公开(公告)号：US11261378B2

公开(公告)日：2022-03-01

申请号：US15539666

申请日：2015-12-17

Applicant: DIC CORPORATION

Inventor： Masahiro Horiguchi ,  Sayaka Nose ,  Akihiro Koiso

IPC: C09K19/54 ,  C07C69/753 ,  C07C69/76 ,  C07D333/22 ,  C07D339/06 ,  C07D339/08 ,  C07D407/12 ,  C07D409/12 ,  C07C323/21 ,  C07D413/12 ,  C07D417/04 ,  C07D417/06 ,  C07D249/06 ,  C07C327/48 ,  C07C251/24 ,  C07D207/452 ,  C07C251/86 ,  C07C251/88 ,  C07D209/12 ,  C07D277/82 ,  C07D513/04 ,  C08F20/10 ,  G02B5/30 ,  C07C69/94 ,  C07C69/75 ,  C09K19/34 ,  C07D409/14 ,  C07D305/06 ,  C07C251/78 ,  C07D403/04 ,  C07D209/40 ,  C07D303/48 ,  C09K19/32 ,  C07D495/04 ,  C07C69/757 ,  C07C245/08 ,  C07D333/36 ,  C07D307/66 ,  C07D403/12 ,  C07D417/12 ,  C07D265/16 ,  C07D249/04 ,  C07D213/74 ,  C07C251/18 ,  C07D409/06 ,  C07D333/76 ,  C07D277/64 ,  C07D209/88 ,  C09K19/38 ,  G02F1/13363 ,  C09K19/04 ,  C08F220/30

Abstract: The present invention aims to provide a polymerizable compound that has high storage stability without causing crystal precipitation when added to a polymerizable composition and to provide a polymerizable composition containing the polymerizable compound. A polymer film produced by polymerization of the polymerizable composition has a low haze, high thickness uniformity, low occurrence of nonuniform orientation, high surface hardness, high adhesiveness, and good appearances and fewer orientation defects even after ultraviolet irradiation. The present invention also aims to provide a polymer produced by polymerization of the polymerizable composition and an optically anisotropic body produced from the polymer.

公开(公告)号：US11046889B2

公开(公告)日：2021-06-29

申请号：US16060265

申请日：2016-12-01

Applicant: DIC Corporation

Inventor： Yoshitaka Saito ,  Tatsufumi Yamazaki ,  Masahiro Horiguchi ,  Junichi Mamiya ,  Toru Tsuruta

IPC: C09K19/38 ,  C09K19/34 ,  C07D277/66 ,  C07D277/82 ,  C07D417/04 ,  C07D409/04 ,  C07D339/06 ,  C08F20/30 ,  C07D277/84 ,  C07D277/64 ,  C08F222/10 ,  G02F1/13363 ,  C09K19/04 ,  C09K19/12 ,  C09K19/20 ,  C09K19/30 ,  C09K19/54

Abstract: The polymerizable liquid crystal compound has reverse wavelength dispersion or low wavelength dispersion and has high solubility in various solvents. The polymerizable liquid crystal compound provides an optically anisotropic body having high adhesiveness to substrates (or alignment films), by adding the polymerizable liquid crystal compound to a polymerizable composition and polymerizing the polymerizable composition using ultraviolet light. The invention provides a polymerizable composition containing the polymerizable liquid crystal compound having reverse wavelength dispersion or low wavelength dispersion, a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low wavelength dispersion or polymerizable reverse wavelength dispersion compound having in the molecule a partial structure represented by the general formula (AO-1); and also provides a composition containing the compound, a polymer obtained by polymerizing the composition, and an optically anisotropic body and the like using the polymer.

公开(公告)号：US20200165215A1

公开(公告)日：2020-05-28

申请号：US16082471

申请日：2017-03-16

Applicant: DIC Corporation

Inventor： Masahiro Horiguchi ,  Junichi Mamiya

IPC: C07D277/82 ,  C09K19/34 ,  C08F22/14

Abstract: The present invention provides a novel method for producing a 2-hydrazinobenzothiazole derivative. The present invention also provides a method for producing a compound by using the 2-hydrazinobenzothiazole derivative obtained by the production method, and a composition that contains the compound. The present invention also provides a polymerizable composition that is useful in producing film-shaped polymers and contains the compound obtained by the production method. The invention of the present application provides a method for producing a compound represented by general formula (I-C), the method including a step of reacting a compound represented by general formula (I-B) with a compound represented by general formula (I-A) in the presence of at least one compound selected from the group consisting of metal amides, metal hydrides, metal alkoxides, and organic alkali metals. A compound derived from the compound produced by the production method, and a composition that contains the compound are also provided.

