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公开(公告)号：US4927578A
公开(公告)日：1990-05-22
申请号：US195663
申请日：1988-05-18
摘要： Virtually uncrosslinked polyacetylenes in film form are prepared by polymerization of acetylene using a liquid catalyst system consisting of an organicaluminum compound and a titanate in the form of a solution in a viscous inert liquid on a substrate to which the catalyst solution is applied, by a process in which, after the polymerization, the polymer is treated with a strong reducing agent which is inert to the organoaluminum catalyst component, the polymer is, if desired, oriented and is freed from residual catalyst and reducing agent by washing with a liquid, doped with a strong electron acceptor or electron donor in a conventional manner to increase the conductivity and dried, and the materials thus obtained are, if desired, covered with a layer or sheath of nonconductive material.
摘要翻译： 膜形式的几乎未交联的聚乙炔通过使用由有机铝化合物和钛酸盐形成的液体催化剂体系的乙炔聚合制备，所述液体催化剂体系为溶液形式的溶液，所述液体催化剂体系是在施加有催化剂溶液的基材上的粘性惰性液体中， 其中聚合后聚合物用对有机铝催化剂组分是惰性的强还原剂处理，如果需要，聚合物是取向的，并通过用液体洗涤而被除去残余的催化剂和还原剂，掺杂 强电子受体或电子给体以常规方式增加导电性并干燥，如果需要，由此获得的材料被非导电材料层或鞘覆盖。
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公开(公告)号：US4566955A
公开(公告)日：1986-01-28
申请号：US631946
申请日：1984-07-18
申请人： Herbert Naarmann
发明人： Herbert Naarmann
CPC分类号： C08G61/124 , C08G73/06 , H01B1/127 , H01M4/60
摘要： Finely divided electrically conductive pyrrole polymers are prepared by a process in which a finely divided pyrrole polymer, obtained by polymerization of pyrroles in solution with an oxygen-containing oxidizing agent, is electrochemically charged in the presence of a conductive salt. The finely divided electrically conductive pyrrole polymers can be used for the production of moldings.
摘要翻译： 精细分散的导电吡咯聚合物通过以下方法制备，其中通过在含有氧的氧化剂溶液中聚合吡咯而获得的细碎的吡咯聚合物在导电盐存在下进行电化学充电。 精细分散的导电吡咯聚合物可用于制造模制品。
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公开(公告)号：US4436854A
公开(公告)日：1984-03-13
申请号：US344015
申请日：1982-01-29
IPC分类号： C08L25/00 , C08K5/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08K5/52 , C08K5/53 , C08L71/04
CPC分类号： C08L51/04 , C08K5/0066 , C08L71/123
摘要： Self-extinguishing molding materials, comprising (A) a polymer of a vinyl-aromatic compound, especially a styrene polymer, which has been made impact-resistant (B) a polyphenylene ether and (C) a flameproofing additive, with or without (D) conventional additives, wherein one part of the soft component of the impact-resistant polymer of the vinyl-aromatic compound has a mean particle size of .ltoreq.1.5 .mu.m and the other part has a mean particle size of .ltoreq.3 .mu.m. Such molding materials not only have good self-extinguishing properties but also give moldings having a particularly uniform matt surface.
摘要翻译： 自动灭火成型材料，包括（A）已经制成抗冲击性的乙烯基芳族化合物，特别是苯乙烯聚合物的聚合物（B）聚苯醚和（C）具有或不具有（D）的（C）阻燃添加剂 ）常规添加剂，其中乙烯基芳族化合物的耐冲击聚合物的一部分软组分的平均粒度为<1.5μm，另一部分的平均粒度为<3μm m。 这种成型材料不仅具有良好的自熄性，而且还具有特别均匀的无光泽表面的模制品。
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公开(公告)号：US4412037A
公开(公告)日：1983-10-25
申请号：US302040
申请日：1981-09-14
IPC分类号： C08L25/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L51/04 , C08L71/123
摘要： Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.
