公开(公告)号：US5788866A

公开(公告)日：1998-08-04

申请号：US715778

申请日：1996-09-19

申请人： Dodd W. Fong ,  Charles F. Marth ,  Ronald V. Davis

发明人： Dodd W. Fong ,  Charles F. Marth ,  Ronald V. Davis

IPC分类号： C02F5/12 ,  C08F220/04 ,  C08F226/04 ,  C08G73/06 ,  C23F14/02 ,  C02F1/00

CPC分类号： C08G73/0611 ,  C02F5/12

摘要： The invention is a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of an N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine of the formula: ##STR1## wherein R is selected from the group consisting of alkyl and aryl groups, and R.sub.1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups, and an anionic monomer. The invention is also a method of inhibiting the precipitation and deposition of scale on metal surfaces in contact with industrial cooling waters comprising the addition of an effective, scale-inhibiting amount of a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of a betaine of the formula: ##STR2## wherein R is selected from the group consisting of alkyl and aryl groups, and R.sub.1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups, and an anionic monomer. A preferred polymer is a water-soluble copolymer of N,N-diallyl-N-methyl-N-(2-sulfoethyl) ammonium betaine and acrylic acid.

摘要翻译： 本发明是一种水溶性N，N-二烯丙基-N-烷基-N-（磺基烷基）铵甜菜碱共聚物，其中所述共聚物是由N，N-二烯丙基-N-烷基-N-（ 磺基烷基）铵甜菜碱，其结构式如下：其中R选自烷基和芳基，R 1选自烷基，芳基和烷基芳基，和阴离子单体。 本发明还是一种抑制与工业冷却水接触的金属表面沉淀和沉积的方法，包括加入有效的阻垢量的水溶性N，N-二烯丙基-N-烷基-N - （磺基烷基）铵甜菜碱的共聚物，其中所述共聚物由下式的甜菜碱的聚合形成：其中R选自烷基和芳基，R 1选自由以下组成的组： 烷基，芳基和烷芳基，以及阴离子单体。 优选的聚合物是N，N-二烯丙基-N-甲基-N-（2-磺乙基）铵甜菜碱和丙烯酸的水溶性共聚物。

公开(公告)号：US5213691A

公开(公告)日：1993-05-25

申请号：US772173

申请日：1991-10-07

申请人： Daniel H. Emmons ,  Dodd W. Fong ,  Mary A. Kinsella

发明人： Daniel H. Emmons ,  Dodd W. Fong ,  Mary A. Kinsella

IPC分类号： C02F5/14

CPC分类号： C02F5/14 ,  Y10S166/902

摘要： A method of removing from and preventing scale from depositing in underground petroleum containing formations and upon equipment used to inject high brine scale forming waters into such formations which comprises treating such waters with a scale inhibiting amount of an acrylic acid polymer which contains from 0-95 mole percent of acrylamide and from 1-30 mole percent of amido C.sub.1 -C.sub.6 alkyl phosphonate groups from the group consisting of:a) Amidomethyl phosphonate groups,b) Alpha-hydroxy-beta-amidoethyl phosphonate groups,c) Alpha-hydroxy-beta-amidoisopropyl phosphonate groups, and,d) Amidopropyl phosphonate groups said polymer having a molecular weight range between 1,000-100,000.

摘要翻译： 一种从地下含石油地层以及用于将高盐度水垢形成水注入这种地层的设备的方法，其包括用含有0-95的含有水垢抑制量的丙烯酸聚合物 丙烯酰胺的摩尔百分数和1-30摩尔％的由以下组成的组的酰胺基C1-C6烷基膦酸酯基团：a）酰氨基甲基膦酸酯基团，b）α-羟基-β-酰胺基乙基膦酸酯基团，c）α-羟基-β - 酰氨基异丙基膦酸酯基团，和d）酰氨基丙基膦酸酯基团，所述聚合物的分子量范围在1,000-100,000之间。