公开(公告)号：US10649124B2

公开(公告)日：2020-05-12

申请号：US15757421

申请日：2016-07-14

Applicant: DIC Corporation

Inventor： Mika Takasaki ,  Masahiro Horiguchi ,  Yasuhiro Kuwana

IPC: G02B26/00 ,  G02B5/30 ,  C08F2/48 ,  C09K19/34 ,  C09K19/54 ,  C08F222/10 ,  C09K19/20 ,  C08F220/36 ,  C09K19/02 ,  C08F226/06 ,  C08F220/30 ,  G02F1/13363 ,  C09K19/04 ,  C08F220/10

Abstract: A polymerizable composition of the present invention has favorable solubility, and an optically anisotropic body using the polymerizable composition is unlikely to discolor and is excellent in heat resistance and light resistance. The problem to be solved by the present invention is to provide a polymer obtained by polymerizing the polymerizable composition and an optically anisotropic body using the polymer. The present invention relates to a polymerizable composition which includes a compound having at least one mesogenic group and satisfying an expression represented by Expression (1), and which satisfies an expression represented by Expression (2). 0.5≤YI/Δn≤500  Expression (2)

公开(公告)号：US10647662B2

公开(公告)日：2020-05-12

申请号：US15542552

申请日：2016-01-07

Applicant: DIC Corporation

Inventor： Yutaka Kadomoto ,  Masahiro Horiguchi ,  Akihiro Koiso

IPC: C07C251/86 ,  C09K19/34 ,  C09K19/32 ,  C08F122/24 ,  C08F122/22 ,  C09K19/38 ,  C07D277/82 ,  C08F20/34 ,  C09K19/20 ,  C09K19/30 ,  C09K19/04

Abstract: In light of requests to reduce or reverse the wavelength dispersion of the birefringence of a phase-retardation film in order to increase the viewing angle of a liquid crystal display, the present invention provides a polymerizable compound that reduces, for example, the likelihood of crystals precipitating in a polymerizable composition including the polymerizable compound and enables the polymerizable composition to have high preservation stability and a polymerizable composition including the polymerizable compound which reduces the likelihood of inconsistencies being formed in a film-like polymer produced by polymerizing the polymerizable composition. Another object of the present invention is to provide a polymer produced by polymerizing the polymerizable composition and an optically anisotropic body including the polymer.

公开(公告)号：US10597371B2

公开(公告)日：2020-03-24

申请号：US15547949

申请日：2016-02-16

Applicant: DIC Corporation

Inventor： Masahiro Horiguchi ,  Yutaka Kadomoto

IPC: C09K19/38 ,  C07D277/82 ,  C07D409/14 ,  C07D417/12 ,  C07C243/20 ,  C07C243/22 ,  C07C323/52 ,  C07D209/56 ,  C07D241/42 ,  C07D263/58 ,  C07D277/84 ,  C07D303/27 ,  C07D317/46 ,  C07D333/58 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D413/14 ,  C07D417/14 ,  C07D495/04 ,  C07D513/04 ,  C08F22/10 ,  C09K19/32 ,  C09K19/34

Abstract: The present invention provides a polymerizable compound having high storage stability without causing crystal precipitation when added to a polymerizable composition. The present invention also provides a polymerizable composition containing the compound. When the filmy polymer produced through polymerization of the polymerizable composition is irradiated with UV light, it hardly discolors or peels from substrate. Further, the present invention provides a polymer produced through polymerization of the polymerizable composition and an optically anisotropic body using the polymer.