摘要翻译： 基于已经制成抗冲击性的苯乙烯聚合物和聚苯醚的热塑性成型材料，其中已经制成抗冲击性的苯乙烯聚合物的软组分的颗粒具有大于1微米的平均直径，并且其中 直径小于0.6微米的颗粒的比例不小于40重量％，直径为0.6至3微米的颗粒的比例小于3重量％。
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公开(公告)号：US4404359A
公开(公告)日：1983-09-13
申请号：US399211
申请日：1982-07-19
CPC分类号： C08G65/44
摘要： A process for the preparation of high molecular weight polyphenylene ethers from monohydric phenols which have alkyl substituents in both ortho-positions and may additionally have an alkyl substituent in one meta-position but not in the para-position, by an oxidative coupling reaction, employing oxygen, at from 10.degree. to 25.degree. C., in the presence of a catalyst complex comprising a copper salt and an N-substituted imidazole, in the presence of an aromatic C.sub.8 -C.sub.10 -hydrocarbon solvent.N-Methylimidazole, N-ethylimidazole, N-isopropylimidazole, N-n-butylimidazole, N-cyclohexylimidazole, N-octylimidazole and N-phenylimidazole are preferably used as the imidazole, advantageously in amounts of from 0.5 to 5 percent by weight.
摘要翻译： 一种从一元酚制备高分子量聚苯醚的方法，其在两个邻位具有烷基取代基，并且可以通过氧化偶联反应另外在一个间位而不是在对位具有烷基取代基，采用 在含有铜盐和N-取代的咪唑的催化剂络合物存在下，在芳族C 8 -C 10 - 烃溶剂存在下，在10〜25℃下进行。 N-甲基咪唑，N-乙基咪唑，N-异丙基咪唑，N-正丁基咪唑，N-环己基咪唑，N-辛基咪唑，N-苯基咪唑优选用作咪唑，有利地为0.5〜5重量％。
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26.发明授权Thermoplastic molding materials containing polymers with polyphenylene ether groups and styrene polymers 失效含聚苯醚聚合物和苯乙烯聚合物的热塑性成型材料
公开(公告)号：US4387189A
公开(公告)日：1983-06-07
申请号：US297948
申请日：1981-08-31
CPC分类号： C08G81/025
摘要： Thermosplastic molding materials which contain styrene polymers and polyphenylene ethers whose phenolic hydroxyl groups have been reacted with reactive copolymers.
摘要翻译： 含有酚羟基与反应性共聚物反应的苯乙烯聚合物和聚苯醚的热塑性成型材料。
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公开(公告)号：US4277588A
公开(公告)日：1981-07-07
申请号：US129828
申请日：1980-03-13
IPC分类号： C08F238/00 , C08F4/64 , C08F4/68 , C08F38/02 , C08F38/04
CPC分类号： C08F238/00
摘要： A process for the preparation of acetylene copolymers by catalytic polymerization of a mixture of acetylene and dialkynes or polyalkynes, using Ziegler catalysts. The novel polymers may be used as colored pigments, as colored coatings for metal, glass or plastics, and for the production of electrical or magnetic components.
摘要翻译： 使用齐格勒催化剂通过乙炔和二炔烃或多炔烃的混合物的催化聚合制备乙炔共聚物的方法。 新型聚合物可用作有色颜料，作为金属，玻璃或塑料的着色涂料，以及用于制造电或磁性组分。
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公开(公告)号：US4200702A
公开(公告)日：1980-04-29
申请号：US912358
申请日：1978-06-05
摘要： Thermoplastic molding compositions based on rubber-modified styrene-acrylonitrile copolymers containing a halogenated styrene oligomer as the effective flame-proofing agent which is sufficiently heat-stable, does not interfere with processing on conventional machinery, does not corrode or cause coatings on such machinery, and has virtually no adverse effect on the impact strength of the polymers. The flameproofing agent as a rule has a degree of polymerization of from 3 to 200 and can be incorporated into the polymer by conventional methods; the polymer may or may not contain additional synergistic agents and processing auxiliaries, which are incorporated in the conventional manner and in the conventional amounts.
