公开(公告)号：US12104002B2

公开(公告)日：2024-10-01

申请号：US17437275

申请日：2020-03-19

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Brad C. Bailey ,  Tomas D. Paine ,  Sukrit Mukhopadhyay ,  Matthew D. Christianson

IPC: C08F210/02 ,  C08F2/04 ,  C08F2/16 ,  C08F4/659 ,  C08F210/16

CPC classification number: C08F4/65908 ,  C08F2/04 ,  C08F210/16

Abstract: Processes for polymerizing polyolefins include contacting ethylene and optionally one or more (C3-C12)α-olefin in the presence of a catalyst system, wherein the catalyst system comprises a metal-ligand complex having a structure according to formula (I):

公开(公告)号：US11897992B2

公开(公告)日：2024-02-13

申请号：US16494136

申请日：2018-03-15

Applicant: Dow Global Technologies LLC

Inventor： Jasson T. Patton ,  Todd D. Senecal ,  Daniel J. Arriola ,  Matthew D. Christianson ,  Gordon R. Roof ,  David D. Devore ,  Anna V. Davis

IPC: C08F10/02 ,  C08F4/64 ,  C08F4/52 ,  C08F4/619 ,  C08F297/08

CPC classification number: C08F4/64193 ,  C08F4/52 ,  C08F4/61904 ,  C08F297/083 ,  C08F2410/01 ,  C08F2420/02

Abstract: The present disclosure relates to an olefin polymerization catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the catalyst system comprises: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

公开(公告)号：US20220162354A1

公开(公告)日：2022-05-26

申请号：US17437275

申请日：2020-03-19

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Brad C. Bailey ,  Tomas D. Paine ,  Sukrit Mukhopadhyay ,  Matthew D. Christianson

IPC: C08F4/659 ,  C08F210/16 ,  C08F2/04

Abstract: Processes for polymerizing polyolefins include contacting ethylene and optionally one or more (C3-C12)α-olefin in the presence of a catalyst system, wherein the catalyst system comprises a metal-ligand complex having a structure according to formula (I):

公开(公告)号：US11208502B2

公开(公告)日：2021-12-28

申请号：US16494150

申请日：2018-03-15

Applicant: Dow Global Technologies LLC

Inventor： Jasson T. Patton ,  Todd D. Senecal ,  Daniel J. Arriola ,  Matthew D. Christianson ,  Gordon R. Roof ,  Jerzy Klosin ,  David D. Devore ,  Anna V. Davis

IPC: C08F4/76 ,  C08F4/64 ,  C08F4/54 ,  C08F210/16

Abstract: The present disclosure relates to an olefin polymerization catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

公开(公告)号：US11066495B2

公开(公告)日：2021-07-20

申请号：US16337588

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Matthew D. Christianson ,  Robert D. J. Froese

IPC: C07F5/00 ,  C08F10/02 ,  C08F10/14

Abstract: Embodiments are directed to phosphaguanidine metal complexes of formula I and using those complexes in α-olefin polymerization systems.

公开(公告)号：US20210122840A1

公开(公告)日：2021-04-29

申请号：US16494136

申请日：2018-03-15

Applicant: Dow Global Technologies LLC

Inventor： Jasson T. Patton ,  Todd D. Senecal ,  Daniel J. Arriola ,  Matthew D. Christianson ,  Gordon R. Roof ,  David D. Devore ,  Anna V. Davis

IPC: C08F4/64 ,  C08F297/08 ,  C08F4/619 ,  C08F4/52

Abstract: The present disclosure relates to an olefin polymerization catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the catalyst system comprises: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

公开(公告)号：US20210108005A1

公开(公告)日：2021-04-15

申请号：US17043029

申请日：2019-03-28

Applicant: Dow Global Technologies LLC ,  Northwestern University

Inventor： Tobin J. Marks ,  Yanshan Gao ,  Tracy L. Lohr ,  Matthew D. Christianson ,  Jerzy Klosin ,  Edmund M. Carnahan ,  Andrew J. Young

IPC: C08F4/64 ,  C08F10/14 ,  C08F10/02

Abstract: Embodiments are directed to catalyst systems comprising: a procatalyst; and a co-catalyst dissolved in a non-halogenated aprotic hydrocarbon solvent, the co-catalyst comprising: a non-coordinating borate dianion having the formula: (III) and two cations, each cation being independently chosen from a cation according to formula (I) or formula (II).