公开(公告)号：US20180354922A1

公开(公告)日：2018-12-13

申请号：US15781950

申请日：2016-11-29

Applicant: DIC Corporation

Inventor： Masahiro Horiguchi ,  Junichi Mamiya

IPC: C07D277/82 ,  C08F20/38

CPC classification number: C07D277/82 ,  C08F16/30 ,  C08F16/32 ,  C08F20/22 ,  C08F20/38

Abstract: The polymerizable compound has a hydrazone moiety. The present invention also provides a polymerizable composition in which discoloration and reduction of aligning property do not easily occur. Furthermore, the present invention provides a polymer obtained by polymerizing a polymerizable composition containing a compound obtained by the production method and an optically anisotropic body using the polymer. The present invention provides a method for producing a polymerizable compound including a step of reacting a compound represented by General Formula (I-B-a) with a compound represented by General Formula (I-B-b) to obtain a compound represented by General Formula (I-C), and provides a composition which contains a compound obtained by this production method.

公开(公告)号：US20240026219A1

公开(公告)日：2024-01-25

申请号：US18034912

申请日：2021-11-04

Applicant: DIC Corporation

Inventor： Yuki Nonaka ,  Takuo Hayashi ,  Masahiro Horiguchi

IPC: C09K11/08 ,  G02F1/1335 ,  B82Y20/00 ,  C09K11/02

CPC classification number: C09K11/0827 ,  G02F1/133514 ,  B82Y20/00 ,  C09K11/025

Abstract: The method for producing light-emitting particles each having a surface layer containing Si on a surface of a semiconductor nanocrystal particle composed of a metal halide includes the steps of: forming the semiconductor nanocrystal particle and a poly-siloxane bond from a solution containing a raw material for the semiconductor nanocrystal particle, a silane compound A having a binding group and a hydrolyzable silyl group, and a solvent, to obtain a precursor particle; mixing the precursor particle, a polymer B containing a structural unit having a basic group and a solvophilic structural unit, and a solvent to obtain a mixture; and adding a silane compound C having a hydrolyzable silyl group to the mixture to obtain a light-emitting particle having a layer containing the polymer B and a polymer of the silane compound C on a surface of the precursor particle.

公开(公告)号：US20220195290A1

公开(公告)日：2022-06-23

申请号：US17605066

申请日：2020-05-15

Applicant: DIC Corporation

Inventor： Yoshio Aoki ,  Yasuo Umezu ,  Koichi Endo ,  Shinichi Hirata ,  Takuo Hayashi ,  Masahiro Horiguchi ,  Misao Horigome ,  Jianjun Yuan

IPC: C09K11/02 ,  C09K11/66 ,  C09D11/50 ,  C09D11/037 ,  C09D11/101 ,  C09D11/107 ,  H01L27/32

Abstract: Provided are light-emitting particles having high stability while having perovskite-type semiconductor nanocrystals having excellent light-emitting properties, a method for producing the same, and a light-emitting particle dispersion, an ink composition, and a light-emitting element containing such light-emitting particles. The method for producing light-emitting particles of the present invention includes a step of preparing parent particles 91 each having hollow particles 912 each having an inner space 912a and pores 912b communicating with the inner space 912a, and perovskite-type semiconductor nanocrystals 911 contained in the inner space 912a and having light-emitting properties, and a step of coating the surface of each parent particle 91 with a hydrophobic polymer to form a polymer layer 92.

公开(公告)号：US10968189B2

公开(公告)日：2021-04-06

申请号：US16082471

申请日：2017-03-16

Applicant: DIC Corporation

Inventor： Masahiro Horiguchi ,  Junichi Mamiya

IPC: C07D277/82 ,  C09K19/38 ,  C08F22/14 ,  C09K19/34

Abstract: The present invention provides a novel method for producing a 2-hydrazinobenzothiazole derivative. The present invention also provides a method for producing a compound by using the 2-hydrazinobenzothiazole derivative obtained by the production method, and a composition that contains the compound. The present invention also provides a polymerizable composition that is useful in producing film-shaped polymers and contains the compound obtained by the production method. The invention of the present application provides a method for producing a compound represented by general formula (I-C), the method including a step of reacting a compound represented by general formula (I-B) with a compound represented by general formula (I-A) in the presence of at least one compound selected from the group consisting of metal amides, metal hydrides, metal alkoxides, and organic alkali metals. A compound derived from the compound produced by the production method, and a composition that contains the compound are also provided.