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公开(公告)号：US5110670A
公开(公告)日：1992-05-05
申请号：US365711
申请日：1989-06-14
CPC分类号： B32B27/20 , D21H19/02 , D21H27/30 , Y10T428/24975 , Y10T428/249969 , Y10T428/24997 , Y10T428/249986 , Y10T428/252 , Y10T428/254 , Y10T428/258 , Y10T428/259 , Y10T428/31913
摘要： A biaxially stretch-oriented film, suitable for the process of transfer metallizing, which comprises a base layer coextruded with covering layers on either side thereof and comprising an inert admixture is disclosed. The three layers are formed of polyolefin and the base layer comprises an additive which migrates from the base layer into the covering layers. The base layer contains the inert admixture in the form of finely divided particles, which partially protrude from the base layer and are completely enveloped by the covering layers. At least one of the two outer surfaces of the covering layers displays, at least in partial areas, an increased roughness attributable to the particles protruding from the base layer.
摘要翻译： 公开了一种适用于转移金属化过程的双轴拉伸取向薄膜，其包括在其两面上共挤出覆盖层并包含惰性混合物的基底层。 三层由聚烯烃形成，基层包括从基层向覆盖层迁移的添加剂。 基层包含细分颗粒形式的惰性混合物，其部分地从基层突出并被覆盖层完全包围。 覆盖层的两个外表面中的至少一个至少在部分区域中显示出归因于从基层突出的颗粒的增加的粗糙度。
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公开(公告)号：US4904325A
公开(公告)日：1990-02-27
申请号：US199788
申请日：1988-05-27
申请人： Guenther Crass , Klaus Paschke , Lothar Bothe
发明人： Guenther Crass , Klaus Paschke , Lothar Bothe
CPC分类号： B32B27/32 , C23C14/0005 , H05K3/025 , Y10S428/91 , Y10T428/1438 , Y10T428/24967 , Y10T428/258 , Y10T428/259 , Y10T428/31667 , Y10T428/31692 , Y10T428/31703 , Y10T428/31757 , Y10T428/31913
摘要： A transfer-metallization method in which a metal coating is applied to a top layer of a metallizing film, and the film is then brought into contact with a substrate such that the metal coating is transferred from the top layer to the substrate. The film is a three-layer biaxially-oriented transfer film produced by coextrusion and having a base layer of a polypropylene homopolymer and top layers applied to the two surfaces thereof. The base layer contains an additive depot of migrating monomers in an amount of 0.01 to 2.0 percent by weight, relative to the weight of the polymer constituting the base layer. The top layers are comprised of polypropylene that has a lower viscosity than the polypropylene of the base layer.
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公开(公告)号：US4786533A
公开(公告)日：1988-11-22
申请号：US915083
申请日：1986-10-03
申请人： Guenther Crass , Lothar Bothe
发明人： Guenther Crass , Lothar Bothe
CPC分类号： B32B27/32 , Y10T428/2826 , Y10T428/31663 , Y10T428/31913
摘要： A transparent propylene polymer film, produced by coextrusion and coated on one or both sides, for candy twist wrapping, wherein the propylene polymer base layer additionally contains a low molecular hydrocarbon resin in an amount of 10 to 40% by weight, based on the total weight of propylene polymer and resin, the base layer has a modulus of elasticity of not less than 3,000 N/mm.sup.2, measured in both directions of molecular orientation, and each top layer contains a polydialkylsiloxane in an amount of 0.3 to 1.5% by weight, based on the weight of the top layer.
