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138 条记录 (耗时 0.019 秒)

    Preparation of aromatic oligomers
    6.
    发明授权
    Preparation of aromatic oligomers 失效
    芳族低聚物的制备

    公开(公告)号：US4879366A

    公开(公告)日：1989-11-07

    申请号：US296907

    申请日：1989-01-11

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C08G61/12 ,  C08G67/00

    CPC分类号： C08G67/00 ,  C08G61/127

    摘要： Aromatic oligomers, in particular arylene ketone and arylene sulfone oligomers, are prepared by reacting an appropriate monomer system in the presence of free Lewis acid and a complex between a Lewis acid, for example, aluminum trichloride, and a Lewis base, for example, N,N-dimethylformamide, and, optionally, a diluent, such as methylene chloride. The process is particularly advantageous for the preparation of substantially or all paralinked arylene ether ketone oligomers as the presence of the Lewis acid/Lewis base complex markedly reduces alkylation and ensures the substantial absence of ortho substitution. The monomer system can be, for example, a self-reacting monomer such as p-phenoxy-benzoyl chloride or a two-monomer system such as 1,4-diphenoxybenzene and terephthaloyl chloride.

    摘要翻译： 芳族低聚物，特别是亚芳基酮和亚芳基砜低聚物，通过使游离路易斯酸和路易斯酸例如三氯化铝与路易斯碱（例如N ，N-二甲基甲酰胺和任选的稀释剂，例如二氯甲烷。 由于路易斯酸/路易斯碱配合物的存在明显降低烷基化并确保基本上不存在邻位取代，所以该方法特别有利于制备基本上或全部分子链的亚芳基醚酮低聚物。 单体体系可以是例如对苯氧基苯甲酰氯等自身反应性单体，1,4-二苯氧基苯，对苯二甲酰氯等双系单体体系。

    Catalytic process for preparing polymers of sulfur dioxide and olefin
    7.
    发明授权
    Catalytic process for preparing polymers of sulfur dioxide and olefin 失效
    用于制备二氧化硫和烯烃聚合物的催化方法

    公开(公告)号：US4808697A

    公开(公告)日：1989-02-28

    申请号：US164161

    申请日：1988-03-03

    申请人： Eit Drent

    发明人： Eit Drent

    IPC分类号： C08G67/00 ,  C08G75/00 ,  C08G75/22 ,  C08G75/18

    CPC分类号： C08G75/22 ,  C08G67/00

    摘要： The invention is a process for preparing linear alternating polymers of sulfur dioxide, ethylene, optionally at least one ethylenically unsaturated hydrocarbon other than ethylene and optionally carbon monoxide having the general formula ##STR1## wherein Z is at least one moiety selected from SO.sub.2 and CO, G is the moiety of at least one ethylenically unsaturated hydrocarbon of at least 2 carbon atoms polymerized through the ethylenic unsaturation, n is an integer of at least 1, and m is an integer of zero or greater, which process comprises contacting sulfur dioxide, ethylene, optionally carbon monoxide, and optionally at least one ethylenically unsaturated hydrocarbon of at least 2 carbon atoms, in the presence of a catalyst obtained from (1) a compound of a Group VIII metal selected from palladium, cobalt and nickel, (2) a bidentate ligand of phosphorus, arsenic, or antimony, and (3) an anion of a non-hydrohalogenic acid having a pKa of less than 6.

    摘要翻译： 本发明是一种制备二氧化硫，乙烯，任选至少一种除乙烯以外的至少一种烯属不饱和烃和任选一种具有通式“IMAGE”的一氧化碳的线性交替聚合物的方法，其中Z是至少一个选自SO 2和CO的部分， G是通过烯属不饱和键聚合的至少一个至少2个碳原子的烯属不饱和烃的部分，n是至少为1的整数，m是零或更大的整数，该方法包括使二氧化硫，乙烯 ，任选的一氧化碳，以及任选的至少一种具有至少2个碳原子的烯属不饱和烃，在（1）选自钯，钴和镍的Ⅷ族金属的化合物的存在下，（2） 磷，砷或锑的双齿配体，和（3）pKa小于6的非氢卤酸的阴离子。

    Preparation of aromatic polymers
    8.
    发明授权
    Preparation of aromatic polymers 失效
    芳族聚合物的制备

    公开(公告)号：US4721771A

    公开(公告)日：1988-01-26

    申请号：US790030

    申请日：1985-10-22

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C07C45/46 ,  C08G61/12 ,  C08G67/00 ,  C08G75/20 ,  C08G2/00 ,  C08G4/00

    CPC分类号： C07C45/46 ,  C08G61/127 ,  C08G67/00 ,  C08G75/20

    摘要： Aromatic oligomers, in particular arylene ketone and arylene sulfone oligomers, are prepared by reacting an appropriate monomer system in the presence of free Lewis acid and a complex between a Lewis acid, for example, aluminum trichloride, and a Lewis base, for example, N,N-dimethylformamide, and, optionally, a diluent, such as methylene chloride. The process is particularly advantageous for the preparation of substantially or all paralinked arylene ether ketone oligomers as the presence of the Lewis acid/Lewis base complex markedly reduces alkylation and ensures the substantial absence of ortho substitution. The monomer system can be, for example, a self-reacting monomer such as p-phenoxy-benzoyl chloride or a two-monomer system such as 1,4-diphenoxybenzene and terephthaloyl chloride.

