摘要:
A fluoropolymer of a monomer (I) represented by the general formula (I), wherein a content of a polymerization unit (I) derived from the monomer (I) is 50% by mass or more based on all polymerization units constituting the fluoropolymer:
CX2═CX—O—Rf—SO3M General formula (I)
wherein X is independently F or CF3; Rf is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having 2 to 100 carbon atoms and having an ether bond or a keto group; and M is —H, a metal atom, —NR74, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R7 is H or an organic group. Also disclosed are an aqueous solution and coating composition containing the fluoropolymer.
摘要:
Multi-acid polymers for use as a fuel cell membrane, for example, have multi-acid monomers that have an imide base and more than two proton conducting groups. The multi-acid polymers are made by reacting a polymer precursor in sulfonyl fluoride or sulfonyl chloride form with a compound with an acid giving group. One example of a multi-acid polymer is: wherein R is one or more units of a non-SO2F or non-SO2Cl portion of a polymer precursor in sulfonyl fluoride or sulfonyl chloride form.
摘要:
A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W1 and W2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R1 is a single bond or a C1-4 alkylene group, R2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R1, R2, and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y1, Y2) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R3a and R3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.
摘要:
A surface active agent composition is prepared including: a polymerizable monomer surface active agent and a polymerizable dimer surface active agent represented by the following chemical formula. In the following chemical formula, R1s each are independently an alkyl group having 8 to 30 carbon atoms, R2s each are independently hydrogen or a methyl group, As each are independently an alkylene group having 2 to 4 carbon atoms or a substituted alkylene group, and ns each are independently an integer from 0 to 200. The surface active agent composition is capable of providing for an emulsion exhibiting excellent mechanical stability and polymerization stability, which in turn is capable of forming a film having sufficiently high adhesion and water resistance.
摘要:
A surface active agent composition is prepared including: a polymerizable monomer surface active agent and a polymerizable dimer surface active agent represented by the following chemical formula. In the following chemical formula, R1s each are independently an alkyl group having 8 to 30 carbon atoms, R2s each are independently hydrogen or a methyl group, As each are independently an alkylene group having 2 to 4 carbon atoms or a substituted alkylene group, and ns each are independently an integer from 0 to 200. The surface active agent composition is capable of providing for an emulsion exhibiting excellent mechanical stability and polymerization stability, which in turn is capable of forming a film having sufficiently high adhesion and water resistance. 1
摘要:
An organic polymeric material, which is preferably perfluorinated and which comprises a polymeric chain and at least one group pendant from the chain, in which the group pendant from the chain comprises a saturated cyclic group and at least one ion-exchange group or group convertible thereto, and in which the ion-exchange group or group convertible thereto is linked to the polymeric chain through the cyclic group. Also an ion-exchange membrane produced from the polymeric material, an electrolytic cell containing the membrane, vinyl monomers from which the organic polymeric material may be produced and intermediates useful in production of the monomers.
摘要:
The polymerizable compound has a hydrazone moiety. The present invention also provides a polymerizable composition in which discoloration and reduction of aligning property do not easily occur. Furthermore, the present invention provides a polymer obtained by polymerizing a polymerizable composition containing a compound obtained by the production method and an optically anisotropic body using the polymer. The present invention provides a method for producing a polymerizable compound including a step of reacting a compound represented by General Formula (I-B-a) with a compound represented by General Formula (I-B-b) to obtain a compound represented by General Formula (I-C), and provides a composition which contains a compound obtained by this production method.
摘要:
Described herein is an oligomer having a pendant bromine-containing moiety according to formula II and/or formula III; and combinations thereof; wherein X1, X2, and X3 are each independently selected from F, Cl, H, and CF3; R is a linear or branched linking group, which may be saturated or unsaturated, substituted or unsubstituted, and may comprise a heteroatom; each Z1 and Z2 is independently selected from F and CF3; n is 0 or 1; q is 0 or 1; and m is at least 2.
摘要:
Described herein are monomers of the formula CH2nullCH(CF2)2nOCF2CF2SO2Nnull(Mnull)SO2Rf where nnull1 and MnullnullHnull or an alkali metal cation, and Rf is C1-4 perfluoroalkyl optionally substituted by one or more ether oxygens, and polymers made therefrom.
摘要翻译:本文描述的是式CH 2 = CH(CF 2)2 OCF 2 CF 2 SO 2 N(M +)SO 2 R f的单体,其中n> = 1和M + = H +或碱金属阳离子,Rf为C1- 任选被一个或多个醚氧取代的全氟烷基,以及由其制备的聚合物。
摘要:
An improved solution polymerization process is provided wherein vinyl monomers are polymerized in the presence of at least one reactive modifier which is a substituted alpha-olefin that incorporates at least three ether groups, is hydrophilic, and has a molecular weight of at least about 200. The modified vinyl polymers so produced are characterized by various improved physical properties including, in particular, electrical characteristics such as antistatic capacity.