Novel methine compounds, polymers containing them and formed articles
therefrom
    22.
    发明授权
    Novel methine compounds, polymers containing them and formed articles therefrom 失效
    新型次甲基化合物,含有它们的聚合物和由其形成的制品

    公开(公告)号:US5086161A

    公开(公告)日:1992-02-04

    申请号:US701401

    申请日:1991-05-06

    摘要: A composition useful for incorporation into polymer compositions employed for food packaging or the like comprising a bis- or tris-methine compound having the structural formula ##STR1## wherein A is selected from the radicals ##STR2## wherein R' and R" are each selected from chlorine, bromine, fluorine, alkyl, alkoxy, aryl, aryloxy and arylthio;each n is independently 0, 1, 2;R.sub.1 is selected from a large variety of radicals such as cycloalkyl, phenyl, and straight or branched alkyl which may be subsituted;R.sub.2 is alkylene or the like;R.sub.3, R.sub.4, and R.sub.5 are each selected from hydrogen and alkyl; andP and Q and P.sup.1 and Q.sup.1 are selected from cyano, carbalkoxy, carbaryloxy, carbaralkyloxy, or the like.The invention compositions are especially useful in combination with molding or fiber-grade condensation polymer; most preferably such polymer having compolymerized therein a total of from 1.0 to about 100,000 ppm, of the reactant residue moieties of one or more of such bis- or tris-methine compounds.

    摘要翻译: 可用于掺入用于食品包装等的聚合物组合物中的组合物,其包含具有结构式为“IMAGE”的双或三 - 次甲基化合物,其中A选自基团 其中R'和R“各自选自氯,溴,氟,烷基,烷氧基,芳基,芳氧基和芳硫基; 每个n独立地为0,1,2; R1选自各种各样的基团,例如环烷基,苯基和可以被取代的直链或支链烷基; R2是亚烷基等; R3,R4和R5各自选自氢和烷基; 并且P和Q以及P1和Q1选自氰基,烷氧基,碳酰氧基,卡巴尔基氧基等。 本发明组合物特别适用于成型或纤维级缩聚物; 最优选地,其中共聚合有总共为1.0至约100,000ppm的一种或多种这样的双 - 或三 - 次甲基化合物的反应物残余部分的这种聚合物。

    Condensation polymer containing copolymerized colorants derived from
indigo and articles produced therefrom
    24.
    发明授权
    Condensation polymer containing copolymerized colorants derived from indigo and articles produced therefrom 失效
    含有衍生自靛蓝的共聚着色剂和由其制备的制品的缩合聚合物

    公开(公告)号:US4808677A

    公开(公告)日:1989-02-28

    申请号:US153635

    申请日:1988-02-08

    CPC分类号: C09B69/109 C08G63/685

    摘要: Disclosed are colored compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising condensation polymer having reacted therewith or copolymerized therein a coloring amount of the residue of a colorant compound having the formula; ##STR1## wherein R.sup.1 is ##STR2## carbonyl halide or an unsubstituted or substituted carbocyclic or hetrocyclic aryl radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl or acyl radical;R.sup.3 is any of the substituents which R.sup.1 may represent; andA.sup.1 and A.sup.2 each is the residue of a fused benzene ring; whereinR.sup.4 is hydrogen, allyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; andR.sup.5 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; provided the colorant compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The colorant compound residues are present in the polymer chain and impart a red color to the polymer. The residues are nonextractable from the polymer and stable at the condition at which the polymers are prepared and processed.

    摘要翻译: 公开了可用于模制成诸如食品容器,饮料瓶,固化的结构塑料等制品的着色组合物,其包含与其反应或与其共聚的具有下式的着色剂化合物的着色量的缩聚物; 或者其中R 1为羰基卤或未取代或取代的碳环或杂环芳基的“IMAGE”或“IMAGE” R2是氢或未取代或取代的烷基或酰基; R3是R1可以表示的任何取代基; A1和A2各自为稠合苯环的残基; 其中R4是氢,烯丙基或未取代或取代的烷基,环烷基或芳基; 并且R 5是氢或未取代或取代的烷基,环烷基或芳基; 只要着色剂化合物具有至少一个与衍生缩合聚合物的单体之一反应的取代基。 着色剂化合物残基存在于聚合物链中并赋予聚合物红色。 残余物不可聚合,并且在制备和加工聚合物的条件下是稳定的。

    Lignin and lignin derivatives as copolymerizable colorants for polyesters
    25.
    发明授权
    Lignin and lignin derivatives as copolymerizable colorants for polyesters 失效
    木质素和木质素衍生物作为聚酯的共聚着色剂

    公开(公告)号:US4803255A

    公开(公告)日:1989-02-07

    申请号:US64646

    申请日:1987-06-22

    IPC分类号: C08G63/46 C08H5/02 C08G63/02

    CPC分类号: C08H6/00 C08G63/46

    摘要: Colored shapable polyesters having copolymerized therein lignin or lignin derivatives are prepared by condensing the lignin or lignin derivatives into the polyester backbone during the polymerization reaction. The lignin moieties are thermally stable at the polymer processing temperatures and are nonextractable from the polyester backbone. These colored, shapable polyesters are particularly suitable for use in food, beverage, pharmaceutical, or cosmetic container applications.

    摘要翻译: 在其中共聚有木质素或木质素衍生物的着色可成形聚酯通过在聚合反应期间将木质素或木质素衍生物缩合成聚酯主链来制备。 木质素部分在聚合物加工温度下是热稳定的,并且不能从聚酯骨架脱模。 这些有色成型聚酯特别适用于食品,饮料,药物或化妆品容器应用。

    UV-absorbing condensation polymeric compositions and products therefrom
    28.
    发明授权
    UV-absorbing condensation polymeric compositions and products therefrom 失效
    紫外线吸收缩合聚合物组合物及其产品

    公开(公告)号:US4707537A

    公开(公告)日:1987-11-17

    申请号:US913204

    申请日:1986-09-30

    CPC分类号: C08G63/68

    摘要: Polyester compositions useful in formed articles such as beverage bottles and having condensation reacted therein at least one UV-absorbing compound of the formula ##STR1## wherein X is hydroxyl, carboxy, carbalkoxy, substituted carbalkoxy, or acyloxy; Y is cyano, carbamyl, substituted carbamyl, aryl, acyl, alkylsulfonyl, substituted alkylsulfonyl, phenylsulfonyl, or substituted phenylsulfonyl; R is selected from -alkylene-O-alkylene-, -alkylene-S-alkylene-, -alkylene-N(-SO.sub.2 alkyl)-alkylene-, straight or branched chain alkylene or such alkylene substituted with an X substituent; and R.sub.1 is hydrogen or 1-3 groups selected from alkyl, alkoxy and halogen.

    摘要翻译: 用于成型制品例如饮料瓶并且具有缩合反应的聚酯组合物其中X是羟基,羧基,烷氧基,取代的烷氧羰基或酰氧基的至少一种下式的UV吸收化合物: Y是氰基,氨甲酰基,取代的氨基甲酰基,芳基,酰基,烷基磺酰基,取代的烷基磺酰基,苯基磺酰基或取代的苯基磺酰基; R选自亚烷基-O-亚烷基 - 亚烷基-S-亚烷基 - 亚烷基-N(-SO 2烷基) - 亚烷基 - ,直链或支链亚烷基或被X取代基取代的亚烷基; 并且R 1是氢或选自烷基,烷氧基和卤素的1-3个基团。