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公开(公告)号：US4999161A
公开(公告)日：1991-03-12
申请号：US297272
申请日：1989-01-13
IPC分类号： C08F8/32 , C23F11/173
CPC分类号： C23F11/173 , C08F8/12
摘要： The invention is a method of making water-insoluble aliphatic primary or secondary amines, water-soluble or dispersible, which comprises reacting at a temperature of at least 120.degree. C. these amines with water-soluble acrylamide polymer which contains at least 5 mole percent acrylamide to transamidate not more than 50% mole percent of the acrylamide polymer with the water-insoluble aliphatic primary or secondary amine. The invention also covers a water-soluble or dispersible polymeric composition comprising an acrylic acid polymer having a molecular weight within the range of 500-100,000 which contains between 0.5-50 mole percent of the acrylic acid groups in the form of the amides of a water-insoluble aliphatic primary or secondary amine which contains from 10-36 carbon atoms.
摘要翻译： 本发明是制备水不溶性脂族伯或仲胺水溶性或分散性的方法，其包括在至少120℃的温度下使这些胺与水溶性丙烯酰胺聚合物反应，所述丙烯酰胺聚合物含有至少5摩尔％ 丙烯酰胺以不超过50％摩尔百分比的丙烯酰胺聚合物与水不溶性脂族伯或仲胺反应。 本发明还涵盖水溶性或分散性聚合物组合物，其包含分子量在500-100,000范围内的丙烯酸聚合物，其含有0.5-50摩尔％的水形式的丙烯酸基团 不溶性脂族伯或仲胺，其含有10-36个碳原子。
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2.发明授权Chemical modification of (meth)acrylic acid homopolymers and alkyl (meth)acrylate polymers in aqueous systems with amino sulfonic acids 失效（甲基）丙烯酸均聚物和（甲基）丙烯酸烷基酯聚合物在氨基磺酸的水性体系中的化学改性
公开(公告)号：US4604431A
公开(公告)日：1986-08-05
申请号：US800833
申请日：1985-11-22
CPC分类号： C08F8/34
摘要： The invention comprises a method of preparing copolymers of acrylamido sulfonic acids which comprises converting to acrylamido sulfonic groups at least 5 mole % of the acrylic acid or methacrylic acid groups in a polymer which contains at least 5 mole % of these monomers in its structures by reacting an aqueous solution of the acrylic acid or methacrylic acid polymer with an amino sulfonic acid under pressure at a temperature of at least 70.degree. C. for a period of time sufficient to convert at least 5 mole % of the acrylic acid or methacrylic acid groups in the polymer to amido sulfonic acid groups corresponding to the starting amino sulfonic acid.
摘要翻译： 本发明包括一种制备丙烯酰氨基磺酸的共聚物的方法，该方法包括在聚合物中至少5摩尔％的丙烯酸或甲基丙烯酸基团转化为丙烯酰氨基磺酸基团，所述聚合物在其结构中含有至少5摩尔％的这些单体， 丙烯酸或甲基丙烯酸聚合物与氨基磺酸的水溶液在压力下在至少70℃的温度下反应一段足以将至少5摩尔％的丙烯酸或甲基丙烯酸基团转化的时间 聚合物与对应于起始氨基磺酸的酰氨基磺酸基团。
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公开(公告)号：US08153057B2
公开(公告)日：2012-04-10
申请号：US11782192
申请日：2007-07-24
申请人： Peter D. Hicks , David A. Grattan
发明人： Peter D. Hicks , David A. Grattan
CPC分类号： C23F11/08 , C02F1/68 , C02F1/70 , C02F1/72 , C02F2209/006 , C02F2209/04 , C02F2303/08 , F22B37/025 , G05D21/02
摘要： Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed one or more active chemical species into the hot water system.
摘要翻译： 公开了一种控制热水系统中的实时氧化还原电位以抑制热水系统中的腐蚀的方法。 该方法包括在热水系统中定义一个或多个操作保护区。 一个或多个操作保护区包括氧化还原电势探针，其可操作以在操作温度和压力下测量热水系统中的实时氧化还原电位。 探测器将测量的实时电位发送到控制器，控制器评估和解释传输的电位，以确定其是否符合氧化还原电位设置。 如果测量的电位不符合氧化还原电位设置，则控制器可操作地将一种或多种活性化学物质进料到热水系统中。
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公开(公告)号：US20120234756A1
公开(公告)日：2012-09-20
申请号：US13442324
申请日：2012-04-09
申请人： Peter D. Hicks , David A. Grattan
发明人： Peter D. Hicks , David A. Grattan
CPC分类号： C02F1/008 , C02F1/68 , C02F1/70 , C02F1/72 , C02F2209/006 , C02F2209/04 , C02F2303/08 , C23F11/08 , C23F15/00 , F22B37/025 , F22D11/006 , G05D21/02
摘要： Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.
