公开(公告)号：US20210175542A1

公开(公告)日：2021-06-10

申请号：US17115235

申请日：2020-12-08

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Qing Wang ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M10/0562 ,  H01M10/052 ,  H01M4/139 ,  H01M4/62 ,  H01M4/38 ,  H01M4/04

Abstract: A lithium-sulfur battery includes: a substrate; a composite cathode disposed on the substrate; a solid-state electrolyte disposed on the composite cathode; and a lithium anode disposed on the solid-state electrolyte, such that the composite cathode comprises: active elemental sulfur, conductive carbon, and sulfide electrolyte, and the sulfide electrolyte is uniformly coated on at least one surface of the conductive carbon. A method of forming a composite cathode for a lithium-sulfur battery includes: synthesizing dispersed carbon fiber from cotton to form carbonized dispersed cotton fiber (CDCF) powder; in-situ coating of the CDCF with an electrolyte component to form a composite powder; and mixing active elemental sulfur powder with the composite powder to form the composite cathode.

公开(公告)号：US20150118582A1

公开(公告)日：2015-04-30

申请号：US14517105

申请日：2014-10-17

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Chen Shen ,  Yanming Cui ,  Zhaoyin Wen

IPC: H01M4/86 ,  H01M12/02 ,  H01M4/88 ,  H01M12/00

CPC classification number: H01M4/8605 ,  H01M4/8875 ,  H01M4/9041 ,  H01M4/92 ,  H01M12/08 ,  Y02E60/128

Abstract: A cathode current collector for a lithium-air battery includes a carbon-free, conductive, porous matrix. The matrix may include a metal boride, a metal carbide, a metal nitride, a metal oxide and/or a metal halide. Example matrix materials are antimony-doped tin oxide and titanium oxide. A carbon-free cathode exhibits improved mechanical and electrochemical properties including improved cycle life relative to conventional carbon-containing porous cathode current collectors.

Abstract translation: 用于锂空气电池的阴极集电器包括无碳导电多孔基体。 基质可以包括金属硼化物，金属碳化物，金属氮化物，金属氧化物和/或金属卤化物。 示例性基质材料是锑掺杂的氧化锡和氧化钛。 相对于常规的含碳多孔阴极集电体，无碳阴极表现出改善的机械和电化学性能，包括改善的循环寿命。

公开(公告)号：US12074282B2

公开(公告)日：2024-08-27

申请号：US18225927

申请日：2023-07-25

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Yinghong Chen ,  Xiao Huang ,  Cai Liu ,  Xinyuan Liu ,  Yanxia Ann Lu ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Nathan Michael Zink

IPC: H01M10/0562 ,  C04B35/01 ,  C04B35/48 ,  C04B35/486 ,  C04B35/488 ,  C04B35/495 ,  C04B35/626 ,  C04B35/64 ,  H01M10/052

CPC classification number: H01M10/0562 ,  C04B35/01 ,  C04B35/481 ,  C04B35/486 ,  C04B35/488 ,  C04B35/495 ,  C04B35/62605 ,  C04B35/6261 ,  C04B35/6262 ,  C04B35/64 ,  H01M10/052 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3244 ,  C04B2235/5436 ,  C04B2235/602 ,  C04B2235/6025 ,  C04B2235/764 ,  C04B2235/77 ,  C04B2235/786 ,  C04B2235/79 ,  C04B2235/85 ,  C04B2235/96

Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.