摘要翻译： 一种透明丙烯聚合物膜，通过共挤出制成并涂覆在一面或两面上，用于糖果扭曲缠绕，其中丙烯聚合物基层另外含有10至40重量％的低分子量烃树脂，基于总计 丙烯聚合物和树脂的重量，基层在分子取向的两个方向上测量的弹性模量不小于3,000N / mm 2，并且每个顶层含有0.3至1.5重量％的聚二烷基硅氧烷， 基于顶层的重量。
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公开(公告)号：US4725466A
公开(公告)日：1988-02-16
申请号：US863447
申请日：1986-05-15
申请人： Guenther Crass , Lothar Bothe
发明人： Guenther Crass , Lothar Bothe
CPC分类号： B32B27/32 , Y10S428/91 , Y10T428/1334 , Y10T428/24967 , Y10T428/259 , Y10T428/2848 , Y10T428/31663 , Y10T428/31913
摘要： A non-sealable polypropylene multi-layer film comprises a base layer and at least one covering layer, the base layer as wella as the covering layer or layers being formed of propylene homopolymers. The covering layers contain a combination of additives composed of (a) from 0.2 to 1.0% by weight of a long-chain aliphatic amine, (b) from 0.2 to 1.0% by weight of a polydialkylsiloxane, and (c) from 0.1 to 1.0% by weight of a platelet-shaped inorganic pigment, the platelets of the pigments being disposed substantially parallel to the surface of the covering layer. The film is preferably produced by a coextrusion process. It is preferably used as a laminating film, an interleaving film or a metallizable film. The novel non-sealable polypropylene multi-layer film has, in particular, good anti-blocking and slip properties, good optical properties, good antistatic properties, and a high scratch resistance. The film can be subjected to a corona treatment without thereby adversely influencing its properties.
摘要翻译： 不可密封的聚丙烯多层膜包括基底层和至少一个覆盖层，基底层以及由丙烯均聚物形成的覆盖层。 覆盖层包含由（a）0.2-1.0重量％的长链脂族胺组成的添加剂组合，（b）0.2-1.0重量％的聚二烷基硅氧烷，和（c）0.1至1.0重量％ 重量％的片状无机颜料，所述颜料的小片基本上平行于覆盖层的表面设置。 膜优选通过共挤出方法制备。 优选用作层压膜，交织膜或金属化膜。 该新颖的不可密封聚丙烯多层膜特别具有良好的防粘连和滑动性能，良好的光学性能，良好的抗静电性能和高耐擦伤性。 该膜可以进行电晕处理，而不会不利地影响其性能。
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公开(公告)号：US4983447A
公开(公告)日：1991-01-08
申请号：US95448
申请日：1987-09-11
申请人： Guenther Crass , Siegfried Janocha , Lothar Bothe
发明人： Guenther Crass , Siegfried Janocha , Lothar Bothe
CPC分类号： B32B27/18 , B32B27/32 , Y10S428/906 , Y10T428/24975 , Y10T428/258 , Y10T428/259 , Y10T428/2826 , Y10T428/31663 , Y10T428/31913
摘要： An opaque polyolefin film having a base layer composed essentially of propylene polymers and having sealing layers present on both sides, composed essentially of sealable olefin polymers, is disclosed. From about 0.2% to 1.5% by weight, relative to the layer of polydialkylsiloxane is incorporated in one of the two sealing layers, and this layer has not been subjected to corona treatment. The other sealing layer has been subjected to corona treatment and has polydialkylsiloxane, not incorporated, but present on the outer surface of this layer, the polydialkylsiloxane having been transferred to this layer by contact between the sealing layer in which polydialkylsiloxane is incorporated. The relative polydialkylsiloxane occupancy of this layer, which is determined by means of ESCA spectroscopy, is not more than 15. The three-layer opaque polyolefin film is prepared by the coextrusion process. It is particularly suitable for use as a packaging film on high-speed packaging machines.
