公开(公告)号：US10131746B2

公开(公告)日：2018-11-20

申请号：US14912160

申请日：2014-08-15

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/00 ,  C08G71/04 ,  C08G65/333 ,  C09D175/04 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a tetravalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times four equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US09683082B2

公开(公告)日：2017-06-20

申请号：US14908843

申请日：2014-07-28

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  Ronald H. Leng

IPC: C09D175/12 ,  C08G71/04 ,  B01J19/24 ,  C08G65/333 ,  C09D161/24

CPC classification number: C08G71/04 ,  B01J19/24 ,  B01J2219/00164 ,  B01J2219/24 ,  C08G65/33303 ,  C09D161/24 ,  C09D175/12

Abstract: A process to produce polycarbamate comprising providing urea in liquid form; and adding the urea in liquid form to a polyol in a reduced gradient profile to form polycarbamate product is provided. Also provided are: (a) a reaction product of the process and (b) an apparatus for operating the process.

公开(公告)号：US20160215094A1

公开(公告)日：2016-07-28

申请号：US14916555

申请日：2014-09-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Gary E. Spilman ,  Congcong Lu ,  Daryoosh Beigzadeh ,  Yiyong He ,  Paul J. Popa ,  John N. Argyropoulos

IPC: C08G71/04 ,  C09D175/06

CPC classification number: C08G71/04 ,  C08G18/6229 ,  C08G18/6254 ,  C09D175/06

Abstract: A method for producing polycarbamate comprising: contacting at least one carbamylating agent with a polyol in the presence of a carbamylation catalyst to form a reaction mixture having an acid value from 3 to 50 mg KOH/g dry polyol is provided. Further provided are a polycarbamate produced by the method and a coating comprising the polycarbamate.

Abstract translation: 一种生产聚氨酯的方法，包括：在氨基甲酰化催化剂存在下使至少一种氨基甲酰化剂与多元醇接触以形成酸值为3-50mg KOH / g干多元醇的反应混合物。 还提供了通过该方法制备的聚氨酯和包含聚氨酯的涂层。

公开(公告)号：US10174163B2

公开(公告)日：2019-01-08

申请号：US15035234

申请日：2014-10-14

Applicant: Dow Global Technologies LLC

Inventor： Paul Foley ,  John N. Argyropoulos ,  Yiyong He

IPC: C08G71/02 ,  C08G12/46 ,  C08G65/333 ,  C09D161/24 ,  C09D175/02

Abstract: A non-aqueous crosslinkable composition comprising a polyurea having a functionality of equal to or greater than 2; an aldehyde or acetal or hemiacetal thereof; and optionally one or more organic solvents is provided. Further provided is a crosslinked composition, a coating, articles including the coating and a method of making a non-aqueous crosslinkable composition.

公开(公告)号：US20180265458A1

公开(公告)日：2018-09-20

申请号：US15986271

申请日：2018-05-22

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C07C269/00 ,  C09D7/63 ,  C07C271/10 ,  C08G65/333 ,  C08G71/04 ,  C09D175/04

CPC classification number: C07C269/00 ,  C07C271/10 ,  C08G65/33303 ,  C08G65/33324 ,  C08G71/04 ,  C09D7/63 ,  C09D175/04

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a trivalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times three equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US20180258224A1

公开(公告)日：2018-09-13

申请号：US15980769

申请日：2018-05-16

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C08G65/333 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US09822280B2

公开(公告)日：2017-11-21

申请号：US14900106

申请日：2014-06-18

Applicant: Dow Global Technologies LLC

Inventor： Gary E. Spilman ,  Jeff R. Anderson ,  John N. Argyropoulos ,  Paul Foley ,  Xinrui Yu ,  John W. Hull ,  Congcong Lu ,  Daryoosh Beigzadeh ,  Yiyong He

IPC: C08K5/05 ,  C08G69/44 ,  C08G73/10 ,  C08L77/00 ,  C08G63/02 ,  C09D175/12 ,  C09D167/00 ,  C09D167/08 ,  C09D161/24

CPC classification number: C09D175/12 ,  C09D161/24 ,  C09D167/00 ,  C09D167/08 ,  C08L67/08

Abstract: The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.

公开(公告)号：US09796815B2

公开(公告)日：2017-10-24

申请号：US13955507

申请日：2013-07-31

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Paul Foley

IPC: C08G71/04 ,  C08G65/333

CPC classification number: C08G71/04 ,  C08G65/33303

Abstract: A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

公开(公告)号：US20160289385A1

公开(公告)日：2016-10-06

申请号：US15035234

申请日：2014-10-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Paul Foley ,  John N. Argyropoulos ,  Yiyong He

IPC: C08G71/02 ,  C09D175/02

CPC classification number: C08G71/02 ,  C08G12/46 ,  C08G65/333 ,  C08G65/33303 ,  C08G65/33396 ,  C08G2650/50 ,  C09D161/24 ,  C09D175/02

Abstract: A non-aqueous crosslinkable composition comprising a polyurea having a functionality of equal to or greater than 2; an aldehyde or acetal or hemiacetal thereof; and optionally one or more organic solvents is provided. Further provided is a crosslinked composition, a coating, articles including the coating and a method of making a non-aqueous crosslinkable composition.

Abstract translation: 包含官能度等于或大于2的聚脲的非水可交联组合物; 醛或缩醛或半缩醛; 并且可选地提供一种或多种有机溶剂。 还提供了一种交联组合物，一种涂层，包括该涂层的制品以及一种制备非水性可交联组合物的方法。

公开(公告)号：US09403759B2

公开(公告)日：2016-08-02

申请号：US14721423

申请日：2015-05-26

Applicant: Dow Global Technologies LLC

Inventor： Jeff R. Anderson ,  Daryoosh Beigzadeh ,  Yiyong He ,  Congcong Lu

IPC: C08G18/06 ,  C07C269/04 ,  C08G71/02 ,  C08G18/79 ,  C08G18/38

CPC classification number: C07C269/04 ,  C08G18/06 ,  C08G18/38 ,  C08G18/3823 ,  C08G18/79 ,  C08G71/02

Abstract: The present invention provides methods for making a polycarbamate by feeding a) a urea in fluid form into a reaction medium containing b) an alkyd polyol, such as a short or med oil alkyd polyol to form a reaction mixture and then carbamylating the alkyd polyol by heating the reaction mixture while feeding water in to the reaction mixture, preferably, in the presence of one or more c) carbamylation catalysts. The polycarbamate of the present invention when combined with a polyaldehyde or an acetal or hemiacetal thereof as a second component makes a multicomponent composition that is substantially isocyanate-free, and cures at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane.

Abstract translation: 本发明提供了通过将a）流体形式的尿素加入到含有b）醇酸多元醇如短油或中油醇酸多元醇的反应介质中以形成反应混合物，然后通过以下方式氨基甲酰化醇酸树脂多元醇，制备聚氨酯的方法： 加热反应混合物同时将水送入反应混合物中，优选在一种或多种c）氨基甲酰化催化剂存在下进行。 当与多醛或其缩醛或半缩醛组合作为第二组分时，本发明的聚氨基甲酸酯形成基本上不含异氰酸酯的多组分组合物，并且在0℃至小于80℃的温度下固化。 以形成交联的聚氨酯。