摘要翻译： 公开了一种控制热水系统中的实时氧化还原电位以抑制热水系统中的腐蚀的方法。 该方法包括在热水系统中定义一个或多个操作保护区。 一个或多个操作保护区包括氧化还原电势探针，其可操作以在操作温度和压力下测量热水系统中的实时氧化还原电位。 探测器将测量的实时电位发送到控制器，控制器评估和解释传输的电位，以确定其是否符合氧化还原电位设置。 如果测量的电位不符合氧化还原电位设置，则控制器可操作地将一种或多种活性化学物质进入或从热水系统中取出或移除，并且还可操作以改变至少一个系统参数。
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5.发明申请METHOD AND DEVICE FOR CLEANUP AND DEPOSIT REMOVAL FROM INTERNAL HOT WATER SYSTEM SURFACES 有权从内部热水系统表面清洗和沉积物去除的方法和装置公开(公告)号：US20090065440A1
公开(公告)日：2009-03-12
申请号：US11852695
申请日：2007-09-10
申请人： Peter D. Hicks , David A. Grattan
发明人： Peter D. Hicks , David A. Grattan
CPC分类号： C23F11/08 , C02F5/08 , C02F2209/008 , C02F2209/04 , C02F2303/08 , C23F15/00 , F22B37/025 , G05D21/02
摘要： Disclosed is a method of inhibiting and/or removing deposits from internal surfaces in a hot water system. The method includes controlling a real-time oxidation-reduction potential in a hot water system to alter the dynamic between deposit constituents and the bulk water of the system to inhibit deposition or initiate deposit removal. The method is equally effective for a system undergoing a wet layup sequence or in an online operational system. The invention further includes a multi-component deposit inhibition and/or removal device, including a receiver, a processor, and a transmitter that work in unison to alter the system dynamics to inhibit or remove deposits.
摘要翻译： 公开了一种抑制和/或去除热水系统内表面沉积物的方法。 该方法包括控制热水系统中的实时氧化还原电位以改变沉积物组分与系统的体积水之间的动态，以抑制沉积或开始沉积物去除。 该方法对于经历湿铺层序列的系统或在线操作系统中同样有效。 本发明还包括多组分沉积抑制和/或去除装置，包括接收器，处理器和发射器，其一致地工作以改变系统动力学以抑制或去除沉积物。
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6.发明申请公开(公告)号：US20080169243A1
公开(公告)日：2008-07-17
申请号：US11622054
申请日：2007-01-11
IPC分类号： C02F5/14
CPC分类号： C02F5/14 , C02F1/042 , C02F1/44 , C02F5/12 , C02F2103/08 , C02F2303/08 , Y02A20/128 , Y02A20/131 , Y02W10/37
摘要： This invention relates to an improved method of inhibiting corrosion and calcium sulfate and calcium carbonate scaling in thermal and membrane desalination processes. The method includes adding a composition having an oligomeric phosphinosuccinic acid to seawater or recirculation brine in a desalting process to produce water for drinking and industrial applications. The method also includes adding a composition including mono, bis, and oligomeric phosphinosuccinic acid adducts to the desalting process.
摘要翻译： 本发明涉及在热和膜脱盐方法中抑制腐蚀和硫酸钙和碳酸钙结垢的改进方法。 该方法包括在脱盐过程中向海水或再循环盐水中加入具有低聚磷酸琥珀酸的组合物以产生用于饮用和工业应用的水。 该方法还包括向脱盐过程中加入包含单，双和低聚磷酸琥珀酸加成物的组合物。
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7.发明授权Use of benzo and tolyltriazole as copper corrosion inhibitors for boiler condensate systems 失效苯并甲苯三唑作为锅炉冷凝水系统的铜腐蚀抑制剂
公开(公告)号：US4657785A
公开(公告)日：1987-04-14
申请号：US807639
申请日：1985-12-11
CPC分类号： C23F11/14 , C23F11/149
摘要： The use of benzo and/or tolyltriazole alone or in combination with neutralizing and filming amines to reduce copper corrosion in boiler condensate systems by feeding the mixture into the main steamheaders.