公开(公告)号：US5049310A

公开(公告)日：1991-09-17

申请号：US419567

申请日：1989-10-10

申请人： Donald A. Johnson ,  John E. Hoots ,  Dodd W. Fong ,  Guy A. Crucil

发明人： Donald A. Johnson ,  John E. Hoots ,  Dodd W. Fong ,  Guy A. Crucil

IPC分类号： C02F5/12 ,  C23F11/08

CPC分类号： C02F5/125 ,  C23F11/08 ,  C23F11/173 ,  C23F14/02

摘要： New zinc stabilizing polymers containing at least 5 mole percent of a monomer represented by the structure: ##STR1## wherein: R is independently, at each occurrence, chosen from H and lower (C.sub.1 -C.sub.4) alkyl groups;R' is a hydrocarbonaceous bridging group containing from 1-12 carbon atoms;X is chosen from --SO.sub.3 M, --OH, --COOM groups or mixtures thereof,M is hydrogen or some other cation species; andn ranges from 1-10,are described. Also, the use of these polymers in combination with zinc salts, and in further combination with phosphate salts, to inhibit corrosion of iron containing metals, and other metals, when these metals are exposed to industrial waters is demonstrated. Deposit control or scale inhibition on these metals exposed to industrial waters is also observed.

摘要翻译： 含有至少5摩尔％的由以下结构表示的单体的新的锌稳定化聚合物：其中：R各自独立地选自H和低级（C 1 -C 4）烷基; R'是含有1-12个碳原子的烃基桥联基团; X选自-SO 3 M，-OH，-COOM基团或其混合物，M是氢或一些其它阳离子物质; 并描述n的范围为1-10。 此外，证明了当这些金属暴露于工业水中时，这些聚合物与锌盐的组合以及与磷酸盐的进一步组合用于抑制含铁金属和其它金属的腐蚀。 也观察到暴露于工业水域的这些金属的沉积物控制或垢垢抑制。

公开(公告)号：US4999456A

公开(公告)日：1991-03-12

申请号：US576880

申请日：1990-09-04

申请人： Dodd W. Fong

发明人： Dodd W. Fong

IPC分类号： C07C233/09 ,  C08F20/54 ,  C09B69/10

CPC分类号： C07C233/09 ,  C08F20/54 ,  C09B69/109 ,  C07C2103/32

摘要： New acrylamide monomer, N-dibenzosuberenylacrylamide, is disclosed. Water soluble polymers containing this monomer are also disclosed.

摘要翻译： 公开了新的丙烯酰胺单体，N-二苯并环丙基丙烯酰胺。 还公开了含有该单体的水溶性聚合物。

公开(公告)号：US4999161A

公开(公告)日：1991-03-12

申请号：US297272

申请日：1989-01-13

申请人： Claudia C. Pierce ,  David A. Grattan ,  Dodd W. Fong

发明人： Claudia C. Pierce ,  David A. Grattan ,  Dodd W. Fong

IPC分类号： C08F8/32 ,  C23F11/173

CPC分类号： C23F11/173 ,  C08F8/12

摘要： The invention is a method of making water-insoluble aliphatic primary or secondary amines, water-soluble or dispersible, which comprises reacting at a temperature of at least 120.degree. C. these amines with water-soluble acrylamide polymer which contains at least 5 mole percent acrylamide to transamidate not more than 50% mole percent of the acrylamide polymer with the water-insoluble aliphatic primary or secondary amine. The invention also covers a water-soluble or dispersible polymeric composition comprising an acrylic acid polymer having a molecular weight within the range of 500-100,000 which contains between 0.5-50 mole percent of the acrylic acid groups in the form of the amides of a water-insoluble aliphatic primary or secondary amine which contains from 10-36 carbon atoms.

摘要翻译： 本发明是制备水不溶性脂族伯或仲胺水溶性或分散性的方法，其包括在至少120℃的温度下使这些胺与水溶性丙烯酰胺聚合物反应，所述丙烯酰胺聚合物含有至少5摩尔％ 丙烯酰胺以不超过50％摩尔百分比的丙烯酰胺聚合物与水不溶性脂族伯或仲胺反应。 本发明还涵盖水溶性或分散性聚合物组合物，其包含分子量在500-100,000范围内的丙烯酸聚合物，其含有0.5-50摩尔％的水形式的丙烯酸基团 不溶性脂族伯或仲胺，其含有10-36个碳原子。

公开(公告)号：US4997890A

公开(公告)日：1991-03-05

申请号：US150459

申请日：1988-01-29

申请人： Dodd W. Fong ,  Ralph W. Kaesler

发明人： Dodd W. Fong ,  Ralph W. Kaesler

IPC分类号： C08F8/34

CPC分类号： C08F220/56 ,  C08F8/34

摘要： Improved methods are provided for the sulfomethylation of high molecular weight polyacrylamide polymers which reduce or minimize cross linking and result in polymers which have a reduced specific viscosity (RSV) greater than the polyacrylamide polymer used as the starting material polymer in the process.

