公开(公告)号：US06515035B2

公开(公告)日：2003-02-04

申请号：US09983325

申请日：2001-10-24

申请人： Magalie Roy-Auberger ,  Patrick Euzen ,  Vincent Zozaya ,  Roberto Zennaro ,  Giovanni Pederzani

发明人： Magalie Roy-Auberger ,  Patrick Euzen ,  Vincent Zozaya ,  Roberto Zennaro ,  Giovanni Pederzani

IPC分类号： C07C2700

CPC分类号： C10G2/332 ,  B01J21/12 ,  B01J23/75 ,  B01J37/0203 ,  B01J37/0207

摘要： A process is described for converting synthesis gas in the presence of a catalyst comprising at least one group VIII element dispersed on a support comprising alumina modified by aqueous impregnation of quaternary ammonium silicate and comprising in the range of about 3% by weight to about 9.5% by weight of silica. Said support can optionally also comprise at least one oxide selected from the group formed by rare earth oxides, alkaline-earth oxides and zirconium oxide.

公开(公告)号：US07662865B2

公开(公告)日：2010-02-16

申请号：US12348044

申请日：2009-01-02

申请人： Marie-Claire Marion ,  Francois Hugues ,  Magalie Roy-Auberger

发明人： Marie-Claire Marion ,  Francois Hugues ,  Magalie Roy-Auberger

IPC分类号： C07C27/00

CPC分类号： B01J23/75 ,  B01J35/1061 ,  C10G2/32

摘要： The subject of the invention is a process for the synthesis of hydrocarbons based on a synthesis gas type feedstock in which said synthesis gas is brought into contact with a catalyst in a reactor under Fischer-Tropsch synthesis conditions and in which the partial pressure of water is controlled in order to keep it below a critical value ppH2O-limit defined by the formula: ppH2Olimit=exp(−7751/dp·T)·Ps(T) where T is the reaction temperature in K, dp is the average diameter of the catalyst pores in nm, determined by nitrogen adsorption-desorption (BJH method), Ps(T) is the saturating water vapour pressure at temperature T, in bar.

摘要翻译： 本发明的主题是基于合成气类型原料合成烃的方法，其中所述合成气在费 - 托合成条件下在反应器中与催化剂接触，并且其中水的分压为 控制以使其低于由以下公式定义的临界值ppH2O限制：ppH2Olimit = exp（-7751 / dp.T）.Ps（T）其中T是K中的反应温度，dp是 通过氮吸附 - 解吸（BJH法）确定的催化剂孔隙，P（T）是在温度T下的饱和水蒸汽压力，单位为bar。

公开(公告)号：US20090188834A1

公开(公告)日：2009-07-30

申请号：US11663497

申请日：2005-09-20

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Magalie Roy-Auberger ,  Partick Bourges ,  Tivadar Cseri ,  Maryline Delage ,  Nathalie Lett

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Magalie Roy-Auberger ,  Partick Bourges ,  Tivadar Cseri ,  Maryline Delage ,  Nathalie Lett

IPC分类号： C10G47/20 ,  B01J27/19 ,  B01J27/188 ,  B01J27/185 ,  B01J21/12 ,  B01J21/02

CPC分类号： B01J21/12 ,  B01J21/02 ,  B01J23/883 ,  B01J23/888 ,  B01J27/1853 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/20 ,  B01J37/28 ,  C10G49/02 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).

摘要翻译： 本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。 该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。

公开(公告)号：US06391929B1

公开(公告)日：2002-05-21

申请号：US09693985

申请日：2000-10-23

申请人： Francois Hughes ,  Magalie Roy-Auberger ,  Marie-Claire Marion

发明人： Francois Hughes ,  Magalie Roy-Auberger ,  Marie-Claire Marion

IPC分类号： C07D2700

CPC分类号： C10G2/332 ,  B01J25/00 ,  C07C1/043 ,  C07C1/0435 ,  C07C1/044 ,  C07C1/066 ,  C07C2525/00

摘要： A process for synthesising hydrocarbons from synthesis gas in the presence of a catalyst essentially constituted by a Raney metal alloy dispersed in a liquid phase is described in which the catalyst comprises at least 60% by weight of at least one metal selected from metals from groups 8, 9 and 10, and optionally at least one additional element selected from alkali metals and metals from groups 4, 5, 6, 7, 8, 9, 10 and 11.

摘要翻译： 描述了在基本上由分散在液相中的阮内金属合金构成的催化剂存在下从合成气中合成烃的方法，其中催化剂包含至少一种选自组8的金属的至少一种金属 ，9和10，以及任选的至少一种选自碱金属和来自第4,5,6,7,8,9,10和11族的金属的另外的元素。