摘要翻译： 公开了一种不透明聚烯烃膜，其具有基本上由丙烯聚合物组成并具有基本上由可密封的烯烃聚合物组成的两侧上的密封层的基层。 相对于聚二烷基硅氧烷层，约0.2重量％至1.5重量％掺入两个密封层之一中，该层未进行电晕处理。 另一个密封层已进行电晕处理，并且具有未加入的聚二烷基硅氧烷，但存在于该层的外表面上，聚二烷基硅氧烷通过其中掺入聚二烷基硅氧烷的密封层之间的接触转移到该层。 通过ESCA光谱法测定的该层的相对聚二烷基硅氧烷占有率不超过15.三层不透明聚烯烃膜通过共挤出法制备。 特别适用于高速包装机上的包装薄膜。
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公开(公告)号：US4734317A
公开(公告)日：1988-03-29
申请号：US836321
申请日：1986-03-05
申请人： Lothar Bothe , Guenther Crass
发明人： Lothar Bothe , Guenther Crass
CPC分类号： B32B27/32 , Y10T428/24967 , Y10T428/2826 , Y10T428/31663 , Y10T428/31667 , Y10T428/31913
摘要： A polyolefin film having a base layer composed essentially of propylene polymers and having sealing layers present on both sides, composed essentially of sealable olefin polymers. Polydialkylsiloxane is incorporated in a first of the two sealing layers, and this layer is not subjected to corona treatment. The second sealing layer is subjected to corona treatment and has polydialkylsiloxane, not incorporated, but present on its outer surface, the polydialkylsiloxane having been transferred to this layer by contact with the sealing layer in which polyidalkylsiloxane is incorporated. The relative polydialkylsiloxane occupancy on the second layer, which is determined by means of ESCA spectroscopy, is not more than 15. The three-layer polyolefin film is prepared by a coextrusion process. It is particularly suitable for use as a packaging film on high-speed packaging machines.
摘要翻译： 一种聚烯烃膜，其基本层基本上由丙烯聚合物组成并且具有基本上由可密封的烯烃聚合物组成的两侧上存在的密封层。 聚二烷基硅氧烷被引入到两个密封层中的第一个中，该层不经过电晕处理。 第二密封层进行电晕处理，并且具有未加入的聚二烷基硅氧烷，但存在于其外表面上，聚二烷基硅氧烷通过与其中掺入聚烷基硅氧烷的密封层接触而转移到该层。 通过ESCA光谱法确定的第二层上的相对聚二烷基硅氧烷占有率不超过15.三层聚烯烃膜通过共挤出法制备。 特别适用于高速包装机上的包装薄膜。
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公开(公告)号：US4921670A
公开(公告)日：1990-05-01
申请号：US218140
申请日：1988-07-13
CPC分类号： C08J5/18 , C08J3/005 , C08L67/02 , G11B5/7305 , C08J2367/02
摘要： A process is described for the production of an oriented, heat-set polyester film including an admixture of polydiorganosiloxane in the amount of 0.001 to 2% by weight, as well as further additives, such as inert inorganic and/or organic particles. The thermoplastic material is melted in an extruder and extruded through an appropriate die to give a cast film, is then quenched, reheated, stretch oriented, and heat set. The characteristic criteria is the addition of the polydiorganosiloxane to the polydiorganosiloxane-free polyester in the form of a masterbatch.
摘要翻译： 描述了一种制备定向的热固性聚酯薄膜的方法，该聚酯薄膜包括0.001至2重量％的聚二有机硅氧烷的混合物，以及其它添加剂，如惰性无机和/或有机颗粒。 将热塑性材料在挤出机中熔融并通过适当的模头挤出以得到流延膜，然后淬火，再加热，拉伸取向和热定形。 特征标准是将聚二有机硅氧烷以母料的形式加入到不含聚二有机硅氧烷的聚酯中。
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公开(公告)号：US4777081A
公开(公告)日：1988-10-11
申请号：US775329
申请日：1985-09-12
申请人： Guenther Crass , Klaus Paschke , Lothar Bothe
发明人： Guenther Crass , Klaus Paschke , Lothar Bothe
CPC分类号： B32B27/32 , C23C14/0005 , H05K3/025 , Y10S428/91 , Y10T428/1438 , Y10T428/24967 , Y10T428/258 , Y10T428/259 , Y10T428/31667 , Y10T428/31692 , Y10T428/31703 , Y10T428/31757 , Y10T428/31913
摘要： A biaxially oriented transfer metallizing film based on polypropylene, and process therefor. The film is a three-layer film produced by coextrusion and having a base layer of a propylene homopolymer and top layers applied to the two surfaces thereof. The base layer contains an additive depot of migrating monomers in an amount of 0.01 to 2.0 percent by weight, relative to the weight of the polymer constituting the base layer. The top layers are polypropylene that has a lower viscosity than the polypropylene of the base layer.