    摘要翻译： 芳族低聚物，特别是亚芳基酮和亚芳基砜低聚物，通过使游离路易斯酸和路易斯酸例如三氯化铝与路易斯碱（例如N ，N-二甲基甲酰胺和任选的稀释剂，例如二氯甲烷。 由于路易斯酸/路易斯碱配合物的存在明显降低烷基化并确保基本上不存在邻位取代，所以该方法特别有利于制备基本上或全部分子链的亚芳基醚酮低聚物。 单体体系可以是例如对苯氧基苯甲酰氯等自身反应性单体，1,4-二苯氧基苯，对苯二甲酰氯等双系单体体系。

    Preparation of aromatic polymers
    9.
    发明授权
    Preparation of aromatic polymers 失效
    芳族聚合物的制备

    公开(公告)号：US4709007A

    公开(公告)日：1987-11-24

    申请号：US922837

    申请日：1986-10-23

    申请人： Viktors Jansons ,  Heinrich C. Gors

    发明人： Viktors Jansons ,  Heinrich C. Gors

    IPC分类号： C08G61/12 ,  C08G67/00 ,  C08G8/02

    CPC分类号： C08G67/00 ,  C08G61/127

    摘要： A process for producing an aromatic polyketone which comprises polymerizing an appropriate monomer or monomers by a Friedel-Crafts polymerization reaction using a Lewis acid catalyst. A controlling agent such as a Lewis base may be added to the reaction medium and/or the reaction is conducted under specified conditions to control the reaction. The reaction medium comprises, for example, aluminum trichloride as the Lewis acid, an organic Lewis base such as N,N-dimethylformamide or an inorganic Lewis base such as sodium or lithium chloride, and a diluent such as methylene chloride or dichloroethane. The amount of Lewis acid, the amount of Lewis base, the temperature of the reaction and the monomer to diluent molar ratio are varied depending on the monomer system to obtain melt-processable, high molecular weight, substantially linear polymers, for example poly(carbonyl-p-phenylene-oxy-p-phenylene), poly(carbonyl-p-phenylene-oxy-p-phenylene-oxy-p-phenylene), and the like. Copolymers containing up to 30% by weight of an aromatic sulfonyl halide comonomer can also advantageously be produced by this process.

    摘要翻译： 一种制备芳族聚酮的方法，其包括使用路易斯酸催化剂通过弗瑞德 - 克来福特聚合反应聚合合适的单体或单体。 可以将控制剂如路易斯碱加入到反应介质中和/或反应在特定条件下进行以控制反应。 反应介质包括例如三氯化铝作为路易斯酸，有机路易斯碱如N，N-二甲基甲酰胺或无机路易斯碱如钠或氯化锂，以及稀释剂如二氯甲烷或二氯乙烷。 路易斯酸的量，路易斯碱的量，反应温度和单体与稀释剂的摩尔比取决于单体体系而变化，以获得可熔融加工的高分子量基本上线性的聚合物，例如聚（羰基 对 - 亚苯基 - 氧 - 对亚苯基），聚（羰基 - 对 - 亚苯基 - 氧 - 对亚苯基 - 氧 - 对 - 亚苯基）等。 含有高达30重量％芳族磺酰卤共聚单体的共聚物也可以通过该方法有利地产生。

    Preparing poly (arylene ketone) with liquefaction agent treatment
    10.
    发明授权
    Preparing poly (arylene ketone) with liquefaction agent treatment 失效
    用液化剂处理制备聚（亚芳基酮）

    公开(公告)号：US4665151A

    公开(公告)日：1987-05-12

    申请号：US659744

    申请日：1984-10-11

    申请人： Robert H. Reamey

    发明人： Robert H. Reamey

    IPC分类号： C08G61/12 ,  C08G67/00 ,  C08G85/00 ,  C08G65/38

    CPC分类号： C08G61/127 ,  C08G67/00

    摘要： The preparation of poly(arylene ketones) and in particular all para-linked poly(arylene ether ketones) by Friedel-Crafts polymerization in the presence of a Lewis acid generally results in an intractible reaction product difficult to remove from the reaction vessel and difficult to purify. The addition of a liquefaction agent, such as a hydrogen halide and in particular hydrogen chloride, to the reaction mixture, results in a tractible gel or a liquid which can be readily handled. The hydrogen halide is preferably under pressure and a diluent may also be added along with the hydrogen halide.

    摘要翻译： 在路易斯酸存在下，通过Friedel-Crafts聚合制备聚（亚芳基酮），特别是所有对位聚（亚芳基醚酮）通常导致难以从反应容器中除去的难处理的反应产物， 净化。 向反应混合物中加入液化剂，例如卤化氢，特别是氯化氢，产生易于处理的可溶性凝胶或液体。 卤化氢优选在压力下，稀释剂也可与卤化氢一起加入。