Chemical modification of (meth)acrylic acid homopolymers and alkyl
(meth)acrylate polymers in aqueous systems with amino sulfonic acids
    1.
    发明授权
    Chemical modification of (meth)acrylic acid homopolymers and alkyl (meth)acrylate polymers in aqueous systems with amino sulfonic acids 失效
    (甲基)丙烯酸均聚物和(甲基)丙烯酸烷基酯聚合物在氨基磺酸的水性体系中的化学改性

    公开(公告)号:US4604431A

    公开(公告)日:1986-08-05

    申请号:US800833

    申请日:1985-11-22

    IPC分类号: C08F8/34 C08F8/36

    CPC分类号: C08F8/34

    摘要: The invention comprises a method of preparing copolymers of acrylamido sulfonic acids which comprises converting to acrylamido sulfonic groups at least 5 mole % of the acrylic acid or methacrylic acid groups in a polymer which contains at least 5 mole % of these monomers in its structures by reacting an aqueous solution of the acrylic acid or methacrylic acid polymer with an amino sulfonic acid under pressure at a temperature of at least 70.degree. C. for a period of time sufficient to convert at least 5 mole % of the acrylic acid or methacrylic acid groups in the polymer to amido sulfonic acid groups corresponding to the starting amino sulfonic acid.

    摘要翻译: 本发明包括一种制备丙烯酰氨基磺酸的共聚物的方法,该方法包括在聚合物中至少5摩尔%的丙烯酸或甲基丙烯酸基团转化为丙烯酰氨基磺酸基团,所述聚合物在其结构中含有至少5摩尔%的这些单体, 丙烯酸或甲基丙烯酸聚合物与氨基磺酸的水溶液在压力下在至少70℃的温度下反应一段足以将至少5摩尔%的丙烯酸或甲基丙烯酸基团转化的时间 聚合物与对应于起始氨基磺酸的酰氨基磺酸基团。

    Modified polymers incorporating fatty amines
    2.
    发明授权
    Modified polymers incorporating fatty amines 失效
    掺入脂肪胺的改性聚合物

    公开(公告)号:US4999161A

    公开(公告)日:1991-03-12

    申请号:US297272

    申请日:1989-01-13

    IPC分类号: C08F8/32 C23F11/173

    CPC分类号: C23F11/173 C08F8/12

    摘要: The invention is a method of making water-insoluble aliphatic primary or secondary amines, water-soluble or dispersible, which comprises reacting at a temperature of at least 120.degree. C. these amines with water-soluble acrylamide polymer which contains at least 5 mole percent acrylamide to transamidate not more than 50% mole percent of the acrylamide polymer with the water-insoluble aliphatic primary or secondary amine. The invention also covers a water-soluble or dispersible polymeric composition comprising an acrylic acid polymer having a molecular weight within the range of 500-100,000 which contains between 0.5-50 mole percent of the acrylic acid groups in the form of the amides of a water-insoluble aliphatic primary or secondary amine which contains from 10-36 carbon atoms.

    摘要翻译: 本发明是制备水不溶性脂族伯或仲胺水溶性或分散性的方法,其包括在至少120℃的温度下使这些胺与水溶性丙烯酰胺聚合物反应,所述丙烯酰胺聚合物含有至少5摩尔% 丙烯酰胺以不超过50%摩尔百分比的丙烯酰胺聚合物与水不溶性脂族伯或仲胺反应。 本发明还涵盖水溶性或分散性聚合物组合物,其包含分子量在500-100,000范围内的丙烯酸聚合物,其含有0.5-50摩尔%的水形式的丙烯酸基团 不溶性脂族伯或仲胺,其含有10-36个碳原子。

    Synthesis of hydrophobic/alkoxylated polymers
    5.
    发明授权
    Synthesis of hydrophobic/alkoxylated polymers 失效
    疏水/烷氧基聚合物的合成

    公开(公告)号:US5075390A

    公开(公告)日:1991-12-24

    申请号:US548838

    申请日:1990-07-06

    申请人: Dodd W. Fong

    发明人: Dodd W. Fong

    IPC分类号: C08F8/32

    CPC分类号: C08F8/32

    摘要: The preparation of polymers which contain pendant hydrophobic groups or a mixture of both pendant hydrophobic and alkoxylated groups is accomplished by reacting a preexisting polymer having pendant acid amide and/or carboxylic groups with a primary or secondary amine in a substantially homogenous reaction mixture, the amine reactant including the desired hydrophobic and alkoxylated radicals. A unique polymer, having both pendant hydrophobic and alkoxylated groups, is provided.

    Alkoxylated/cationically modified amide-containing polymers
    6.
    发明授权
    Alkoxylated/cationically modified amide-containing polymers 失效
    烷氧基化/阳离子改性含酰胺的聚合物

    公开(公告)号:US4970290A

    公开(公告)日:1990-11-13

    申请号:US163220

    申请日:1988-02-26

    申请人: Dodd W. Fong

    发明人: Dodd W. Fong

    IPC分类号: C08F8/32 C08F8/44

    CPC分类号: C08F8/44 C08F2800/10

    摘要: Pendant amide-containing polymers may be modified in such a way to achieve substituted pendant amide groups described by the structure: ##STR1## wherein: R is chosen from the group consisting of hydrogen and lower alkyl (C.sub.1 -C.sub.4) groups,R.sup.1 is a multivalent hydrocarbonaceous bridging group containing from 1-20 carbon atoms,X is a tertiary amine or a quaternary ammonium salt functional group,Y is chosen from the group consisting of --OR'", and ##STR2## and mixtures thereof, and whereinR'" is chosen from the group consisting of hydrogen, alkyl groups, aryl alkyl, aryl groups and the like,q ranges from 0-50,m ranges from -24,n ranges from 0-24, provided that the sum of m plus n is at least 1.Processes for achieving modified polymers having the above functional group is also disclosed.