摘要翻译： 基于聚丙烯的双轴取向转移金属化膜及其工艺。 该膜是通过共挤出制备的三层膜，并且具有丙烯均聚物的基层和施加到其两个表面的顶层。 相对于构成基底层的聚合物的重量，基层含有相对于迁移单体的添加剂储存量为0.01〜2.0重量％。 顶层是具有比基层聚丙烯低的粘度的聚丙烯。
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公开(公告)号：US4734318A
公开(公告)日：1988-03-29
申请号：US927163
申请日：1986-11-05
申请人： Guenther Crass , Rudolf Mauer , Lothar Bothe
发明人： Guenther Crass , Rudolf Mauer , Lothar Bothe
CPC分类号： B32B27/32 , Y10T428/24975 , Y10T428/2826 , Y10T428/31663 , Y10T428/31913
摘要： A sealable, transparent multilayer film comprised of a base layer, essentially of polypropylene, which is coated on both sides with further polyolefin layer is described. The base layer is coated on both surfaces with a layer of polypropylene which contains, as additives(i) 0.1 to 1% by weight of an inorganic pigment and(ii) 0.2 to 1% by weight of an oxyalkylamine, in each case relative to the total weight of the layer. Both free surfaces of the polypropylene layers are coated with a sealable covering layer which comprises a combination of(a) 68.5 to 89.7% by weight of an olefin resin composition comprising a copolymer or terpolymer of ethylene, propylene, butylene or further .alpha.-olefins having 5 to 10 carbon atoms or mixtures of these,(b) 5 to 15% by weight of a low molecular weight resin compatible with the olefin resin composition,(c) 5 to 15% by weight of a propylene homopolymer and(d) 0.3 to 1.5% by weight of polydiorganosiloxane,in each case relative to the total weight of the sealable covering layers.
摘要翻译： 描述了一种可密封的透明多层膜，其由基本上由聚丙烯组成的基层，其两面涂覆有另外的聚烯烃层。 基材层在两面上涂覆有一层聚丙烯，该聚丙烯层包含作为添加剂（i）0.1至1重量％的无机颜料和（ii）0.2至1重量％的氧烷基胺，在每种情况下相对于 层的总重量。 聚丙烯层的两个自由表面涂覆有可密封的覆盖层，其包含（a）68.5至89.7重量％的包含乙烯，丙烯，丁烯或其它α-烯烃的共聚物或三元共聚物的烯烃树脂组合物的组合，其具有 5至10个碳原子或它们的混合物，（b）5至15重量％的与烯烃树脂组合物相容的低分子量树脂，（c）5至15重量％的丙烯均聚物和（d）0.3 至1.5重量％的聚二有机硅氧烷，在每种情况下相对于可密封的覆盖层的总重量。
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公开(公告)号：US07045200B2
公开(公告)日：2006-05-16
申请号：US10128563
申请日：2002-04-24
IPC分类号： C08K3/34
CPC分类号： B32B27/08 , B32B27/18 , B32B27/20 , B32B27/36 , B32B2272/00 , B32B2307/518 , B32B2367/00 , B32B2451/00 , B32B2519/00 , C08J5/18 , C08J2367/02 , C08K3/013 , C08K5/3475 , C08K5/3492 , C08L67/02
摘要： A white film whose thickness is in the range from 1 to 500 μm and which comprises, as principal constituent, a crystallizable thermoplastic, wherein the film comprises at least one UV stabilizer as light stabilizer and at least one white pigment, the use of the film, and also a process for its production.
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