公开(公告)号：US20240038984A1

公开(公告)日：2024-02-01

申请号：US18330767

申请日：2023-06-07

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Liu Yao

IPC: H01M4/525 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0568 ,  H01M4/505 ,  H01M4/58 ,  H01M4/36

CPC classification number: H01M4/525 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0568 ,  H01M4/505 ,  H01M4/58 ,  H01M4/366

Abstract: A composition includes a first portion including Ni-rich LiNixCoyMnzO2, where 0.5

公开(公告)号：US11858854B2

公开(公告)日：2024-01-02

申请号：US17308646

申请日：2021-05-05

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu ,  Chujun Zheng

IPC: C04B35/48 ,  C04B35/465 ,  H01M10/0525 ,  H01M10/0562

CPC classification number: C04B35/48 ,  C04B35/465 ,  H01M10/0525 ,  H01M10/0562 ,  C04B2235/764 ,  C04B2235/77 ,  H01M2300/0077

Abstract: A sintered composite ceramic includes: a lithium-garnet major phase; and a lithium-rich minor phase, such that the lithium-rich minor phase has LixTiO(x+4)/2, with 0.66≤x≤4. The sintered composite ceramic may exhibit a relative density of at least 90% of a theoretical maximum density of the ceramic, an ionic conductivity of at least 0.35 mS·cm−1, or a critical current density (CCD) of at least 1.0 mA·cm−2.

公开(公告)号：US20230118975A1

公开(公告)日：2023-04-20

申请号：US17967338

申请日：2022-10-17

Applicant: CORNING INCORPORATED ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu ,  Chujun Zheng

IPC: C04B35/495 ,  H01M10/0562

Abstract: A sintered composite ceramic includes a lithium-garnet major phase; and a lithium dendrite growth inhibitor minor phase, such that the lithium dendrite growth inhibitor minor phase comprises lithium tungstate. A method includes sintering a metal oxide component and a garnet component at a temperature in a range of 750° C. to 1500° C. to form a sintered composite ceramic.

公开(公告)号：US20230094026A1

公开(公告)日：2023-03-30

申请号：US17955757

申请日：2022-09-29

Applicant: CORNING INCORPORATED ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Mingli Cai ,  Jun Jin ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M10/0562 ,  H01M10/0525

Abstract: A lithium-metal battery includes: a cathode; a garnet solid-state electrolyte disposed on the cathode; and a lithium anode disposed on the garnet solid-state electrolyte, such that a modification layer is disposed at an interface of the lithium anode and garnet solid-state electrolyte, the modification layer comprising an inorganic lithium salt. A method of forming a lithium-metal battery includes treating garnet solid-state electrolyte with an acid solution; and exposing the acid-treated garnet solid-state electrolyte to hydrogen fluoride to form a modification layer atop the garnet solid-state electrolyte.

公开(公告)号：US20220181628A1

公开(公告)日：2022-06-09

申请号：US17603380

申请日：2020-04-14

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianing Wang ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M4/62 ,  H01M10/0562 ,  H01M10/0525

Abstract: A lithium-sulfur battery includes a substrate; a sulfur cathode disposed on the substrate; a coating layer disposed on the cathode; a first interlayer disposed on the coating layer; a solid-state electrolyte disposed on the first interlayer; a second interlayer disposed on the electrolyte; and a lithium anode disposed on the second interlayer, such that the coating layer is further disposed within pores of the cathode.

公开(公告)号：US20210363065A1

公开(公告)日：2021-11-25

申请号：US17236528

申请日：2021-04-21

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu ,  Chujun Zheng

IPC: C04B35/48 ,  H01M10/0525 ,  H01M10/0562

Abstract: A sintered composite ceramic, including: a lithium-garnet major phase; and a lithium-rich minor phase, such that the lithium-rich minor phase comprises LixZrO(x+4)/2, with 2≤x≤10.

公开(公告)号：US20180301754A1

公开(公告)日：2018-10-18

申请号：US15953050

申请日：2018-04-13

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Yinghong Chen ,  Xiao Huang ,  Cai Liu ,  Xinyuan Liu ,  Yanxia Ann Lu ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Nathan Michael Zink

IPC: H01M10/0562 ,  H01M10/052 ,  C04B35/486 ,  C04B35/626 ,  C04B35/64 ,  C04B35/48 ,  C04B35/495

Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.