公开(公告)号：US20200031960A1

公开(公告)日：2020-01-30

申请号：US16337588

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Matthew D. Christianson ,  Robert DJ Froese

IPC: C08F10/14 ,  C08F10/02 ,  C07F5/00

Abstract: Embodiments are directed to phosphaguanidine metal complexes of formula I and using those complexes in α-olefin polymerization systems.

公开(公告)号：US09459533B2

公开(公告)日：2016-10-04

申请号：US13926004

申请日：2013-06-25

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Electronic Materials LLC

Inventor： Matthew D. Christianson ,  Matthew M. Meyer ,  Owendi Ongayi

IPC: G03F7/039 ,  C08F14/18 ,  G03F7/00

CPC classification number: G03F7/0397 ,  C08F14/185 ,  G03F7/00 ,  G03F7/0045 ,  G03F7/0046

Abstract: A copolymer comprises the polymerized product of a dissolution-rate controlling monomer having the formula (I), an acyclic vinyl ether monomer of the formula (II), and a cyclic vinyl ether monomer of the formula (III): wherein Ra, Rb, Rc, L, X, and Z1 are defined herein. A photoresist composition comprising the copolymer is described, as is an article coated with the photoresist composition, and a method of forming an electronic device using the photoresist composition.

公开(公告)号：US09422375B2

公开(公告)日：2016-08-23

申请号：US14931258

申请日：2015-11-03

Applicant: Dow Global Technologies LLC

Inventor： Matthew D. Christianson ,  Timothy S. De Vries ,  Robert D J Froese ,  Matthias S. Ober ,  Jasson T. Patton ,  Duane R. Romer ,  Gordon R. Roof ,  Lixin Sun ,  Endre Szuromi ,  Curt N. Theriault ,  Dean M. Welsh ,  Timothy T. Wenzel ,  Paul H. Moran

IPC: C07F11/00 ,  C08F4/78 ,  C08F10/00 ,  C08F210/06 ,  C08F110/06 ,  C08F110/02

CPC classification number: C08F4/78 ,  C07F11/00 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/69112 ,  C08F210/16 ,  C08F2500/15

Abstract: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly(1-alkene) or olefin block copolymer. Further provided is the partially chain-straightened poly(1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.

Abstract translation: 提供非环戊二烯基铬配体络合物，优选式（J）的铬配体络合物：LCr（RA）m（D）k（J），其中L是非Cp单阴离子配体; Cr（铬）处于+3或+2的正式氧化态; 当Cr正式为Cr + 3时，m为1，RA为亚烃基（式（J））的亚烃基铬 - 配体配合物）或m为2，各RA独立地为烃基（式（J）的二烃基铬 - 配体络合物 ）），其中RA的各个烃基或亚烃基独立地未被取代或被1至5个RAS取代; 每个RAS独立地是中性非质子杂烷基，中性非质子杂环烷基，中性非质子杂芳基或中性非质子性芳基; 当Cr正式为Cr + 2时，m为1，RA为烃基（式（J））的烃基铬 - 配体络合物）; k是0或1的整数; 当k为0时，D不存在，或当k为1时D为中性配体; 其中式（J）的铬配体络合物是总体中性的，并且缺少基于环戊二烯基的（Cp-基）部分。 还提供了包含或由络合物制备的铬催化剂。 还提供了制备催化剂的方法和使用铬催化剂聚合烯烃单体，特别是直链1-烯烃的方法，以制备聚烯烃，特别是部分链改性的聚（1-烯烃）或烯烃嵌段 共聚物。 进一步提供由其制备的部分链直链化的聚（1-烯烃）或烯烃嵌段共聚物。 还提供了高吞吐量的工作流程。