Catalyst and process for hydrocracking hydrocarbon-containing feedstocks
    2.
    发明授权
    Catalyst and process for hydrocracking hydrocarbon-containing feedstocks 有权
    用于加氢裂化含烃原料的催化剂和方法

    公开(公告)号:US07270738B2

    公开(公告)日:2007-09-18

    申请号:US10696561

    申请日:2003-10-30

    摘要: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 Å, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 160 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 200 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 500 Å, of less than 0.01 ml/g, an X diffraction diagram contains at least the main lines that are characteristic of at least one of the transition aluminas contained in the group that consists of the alpha, rho, chi, eta, gamma, kappa, theta and delta aluminas.

    摘要翻译: 本发明涉及硅铝基板,催化剂以及使用它们的加氢裂化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和非沸石二氧化硅 - 氧化铝基底物的含氢量超过5的氢脱氢元件 重量百分比和小于或等于95重量%的二氧化硅(SiO 2/2),并具有以下特征:通过水银孔率法测量的平均孔径包含在20和140之间,a 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间,通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间,包括在 100和550m 2 / g,通过水银孔率法测量的孔体积包含在直径大于140埃,小于0.1ml / g的孔中,孔体积由 包含在直径大于160埃,小于0的孔中的水银孔率法。 1毫升/克,通过水银孔率测定法测量的孔体积,直径大于200埃,小于0.1毫升/克,通过水银孔率法测定的孔体积,包含在直径为 大于500埃,小于0.01ml / g,X衍射图至少包含由α,rho,chi,eta等组成的组中包含的至少一种过渡氧化铝的特征的主线, γ,κ,θ和δ氧化铝。

    Hydrocracking catalyst having a unique silica-alumina substrate
    5.
    发明授权
    Hydrocracking catalyst having a unique silica-alumina substrate 有权
    具有独特二氧化硅 - 氧化铝底物的加氢裂化催化剂

    公开(公告)号:US06733657B2

    公开(公告)日:2004-05-11

    申请号:US10045678

    申请日:2002-01-15

    IPC分类号: C10G4704

    摘要: A hydrocarbon conversion catalyst contains at least one silica-alumina having the following characteristics: A content by weight of silica SiO2 of between 10 and 60% by weight; an Na content less than 300 ppm by weight; a total pore volume of between 0.5 and 1.2 m/g measured by mercury porosimetry; a porosity of said silica-alumina wherein: the volume of mesopores whose diameter is between 40 Å and 150 Å, and whose mean diameter varies between 80 and 120 Å represents between 30 and 80% of the total pore volume, and (ii) the volume of macropores, whose diameter is greater than 500 Å and preferably between 1000 Å and 10,000 Å represents between 20 and 80% of the total pore volume; a specific surface area greater than 200 m2/g, and at least one hydro-dehydrogenating element selected metals of group VIB and group VIII, and optionally phosphorus, boron, silicon, or elements of group VIIA, VIIB or VB.

    摘要翻译: 烃转化催化剂含有至少一种具有以下特征的二氧化硅 - 氧化铝:二氧化硅SiO 2的重量含量为10至60重量%; Na含量小于300重量ppm; 通过水银孔率法测量的总孔体积为0.5-1.2m 2 / g; 所述二氧化硅 - 氧化铝的孔隙率,其中直径为介于40和150之间,其平均直径在80和120之间变化的介孔的体积占总孔体积的30至80%,和(ii) 其直径大于500埃,优选在1000埃至10,000埃之间的大孔体积占总孔体积的20至80%; 比表面积大于200m 2 / g,以及至少一种加氢脱氢元素选择VIB族和VIII族的金属,以及任选的磷,硼,硅或VIIA,VIIB或VB族的元素。

    Process for the production of phenylalkanes that use a catalyst based on silicated alumina
    8.
    发明授权
    Process for the production of phenylalkanes that use a catalyst based on silicated alumina 有权
    制备使用基于硅酸铝的催化剂的苯基烷烃的方法

    公开(公告)号:US07262333B2

    公开(公告)日:2007-08-28

    申请号:US10981740

    申请日:2004-11-05

    IPC分类号: C07C2/68

    摘要: The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the presence of a catalyst that comprises at least one non-zeolitic substrate with a silicated alumina base that contains an amount of more than 6% by weight and less than or equal to 50% by weight of silica (SiO2) and that exhibits particular characteristics, whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.

    摘要翻译: 本发明涉及一种通过至少一种烯烃将芳族化合物烷基化制备至少一种选自2-,3-,4-,5-和6-苯基烷烃的化合物的方法, 在每个分子中包含至少9个碳原子的催化剂存在下,所述催化剂包含至少一种非沸石基质,其中硅烷氧化铝基质含量超过6重量%且小于或等于50重量% 的二氧化硅(SiO 2),并且其表现出特定的特性,由此所述方法在30至400℃的温度下进行,压力为0.1至10MPa,小时体积流速为0.50至200h -1 ,芳香族化合物/烯烃的摩尔比为1:1〜50:1。

    Method for treating a hydrocarbon feedstock including resin removal
    9.
    发明申请
    Method for treating a hydrocarbon feedstock including resin removal 有权
    用于处理包括树脂去除的烃原料的方法

    公开(公告)号:US20070108102A1

    公开(公告)日:2007-05-17

    申请号:US10584048

    申请日:2004-12-13

    IPC分类号: C10G7/00 B01D3/00

    摘要: The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage. Drawing to be published.

    摘要翻译: 本发明涉及一种方法,包括除去树脂,用于处理烃装料,其中至少80%的化合物具有高于或等于340℃的沸点,其中所述装料 送入分馏阶段,在此阶段,回收发生至少一个重馏分和至少一个轻馏分,至少部分重馏分被送至萃取阶段,在此阶段萃取所述重馏分中所含的树脂,以及 回收纯化的馏分,制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物,将得到的混合物送入裂化 阶段。 绘图出版。