Abstract:
A composition for pattern formation includes a polymer or a polymer set including a plurality of polymers, and an acid generator. The polymer or the polymer set is capable of forming a phase separation structure through directed self-assembly. The polymer or at least one polymer in the polymer set includes an acid-labile group in a side chain thereof. The acid generator generates an acid upon application of energy. A pattern-forming method includes providing a directed self-assembling film on a substrate using the composition. The directed self-assembling film includes a phase separation structure.
Abstract:
A directed self-assembly composition for pattern formation, includes two or more kinds of polymers. The two or more kinds of polymers each do not have a silicon atom in a main chain thereof. At least one of the two or more kinds of polymers has a group binding to the polymerizing end of the main chain and having a hetero atom.
Abstract:
A radiation-sensitive resin composition includes a compound represented by a following formula (1) and a base polymer. In the formula (1), R1 represents a monovalent cyclic organic group having a cyclic ester structure or a cyclic ketone structure; R2 represents a single bond or —CH2—; X is —O—*, —COO—*, —O—CO—O—* or —SO2-O—*, wherein * denotes a binding site to R3; R3 represents a bivalent chain hydrocarbon group having 1 to 5 carbon atoms; and M+ is a monovalent cation. The base polymer has a structural unit derived from (meth)acrylate that includes a lactone skeleton, a structural unit derived from (meth)acrylate that includes a cyclic carbonate skeleton, a structural unit derived from (meth)acrylate that includes a sultone skeleton, a structural unit derived from (meth)acrylate that includes a polar group, or a combination thereof. R1—R2—X—R3—CHF—CF2—SO3−M+ (1)
Abstract translation:辐射敏感性树脂组合物包含由下式(1)表示的化合物和基础聚合物。 式(1)中,R 1表示具有环状酯结构或环状酮结构的1价的环状有机基团, R 2表示单键或-CH 2 - ; X是-O-,-COO- *,-O-CO-O- *或-SO2-O- *,其中*表示与R3的结合位点; R3表示碳原子数为1〜5的二价链烃基; M +是一价阳离子。 基础聚合物具有衍生自包含内酯骨架的(甲基)丙烯酸酯的结构单元,衍生自包含环状碳酸酯骨架的(甲基)丙烯酸酯的结构单元,衍生自包含磺内酯骨架的(甲基)丙烯酸酯的结构单元, 衍生自包括极性基团的(甲基)丙烯酸酯的结构单元或其组合。 R1-R2-X-R3-CHF-CF2-SO3-M +(1)