摘要翻译： 单独使用苯并和/或甲苯基三唑或与中和和成膜胺组合使用，以通过将混合物进料到主蒸汽头中来减少锅炉冷凝水系统中的铜腐蚀。
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8.发明授权公开(公告)号：US08906202B2
公开(公告)日：2014-12-09
申请号：US12428792
申请日：2009-04-23
IPC分类号： G08B21/00 , C02F1/00 , C23F11/08 , F22B37/02 , C02F103/28
CPC分类号： C23F11/08 , C02F1/008 , C02F2103/28 , C02F2209/04 , C02F2209/06 , C02F2303/08 , C23F15/00 , F22B37/025
摘要： This invention relates to a method and system for detecting contamination of boiler condensate and/or boiler feedwater in a papermaking process. The method includes measuring an oxidation-reduction potential at one or more locations in the boiler condensate and/or the boiler feedwater of the papermaking process with one or more corrosion stress monitoring devices. A controller is operable to assess whether the measured or a calculated oxidation-reduction potential is within an optimum range. The controller is operable to cause transmission of a signal to direct feeding an effective amount of one or more reductants and/or one or more pH-controlling chemicals into the boiler feedwater and/or one or more a satellite feed locations of the papermaking process.
摘要翻译： 本发明涉及一种在造纸过程中检测锅炉冷凝水和/或锅炉给水污染的方法和系统。 该方法包括用一个或多个腐蚀应力监测装置测量造纸工艺的锅炉冷凝水和/或锅炉给水中的一个或多个位置处的氧化还原电位。 控制器可操作以评估所测量的或计算的氧化还原电位是否在最佳范围内。 控制器可操作以使信号的传输直接将有效量的一种或多种还原剂和/或一种或多种pH控制化学品输送到造纸工艺的锅炉给水和/或一个或多个卫星进料位置。
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公开(公告)号：US08771593B2
公开(公告)日：2014-07-08
申请号：US13442324
申请日：2012-04-09
申请人： Peter D. Hicks , David A. Grattan
发明人： Peter D. Hicks , David A. Grattan
CPC分类号： C02F1/008 , C02F1/68 , C02F1/70 , C02F1/72 , C02F2209/006 , C02F2209/04 , C02F2303/08 , C23F11/08 , C23F15/00 , F22B37/025 , F22D11/006 , G05D21/02
摘要： Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.
摘要翻译： 公开了一种控制热水系统中的实时氧化还原电位以抑制热水系统中的腐蚀的方法。 该方法包括在热水系统中定义一个或多个操作保护区。 一个或多个操作保护区包括氧化还原电势探针，其可操作以在操作温度和压力下测量热水系统中的实时氧化还原电位。 探测器将测量的实时电位发送到控制器，控制器评估和解释传输的电位，以确定其是否符合氧化还原电位设置。 如果测量的电位不符合氧化还原电位设置，则控制器可操作地将一种或多种活性化学物质进入或从热水系统中取出或移除，并且还可操作以改变至少一个系统参数。
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10.发明申请METHOD AND DEVICE FOR PREVENTING CORROSION IN HOT WATER SYSTEMS UNDERGOING INTERMITTENT OPERATIONS 有权用于防止在干扰操作中的热水系统中的腐蚀的方法和装置公开(公告)号：US20090065439A1
公开(公告)日：2009-03-12
申请号：US11852616
申请日：2007-09-10
申请人： Peter D. Hicks , David A. Grattan
发明人： Peter D. Hicks , David A. Grattan
CPC分类号： G05D21/02 , C02F1/008 , C02F1/66 , C02F1/70 , C02F1/72 , C02F2209/02 , C02F2209/04 , C02F2303/08 , C23F15/00 , F22B37/025
摘要： Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system undergoing a wet layup sequence to inhibit corrosion in the hot water system. The method includes separating the wet layup sequence into a plurality of phases. Each phase is either short-term or long-term and a subset of the short-term phases is optionally transitional. The method further includes defining one or more zones in the hot water system. At least one of the defined zones is selected for each phase and one or more of the selected zones include at least one ORP probe operable to measure the real-time ORP and communicate with a controller. The ORP probe(s) either intermittently or continuously measure the real-time ORP at operating temperature and pressure at one or more of the selected zones in one or more of the phases and transmit the measured real-time ORP to the controller. The real-time ORP is assessed to determine whether it conforms to an ORP setting for that phase. The invention further includes a multi-component control device for a hot water system undergoing a wet layup sequence.
摘要翻译： 公开了一种在经受湿铺层序列的热水系统中控制实时氧化还原电位以抑制热水系统中的腐蚀的方法。 该方法包括将湿铺层序列分离成多个相。 每个阶段都是短期的或长期的，短期阶段的一个子集可以选择是过渡的。 该方法还包括限定热水系统中的一个或多个区域。 为每个阶段选择至少一个定义的区域，并且所选择的区域中的一个或多个包括至少一个可操作以测量实时ORP并与控制器通信的ORP探测器。 在一个或多个相中的一个或多个所选区域中，ORP探头间歇地或连续地测量操作温度和压力下的实时ORP，并将测量的实时ORP传送到控制器。 评估实时ORP以确定其是否符合该阶段的ORP设置。 本发明还包括用于经受湿铺层序列的热水系统的多组分控制装置。
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