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    Production of molding materials containing polyphenylene ethers
    3.
    发明授权
    Production of molding materials containing polyphenylene ethers 失效
    生产含聚苯醚的成型材料

    公开(公告)号：US4436870A

    公开(公告)日：1984-03-13

    申请号：US400689

    申请日：1982-07-22

    申请人： Klaus Hinselmann ,  Herbert Naarmann ,  Adolf Echte ,  Eduard Heil ,  Albert Nikles ,  Rudi W. Reffert ,  Juergen Hambrecht

    发明人： Klaus Hinselmann ,  Herbert Naarmann ,  Adolf Echte ,  Eduard Heil ,  Albert Nikles ,  Rudi W. Reffert ,  Juergen Hambrecht

    IPC分类号： C08L7/00 ,  B29C35/00 ,  B29C45/00 ,  C08G65/46 ,  C08J3/00 ,  C08J3/20 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L71/00 ,  C08L71/12 ,  C08L101/00 ,  C08L71/04

    CPC分类号： C08J3/005 ,  C08G65/46 ,  C08L71/12 ,  Y10S525/905

    摘要： Molding materials containing high molecular weight polyphenylene ethers are produced by a process in which a solution of a polyphenylene ether in an organic solvent, together with another polymer, is freed of solvent by multi-stage evaporation.The solvent is preferably an aromatic compound from the class comprising the hydrocarbons, halohydrocarbons, ethers or esters, the ratio of the other polymer to the polyphenylene ether is advantageously from 99:1 to 20:80 parts by weight, the other polymer is, in particular, a homopolymer or copolymer of styrene or of a homolog thereof, which may be modified with rubber, and the multi-stage evaporation process preferably comprises not less than two and not more than four working up stages.The evaporation is carried out in general at from 120.degree. to 280.degree. C. and under a pressure of from 1 to 3,000 mbar, advantageously in the presence of assistants which reduce the partial pressure, eg. water and/or methanol.

    摘要翻译： 含有高分子量聚苯醚的成型材料是通过多层蒸发而将有机溶剂中的聚苯醚与其它聚合物一起溶解的方法而制得的。 溶剂优选为包含烃类，卤代烃类，醚类或酯类的芳族化合物，另一种聚合物与聚苯醚的比率有利地为99:1至20:80重量份，另一个聚合物为 特别是可以用橡胶改性的苯乙烯或其同系物的均聚物或共聚物，多级蒸发方法优选包括不少于2个且不超过4个加工阶段。 蒸发通常在120℃至280℃和1至3,000毫巴的压力下进行，有利的是在有助于降低分压的助剂的存在下进行。 水和/或甲醇。

    Flameproofed thermoplastic molding material comprising a novolak resin
    10.
    发明授权
    Flameproofed thermoplastic molding material comprising a novolak resin 失效
    包含酚醛清漆树脂的防火热塑性成型材料

    公开(公告)号：US4618636A

    公开(公告)日：1986-10-21

    申请号：US692621

    申请日：1985-01-18

    申请人： Volker Muench ,  Juergen Hambrecht ,  Herbert Naarmann ,  Adolf Echte ,  Karl H. Illers

    发明人： Volker Muench ,  Juergen Hambrecht ,  Herbert Naarmann ,  Adolf Echte ,  Karl H. Illers

    IPC分类号： C08K13/02 ,  C08L25/00 ,  C08L61/04 ,  C08K3/10 ,  C08K5/13 ,  C08K5/51 ,  C08L61/10

    CPC分类号： C08K13/02 ,  C08L25/00 ,  C08L61/04

    摘要： A flameproofed thermoplastic molding material consists ofA. a thermoplastic resin containing a vinylaromatic monomerand furthermore containsB. from 0 to 100 parts by weight of an elastomer having a glass transition temperature Tg 0.degree. C., as an impact modifier,C. from 2 to 50 parts by weight of a halogen-containing organic compound (flameproofing agent),D. from 0.5 to 20 parts by weight of a compound containing a metal or non-metal (synergistic agent) andE. from 5 to 50 parts by weight of a novolak (phenol/aldehyde resin).The novolak is obtained from an aldehyde of the formula (I)R.sup.1 --CHO (I)where R.sup.1 is H, C.sub.1 -C.sub.10 -alkyl, cycloalkyl, C.sub.6 -C.sub.12 -aryl or .omega.-aryl-C.sub.1 -C.sub.3 -alkyl, and a mixture of phenols, and this mixture contains two or more monosubstituted phenols and the substituents can be alkyl of 1 to 8 carbon atoms or CN.The molding material is used for the production of flameproofed moldings.

    摘要翻译： 一种防火热塑性成型材料由A.含有乙烯基芳族单体的热塑性树脂组成，并且还含有0-100重量份玻璃化转变温度Tg 0℃的弹性体，作为抗冲改性剂的C.来自 2至50重量份的含卤素的有机化合物（防火剂），D。0.5至20重量份的含有金属或非金属的化合物（增效剂）和E。5至50份 酚醛清漆（苯酚/醛树脂）的重量。 酚醛清漆得自式（Ⅰ）R1-CHO（Ⅰ）的醛，其中R1是H，C1-C10-烷基，环烷基，C6-C12-芳基或ω-芳基-C1-C3-烷基，和 酚的混合物，并且该混合物含有两个或更多个单取代的酚，并且取代基可以是1至8个碳原子的烷基或CN。 成型材料用于生产防火模制品。