摘要翻译： 含有卤代苯乙烯低聚物作为充分热稳定性的有效阻燃剂的橡胶改性苯乙烯 - 丙烯腈共聚物的热塑性模塑组合物不影响常规机械的加工，不会在这种机械上腐蚀或引起涂层， 并且对聚合物的冲击强度几乎没有不利影响。 通常防火剂的聚合度为3〜200，可以通过常规方法加入到聚合物中; 聚合物可以包含或可以不含有以常规方式和常规量掺入的其它协同剂和加工助剂。
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公开(公告)号：US4158097A
公开(公告)日：1979-06-12
申请号：US782613
申请日：1977-03-30
申请人： Herbert Naarmann , Klaus Penzien
发明人： Herbert Naarmann , Klaus Penzien
CPC分类号： C08F20/24
摘要： New compounds containing tribromomethyl groups, of the general formula ##STR1## WHEREIN X is chlorine or bromine, R is hydrogen or methyl and R.sup.1 is hydrogen or a group of the formula --COO--CHX--CBr.sub.3 and a process for their preparation. The compounds may be used for the manufacture of homopolymers or copolymers which find diverse uses, eg. for the manufacture of moldings, coatings or adhesives. The compounds are manufactured by reacting the corresponding acid chlorides or acid bromides with equivalent amounts of tribromoacetaldehyde. The acid chlorides and bromides have the formula ##STR2## wherein X is chlorine or bromine, R is hydrogen or methyl and R.sup.2 is hydrogen or --COX. The reaction is carried out in the presence of from 0.1 to 10 per cent by weight of a Lewis acid, preferably AlBr.sub.3 or FeBr.sub.3, at from 0 to 80.degree. C., generally with reaction times of from 1 to 10 hours, preferably from 2 to 3 hours. The reaction is carried out without solvents or, with particular advantage, in a solution, of about 50 per cent strength, in an inert aliphatic, cycloaliphatic or aromatic solvent, eg. hexane mixtures, octane mixtures, cyclohexane or toluene. From 0.1 to 10 per cent by weight of magnesium oxide is added to the reaction mixture, prior to the distillation to achieve good yields and compound purity.
摘要翻译： 含有三溴甲基的新化合物，通式为：其中X为氯或溴，R为氢或甲基，R 1为氢或式-COO-CHX-CBr 3基团及其制备方法。 这些化合物可以用于制造均聚物或共聚物，其可以找到不同的用途，例如。 用于制造模制品，涂料或粘合剂。 该化合物通过使相应的酰氯或酸性溴化物与等量的三溴乙醛反应制备。 酰氯和溴化物具有式“其中X是氯或溴，R是氢或甲基，R 2是氢或-COX”。 反应在0.1至10重量百分比的路易斯酸，优选AlBr 3或FeBr 3存在下进行，在0至80℃下，通常反应时间为1至10小时，优选2 至3小时。 该反应在惰性脂族，脂环族或芳族溶剂（例如）中没有溶剂或特别有利的是在约50％的强度溶液中进行。 己烷混合物，辛烷混合物，环己烷或甲苯。 在蒸馏之前，将0.1至10重量％的氧化镁加入到反应混合物中以获得良好的收率和化合物纯度。
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公开(公告)号：US4058508A
公开(公告)日：1977-11-15
申请号：US632641
申请日：1975-11-17
申请人： Herbert Naarmann , Heinz Pohlemann
发明人： Herbert Naarmann , Heinz Pohlemann
摘要： Polymers of which the side chains contain urethane groups and which have the reactivity of a urethane but can, in addition, contain other reactive groups. The new polymers may be used to produce moldings, coatings or adhesives.
摘要翻译： 侧链含有氨基甲酸酯基并且具有氨基甲酸酯的反应性的聚合物，而且还可以含有其它反应性基团。 新的聚合物可用于生产模制品，涂料或粘合剂。
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