HANS
Abstract: COMPOSITION WHICH CAN BE CONVERTED TO RUBBER-ELASTIC PLASTIC PRODUCTS ON WARMING, CHARACTERISED IN THAT THEY CONTAIN LONG-CHAIN POLYESTER-POLYAMIDE-DICARBOXYLIC ACIDS OF FORMULA HO-(CO-R1-NH)N-CO-A-CO-(NH-R1-CO)B-OH WHEREINE R1 REPRESENT A BRANCHED OR UNBRANCHED ALKYLENE RESIUDE HAVING 2 TO 11 CARBON ATOMS IN THE LINAR CHAIN, PREFERABLY THE PENTAMETHYLENE RESIUDE, AND A AND B DENOTE ZERO OR AN INTER, WITH THE SUM (A+B) BEING AT LEAST 1 AND AT MOST 8, AND WHEREIN A DENOTES A BRANCHED OR UNBRANCHED HYDROCARBON CHAIN INTERRUPTED BY AT LEAST TWO ESTER GROUPS -O-COWHEREIN, IN THE STRUCTURAL UNIT OF THE POLYESTER RESIDUE A, THE NUMBER OF CARBON ATOMS IN HYDROCARBON RESIDUES DIVIDED BY THE NUMBER OF OXYGEN BRIDGES IS 3 TO 32, WHEREIN FURTHERMORE THE TOTAL NUMBER OF CARBON ATOMS PRESENT IN HYDROCARBON RESIDUES IN THE RESIUDE A IS AT LEAST 10, AND WHEREIN AT LEAST 1.0 AND A MOST 7.0 EQUIVALENTS OF AMIDE GROUPS PER KG. ARE PRESENT IN THE POLYESTER-POLYAMIDE-DICARBOXYLIC ACID MENTIONED, AND ALSO DIEPOXIDE COMPOUNDS, WITH 0.6 TO 1.2, PREFERABLY 0.8 TO 1.0, EQUIVALENTS OF CARBOXYL GROUPS BEING PRESENT PER 1 EQUIVALENT OF EPOXIDE GROUPS.
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公开(公告)号：US3624178A
公开(公告)日：1971-11-30
申请号：US3624178D
申请日：1970-02-03
Applicant: CIBA LTD
Inventor： LOHSE FRIEDRICH , PORRET DANIEL , FATZER WILLY
IPC: C07D303/16 , C07D303/22 , C07D303/24 , C07D303/34 , C08G18/10 , C08G18/28 , C08G59/22 , C08G59/28 , C08G59/30 , C08G45/00 , C08G22/00 , C08G45/12
CPC classification number: C07D303/22 , C07D303/16 , C07D303/24 , C07D303/34 , C08G18/10 , C08G18/2845 , C08G59/22 , C08G59/226 , C08G59/28 , C08G59/302
Abstract: WHERE N IS A WHOLE NUMBER, AT LEAST 2, PREFERABLY 2 OR 3, R stands for a n-valent aliphatic residue which may be interrupted by oxygen atoms and A represents the residue of a glycol or of a polyglycol whose terminal hydroxyl groups have been removed, and (2) the diglycidyl ether of a glycol or polyglycol.
An epoxy resin mixture containing (1) the polyepoxide of the formula-
公开(公告)号：US3558742A
公开(公告)日：1971-01-26
申请号：US3558742D
申请日：1968-08-30
Applicant: CIBA LTD
Inventor： SCHMID ROLF , LOHSE FRIEDRICH , BATZER HANS
Abstract: A CURABLE COMPOSITION WHICH CAN BE CONVERTED INTO CRYALLINE PLASTICS AT AN ELEVATED TEMPERATURE, CHARACTERIZED IN THAT IT CONTAINS LONG-CHAIN POLYAMIDE-DICARBOXYLIC ACIDS OF THE FORMULA
HOOC-A-COOH
WHERE A REPRESENTS A POLYAMIDE RESIDUE WHICH CONTAINS AT LEAST 2 CARBOXYLIC ACID AMIDE GROUPS AND IN WHICH BRANCHED OR LINEAR ALKYLENE AND/OR ALKENYLENE RESIDUE AL. TERNATE WITH THE CARBOXYLIC ACID AMIDE GROUPS, AS WELL AS DIEPOXY COMPOUNDS AND, IF DESIRED, ALSO ANTIOXIDANTS, AND IN WHICH FOR EVERY EPOXIDE GROUP EQUIVALENT 0.7 TO 1.2, PREFERABLY 0.9 TO 1.0 EQUIVALENT OF CARBOXYL GROUPS IS PRESENT.Abstract translation: 一种可在升高的温度下转化为结晶塑料的可固化组合物，其特征在于它含有式IN的长链聚酰胺 - 二羧酸，其中R1和R2各自为支链亚烷基，直链亚烷基， 支链亚烯基和直链亚烯基残基，a是至少2，优选2-10的整数，以及二环氧化合物，并且如果需要也是抗氧化剂，并且其中对于每个环氧基团当量为0.7-1.2，优选0.9至 存在1.1当量的羧基。
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10.发明授权High crystalline transition temperature elastomers from polyester polyurethanes 失效来自聚酯聚氨酯的高晶体转变温度弹性体
公开(公告)号：US3674746A
公开(公告)日：1972-07-04
申请号：US3674746D
申请日：1969-12-02
Applicant: CIBA LTD
Inventor： LOHSE FRIEDRICH , SCHMID ROLF , FISCH WILLY , BATZER HANS
CPC classification number: C08G18/6644 , C08G2250/00 , Y10S260/35
Abstract: Manufacture of high molecular, crosslinked crystalline polyadducts possessing urethane groups, from (a) linear succinic acid butane-1,4-diol polyesters possessing terminal hydroxyl groups and having an average molecular size of about 750 to about 5300, (b) as crosslinking agents, polyhydroxyl compounds containing at least 3 hydroxyl groups, preferably those having a hydroxyl equivalent weight of at most 300, e.g., 3-hydroxymethyl2,4-dihydroxypentane, and (c) diisocyanates, for example hexamethylene-diisocyanate 3,5,5-trimethyl-3-(isocyanato-methyl)cyclohexane-isocyanate-(1), 2,4-toluylene-diisocyanate or 2,6toluylene-diisocyanate, with 0.9 to 1.1 equivalents of isocyanate groups of the isocyanate being employed in each case per 1 equivalent of the total amount of hydroxyl groups of the two components (a) and (b).
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