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公开(公告)号:US4556723A
公开(公告)日:1985-12-03
申请号:US712228
申请日:1985-03-15
CPC分类号: C07F7/1856 , C07C45/64 , C07C45/673 , C07C49/83 , C07C49/84 , C07F3/02
摘要: Process for the production of an acyloin comprising the steps of:A. reacting a Grignard reagent with silylated cyanohydrin,B. treating the reaction product of step A with aqueous acid, andC. recovering the resulting acyloin.Acyloins thus formed are useful as photoinitiators for initiation of free radical polymerization reactions.
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公开(公告)号:US4524221A
公开(公告)日:1985-06-18
申请号:US468719
申请日:1983-02-22
CPC分类号: C07F3/02 , C07C45/64 , C07C45/673 , C07C49/83 , C07C49/84 , C07F7/1856
摘要: Process for the production of an acyloin comprising the steps of:A. reacting a Grignard reagent with silylated cyanohydrin,B. treating the reaction product of step A with aqueous acid, andC. recovering the resulting acyloin.Acyloins thus formed are useful as photoinitiators for initiation of free radical polymerization reactions.
摘要翻译: 用于生产丙交酯的方法,包括以下步骤:A.使格利雅试剂与甲硅烷基化的氰醇反应,B.用酸水溶液处理步骤A的反应产物,和C.回收所得的偶姻蛋白。 由此形成的叶绿素可用作引发自由基聚合反应的光引发剂。
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公开(公告)号:US4451619A
公开(公告)日:1984-05-29
申请号:US429986
申请日:1982-09-30
CPC分类号: C08F8/00
摘要: A method of modifying the overall hydrophilic or hydrophobic nature of a high molecular weight free radical addition interpolymer, which is an azlactone-functional interpolymer, with a hydrophilic or hydrophobic nucleophilic compound is disclosed. Only the surface of the interpolymer can by hydrophilized or hydrophobized, as when the interpolymer is a coating, or the modification can take place throughout the entire bulk of the interpolymer.
摘要翻译: 公开了一种改进具有亲水或疏水亲核化合物的高分子量自由基加成互聚物(其是吖内酯官能互聚物)的整体亲水性或疏水性的方法。 只有互聚物的表面可以通过亲水化或疏水化,如互聚物是涂层时,或者可以在互聚物的整个整体上进行改性。
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公开(公告)号:US06998179B2
公开(公告)日:2006-02-14
申请号:US10872749
申请日:2004-06-21
申请人: Duane D. Fansler , Todd D. Jones , Babu N. Gaddam , Robert T. Fitzsimons , Steven M. Heilmann , John J. Cael
发明人: Duane D. Fansler , Todd D. Jones , Babu N. Gaddam , Robert T. Fitzsimons , Steven M. Heilmann , John J. Cael
IPC分类号: B32B27/30
CPC分类号: G02B5/3033 , B32B7/00 , B32B27/08 , C08F8/30 , C08F2800/20 , Y10S428/91 , Y10T428/31855 , Y10T428/31909 , Y10T428/31924 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938 , C08F2220/1858
摘要: A process for preparing a polarizer is described whereby an article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a photoacid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.
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公开(公告)号:US06911510B2
公开(公告)日:2005-06-28
申请号:US10820204
申请日:2004-04-07
申请人: Kevin M. Lewandowski , Duane D. Fansler , Michael S. Wendland , Steven M. Heilmann , Babu N. Gaddam
发明人: Kevin M. Lewandowski , Duane D. Fansler , Michael S. Wendland , Steven M. Heilmann , Babu N. Gaddam
IPC分类号: C07D263/42 , C08F2/38 , C08F2/50 , C08F293/00 , C08F4/00
CPC分类号: C07D263/42 , C08F2/38 , C08F293/005 , C08F2438/03
摘要: Chain transfer agents for controlled radical polymerizations (RAFT) are described. The chain transfer agents have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.
摘要翻译: 描述了用于受控自由基聚合(RAFT)的链转移剂。 链转移剂具有吖内酯或开环的吖内酯部分以提供遥爪(共)聚合物。
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26.
公开(公告)号:US06841637B2
公开(公告)日:2005-01-11
申请号:US10807007
申请日:2004-03-23
申请人: Kevin M. Lewandowski , Duane D. Fansler , Michael S. Wendland , Babu N. Gaddam , Steven M. Heilmann
发明人: Kevin M. Lewandowski , Duane D. Fansler , Michael S. Wendland , Babu N. Gaddam , Steven M. Heilmann
CPC分类号: C08F2/38
摘要: Chain transfer agents for controlled radical polymerizations (RAFT) are described. The chain transfer agents have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.