公开(公告)号：US4983686A

公开(公告)日：1991-01-08

申请号：US3349

申请日：1987-01-14

申请人： Ralph W. Kaesler ,  Dodd W. Fong

发明人： Ralph W. Kaesler ,  Dodd W. Fong

IPC分类号： C08F8/34

CPC分类号： C08F8/34 ,  C08F2800/10

摘要： Acrylamide terpolymers which contain from 1-40 mole percent of acrylamido C.sub.1 -C.sub.3 alkyl of C.sub.1 -C.sub.3 hydroxy alkyl sulfonates may be prepared by using as the starting material aqueous acrylamide polymer gels.

摘要翻译： 含有1-40摩尔％的C1-C3羟基烷基磺酸酯的丙烯酰氨基C1-C3烷基的丙烯酰胺三元共聚物可以通过使用丙烯酰胺聚合物水凝胶的原料来制备。

公开(公告)号：US4885345A

公开(公告)日：1989-12-05

申请号：US123759

申请日：1987-11-23

申请人： Dodd W. Fong

发明人： Dodd W. Fong

IPC分类号： C08F8/32 ,  C08F8/44

CPC分类号： C08F8/44 ,  C08F8/32 ,  C08F2800/10

摘要： Pendant amide-containing polymers may be modified in such a way to achieve substituted pendant amide groups described by the structure: ##STR1## wherein: R is chosen from the group consisting of hydrogen and lower alkyl (C.sub.1 -C.sub.4) groups,R.sup.1 is a multivalent hydrocarbonaceous bridging group containing from 1-20 carbon atoms,X is a tertiary amine or a quaternary ammonium salt functional group,Y is chosen from the group consisting of --OR"', and ##STR2## and mixtures thereof, and whereinR'" is chosen from the group consisting of hydrogen, alkyl groups, aryl alkyl, aryl groups and the like,q ranges from 0-50,m ranges from 0-24,n ranges from 0-24, provided that the sum of m plus n is at least 1.Processes for achieving modified polymers having the above functional group is also disclosed.

摘要翻译： 可以以这样的方式修饰含酰胺的聚合物，以实现由以下结构描述的取代的侧酰胺基团：其中：R选自氢和低级烷基（C 1 -C 4）基团，R 1是 含有1-20个碳原子的多价烃基桥接基团，X是叔胺或季铵盐官能团，Y选自-OR“和”IMAGE“及其混合物，其中R “选自氢，烷基，芳基烷基，芳基等，q范围为0-50，m的范围为0-24，n的范围为0-24，条件是 m加上n为至少1.还公开了获得具有上述官能团的改性聚合物的方法。

公开(公告)号：US4868248A

公开(公告)日：1989-09-19

申请号：US327482

申请日：1989-03-22

申请人： John W. Sparapany ,  Dodd W. Fong ,  Josepha M. Fu

发明人： John W. Sparapany ,  Dodd W. Fong ,  Josepha M. Fu

IPC分类号： C08F8/32

CPC分类号： C08F8/32

摘要： Polyacrylic acid polymers are modified with hydroxylamine to convert a portion of the acrylic acid groups in the polymer to hydroxamic acid groups. The process requires utiization of a pH between 1-6 and a temperature ranging between 70.degree.-150.degree. C.

摘要翻译： 用羟胺改性聚丙烯酸聚合物，将聚合物中的一部分丙烯酸基团转化为异羟肟酸基团。 该方法需要使pH在1-6之间，温度在70-150℃之间。

公开(公告)号：US4829121A

公开(公告)日：1989-05-09

申请号：US150443

申请日：1988-01-29

申请人： Dodd W. Fong ,  Ralph W. Kaesler

发明人： Dodd W. Fong ,  Ralph W. Kaesler

IPC分类号： C08F8/34

CPC分类号： C08F8/34 ,  C08F2800/10

摘要： Improved methods of sulfoethylation of high molecular weight polysoap acrylamide containing polymers to produce sulfoethylated acrylamide polymers in water-in-oil latex form having reduced specific viscosities (RSV's) above about 18.

摘要翻译： 改进的高分子量聚丙烯酰胺丙烯酰胺聚合物的磺基乙基化方法，以在油包水胶乳形式中制备磺基乙基化丙烯酰胺聚合物，其具有约18以上降低的比粘度（RSV）。