    摘要翻译: 可以以这样的方式修饰含酰胺的聚合物,以实现由以下结构描述的取代的侧酰胺基团:其中:R选自氢和低级烷基(C 1 -C 4)基团,R 1是 含有1-20个碳原子的多价烃基桥接基团,X是叔胺或季铵盐官能团,Y选自-OR“和”IMAGE“及其混合物,其中R “选自氢,烷基,芳基烷基,芳基等,q范围为0-50,m的范围为-24,n的范围为0-24,条件是m的和 加上n至少为1.还公开了获得具有上述官能团的改性聚合物的方法。

    Cooling water corrosion inhibition method
    7.
    发明授权
    Cooling water corrosion inhibition method 失效
    冷却水腐蚀抑制方法

    公开(公告)号:US4923634A

    公开(公告)日:1990-05-08

    申请号:US155393

    申请日:1988-02-12

    IPC分类号: C23F11/08

    CPC分类号: C23F11/08

    摘要: A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, where R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms,and substituted alkyl of from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide, (poly)carboxy and (poly)hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.

    摘要翻译: 一种通过用含有能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐的组合物给予水,并且含有至少为6.5的烃聚合物的含有硬度和pH至少为6.5的工业冷却水中的腐蚀的方法 具有酰胺结构的N-取代丙烯酰胺聚合物如下:其中R 2是氢或甲基,其中R 1是氢或烷基,R是亚烷基或亚苯基,X是磺酸根,(多)羟基,(聚) 羧基或羰基,及其组合; 或含有具有N-取代的马来酰胺酸单元,N-取代的马来酰亚胺单元和具有如下结构的马来酸(和盐)单元的衍生化马来酸酐均聚物,共聚物和三元共聚物:其中R 1,R 2和R 3各自为 独立地选自氢,羟基,羧基烷基,羧基酰胺,苯基,取代的苯基,1至10个碳原子的直链或支链烷基和1至10个碳原子的取代烷基,其中取代基是膦酸; 次膦酸 磷酸酯; 磺酸 硫酸酯,羧酰胺,(多)羧基和(多)羟基,烷氧基和羧酸酯基团; 及其组合。

    Process for preparing high molecular weight hydrophobic acrylamide
polymers
    8.
    发明授权
    Process for preparing high molecular weight hydrophobic acrylamide polymers 失效
    制备高分子量疏水性丙烯酰胺聚合物的方法

    公开(公告)号:US4921903A

    公开(公告)日:1990-05-01

    申请号:US256339

    申请日:1988-10-11

    申请人: Dodd W. Fong

    发明人: Dodd W. Fong

    IPC分类号: C08F8/32

    CPC分类号: C08F8/32

    摘要: A process of making a water-in-oil emulsion which contains from 5-60% by weight of a hydrophobic acrylamide terpolymer composed of the random repeating units: ##STR1## where: R is methyl or hydrogen,M is hydrogen, alkali metal, ammonia, or amine,R.sup.1 is a hydrophobic radical,with the mol ratio of A:B:C being A(2-50):B(50-98):C(0.1-15), which comprises reacting a 5-60% by weight water-in-oil emulsion of an acrylamide polymer with a hydrophobic amine at a temperature above 120.degree. C. for a period of time sufficient to transamidate the acrylamide groups in the acrylamide polymer with the hydrophobic amine.

    摘要翻译: 一种制备油包水乳液的方法,其包含5-60重量%的由无规重复单元组成的疏水丙烯酰胺三元共聚物:其中:R是甲基或氢,M是氢,碱金属, 氨或胺,R1是疏水基团,A:B:C的摩尔比为A(2-50):B(50-98):C(0.1-15),其包括使5-60 重量%的丙烯酰胺聚合物与疏水性胺在温度高于120℃下的油包水乳液一段足以使丙烯酰胺聚合物中的丙烯酰胺基团与疏水胺转酰胺化的时间。

    AMPIQ copolymers as scale inhibitors
    10.
    发明授权
    AMPIQ copolymers as scale inhibitors 失效
    AMPIQ共聚物作为阻垢剂

    公开(公告)号:US4657679A

    公开(公告)日:1987-04-14

    申请号:US839236

    申请日:1986-03-13

    申请人: Dodd W. Fong

    发明人: Dodd W. Fong

    IPC分类号: C02F5/12

    CPC分类号: C02F5/12

    摘要: A method is disclosed to control calcium phosphate scale by using an effective amount of an ampholytic polymer synthesized from acrylic acid, methacrylic acid, and the quaternary salts of 1-acryloyl-4-methyl piperizine, or mixtures thereof.

    摘要翻译: 公开了一种通过使用有效量的由丙烯酸,甲基丙烯酸和1-丙烯酰基-4-甲基哌嗪的季盐合成的两性聚合物或其混合物来控制磷酸钙垢的方法。