摘要翻译: 描述了用于受控自由基聚合(RAFT)的链转移剂。 链转移剂具有吖内酯或开环的吖内酯部分以提供遥爪(共)聚合物。
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公开(公告)号:US06818716B2
公开(公告)日:2004-11-16
申请号:US10822479
申请日:2004-04-12
申请人: Michael S. Wendland , Kevin M. Lewandowski , Duane D. Fansler , Babu N. Gaddam , Steven M. Heilmann
发明人: Michael S. Wendland , Kevin M. Lewandowski , Duane D. Fansler , Babu N. Gaddam , Steven M. Heilmann
IPC分类号: C08F400
摘要: Photoiniferters for controlled radical polymerizations and telechelic copolymers comprising polymerized units of one or more free radically (co)polymerizable monomers having a first azalactone terminal group and a second dithiocarbamate terminal group are described.
摘要翻译: 描述了用于受控自由基聚合的光引发剂和遥爪共聚物,其包含具有第一氮杂内酯末端基团和第二二硫代氨基甲酸酯末端基团的一种或多种自由基(共)可聚合单体的聚合单元。
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公开(公告)号:US06635690B2
公开(公告)日:2003-10-21
申请号:US09884173
申请日:2001-06-19
申请人: Steven M. Heilmann , Babu N. Gaddam , Ahmed S. Abuelyaman , Duane D. Fansler , Todd D. Jones , Maureen A. Kavanagh , Kevin M. Lewandowski , Michael S. Wendland
发明人: Steven M. Heilmann , Babu N. Gaddam , Ahmed S. Abuelyaman , Duane D. Fansler , Todd D. Jones , Maureen A. Kavanagh , Kevin M. Lewandowski , Michael S. Wendland
IPC分类号: C08L8700
CPC分类号: C09D201/005 , C09D201/08
摘要: The present invention provides novel compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.
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公开(公告)号:US5679779A
公开(公告)日:1997-10-21
申请号:US447852
申请日:1995-05-23
申请人: Steven M. Heilmann , Gary J. Drtina , Louis C. Haddad , Frederick W. Hyde , Dean M. Moren , Robert A. Pranis
发明人: Steven M. Heilmann , Gary J. Drtina , Louis C. Haddad , Frederick W. Hyde , Dean M. Moren , Robert A. Pranis
IPC分类号: B01J31/06 , A61K47/32 , C08F20/36 , C08F212/36 , C08F220/20 , C08F220/34 , C08F220/36 , C08F220/56 , C08G18/64 , C08G18/72 , C12N11/08 , C08K17/02
CPC分类号: C08G18/728 , C08F20/36 , C08F220/36 , C08G18/6446 , C12N11/08 , Y10S530/815
摘要: Insoluble supports are prepared which possess high surface areas and efficiently dispersed isocyanate groups. These reactive supports are useful for covalently binding proteins which preferably are enzymes and provide catalysts for conducting organic reactions.
摘要翻译: 制备具有高表面积和有效分散的异氰酸酯基团的不溶性载体。 这些反应性支持物可用于共价结合蛋白质,其优选为酶并提供用于进行有机反应的催化剂。
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30.
公开(公告)号:US5614105A
公开(公告)日:1997-03-25
申请号:US425585
申请日:1995-04-20
申请人: Steven M. Heilmann , Gary J. Drtina , Philip D. Eitzman , Louis C. Haddad , Frederick W. Hyde , Todd W. Johnson
发明人: Steven M. Heilmann , Gary J. Drtina , Philip D. Eitzman , Louis C. Haddad , Frederick W. Hyde , Todd W. Johnson
摘要: Insolubilized enzyme particulates are located on the upstream surface of a filtration layer of a filtering element which can be used in a cartridge filter. Employed in a recycling flow reaction system at relatively high flux rates, the cartridges are useful for conducting catalyzed chemical reactions of dissolved solutes, for example, esterifications, isomerizations, oxidations, reductions, and cyclizations.
摘要翻译: 不溶解的酶微粒位于可用于筒式过滤器的过滤元件的过滤层的上游表面上。 在相对较高的通量速率下在回收流动反应系统中使用,所述筒可用于进行溶解的溶质的催化化学反应,例如酯化,异构化,氧化,还原和环化。
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