公开(公告)号：US6004897A

公开(公告)日：1999-12-21

申请号：US683068

申请日：1996-07-16

申请人： Junichi Imuta ,  Masayasu Yoshida ,  Yasushi Tohi

发明人： Junichi Imuta ,  Masayasu Yoshida ,  Yasushi Tohi

IPC分类号： C07F17/00 ,  C08F4/42 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943

摘要： The olefin polymerization catalyst of the invention is formed from a Group IVB transition metal compound represented by the following formula (I) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair. In the olefin polymerization process of the invention using this catalyst or a catalyst formed from a Group IVB transition metal compound represented by the following formula (II) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair, an olefin (co)polymer having a high molecular weight can be obtained with high polymerization activities, and besides an olefin copolymer having a high comonomer content can be obtained even if a comonomer is used in a small amount. ##STR1## wherein, M is a transition metal of Group IVB, at least one of R.sup.1 is an aryl group and the remainder is hydrogen or the like, R.sup.2 is hydrogen, an alkyl group or the like, R.sup.3 and R.sup.4 are each hydrogen, an alkyl group or the like, R.sup.6 is hydrogen, an alkyl group or the like, R.sup.7 is hydrogen, an alkyl group or the like, any one of R.sup.8 and R.sup.9 is an alkyl group, and X.sup.1 and X.sup.2 are each halogen, a hydrocarbon group or the like.

摘要翻译： 本发明的烯烃聚合催化剂由下式（I）表示的ⅣB族过渡金属化合物和有机铝氧化合物或与过渡金属化合物反应形成离子对的化合物形成。 在使用该催化剂的本发明的烯烃聚合方法或由下式（II）表示的IVB族过渡金属化合物和有机铝氧化合物或与过渡金属化合物反应形成离子的化合物形成的催化剂 可以以高聚合活性获得具有高分子量的烯烃（共）聚合物，并且即使使用少量共聚单体，也可以获得具有高共聚单体含量的烯烃共聚物。 其中，M是IVB族的过渡金属，R 1中的至少一个是芳基，其余是氢等，R 2是氢，烷基等，R 3和R 4各自是氢，烷基 R 6为氢，烷基等，R 7为氢，烷基等，R 8和R 9中的任一个为烷基，X 1和X 2各自为卤素，烃基或 喜欢。

公开(公告)号：US06297333B1

公开(公告)日：2001-10-02

申请号：US09315268

申请日：1999-05-20

申请人： Junichi Imuta ,  Masayasu Yoshida ,  Yasushi Tohi

发明人： Junichi Imuta ,  Masayasu Yoshida ,  Yasushi Tohi

IPC分类号： C08F442

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F2500/17 ,  C08F2500/03 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08

摘要： The olefin polymerization catalyst of the invention is formed from a Group IVB transition metal compound represented by the following formula (I) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair. In the olefin polymerization process of the invention using this catalyst or a catalyst formed from a Group IVB transition metal compound represented by the following formula (II) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair, an olefin (co)polymer having a high molecular weight can be obtained with high polymerization activities, and besides an olefin copolymer having a high comonomer content can be obtained even if a comonomer is used in a small amount, wherein, M is a transition metal of Group IVB, at least one of R1 is an aryl group and the remainder is hydrogen or the like, R2 is hydrogen, an alkyl group or the like, R3 and R4 are each hydrogen, an alkyl group or the like, R6 is hydrogen, an alkyl group or the like, R7 is hydrogen, an alkyl group or the like, any one of R8 and R9 is an alkyl group, and X1 and X2 are each halogen, a hydrocarbon group or the like.

摘要翻译： 本发明的烯烃聚合催化剂由下式（I）表示的ⅣB族过渡金属化合物和有机铝氧化合物或与过渡金属化合物反应形成离子对的化合物形成。 在使用该催化剂的本发明的烯烃聚合方法或由下式（II）表示的IVB族过渡金属化合物和有机铝氧化合物或与过渡金属化合物反应形成离子的化合物形成的催化剂 可以获得高聚合活性的具有高分子量的烯烃（共）聚合物，并且即使使用少量共聚单体，也可以获得具有高共聚单体含量的烯烃共聚物，其中M为 IVB族的过渡金属，R 1中的至少一个是芳基，其余是氢等，R 2是氢，烷基等，R 3和R 4各自是氢，烷基等，R 6 是氢，烷基等，R 7是氢，烷​​基等，R 8和R 9中的任一个是烷基，X 1和X 2各自是卤素，烃基等。

公开(公告)号：US5424378A

公开(公告)日：1995-06-13

申请号：US281541

申请日：1994-07-28

申请人： Junichi Imuta ,  Takashi Ueda

发明人： Junichi Imuta ,  Takashi Ueda

IPC分类号： C08F2/06 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  Y10S526/904

摘要： The catalyst for olefin polymerization of the present invention contains R.sup.1.sub.k R.sup.2.sub.1 R.sup.3.sub.m M(SO.sub.3 R.sup.4) (M=Zr, Ti or Hf; R.sup.1-3 =a group having a cyclopentadienyl skeleton) as a catalyst component of a transition metal compound. According to the catalyst of the invention, an olefin polymer having excellent particle properties can be prepared with high polymerization activities, and further a copolymer having a narrow composition distribution can be prepared when two or more monomers are copolymerized. Of the above-mentioned transition metal compounds, a compound represented by the following formula is a novel compound unknown so far and shows excellent catalytic properties. ##STR1## (Cp=a group having a cyclopentadienyl skeleton, X=SO.sub.3 R, a halogen atom, R, OR, NR.sub.n, S(O).sub.q R, SiR.sub.3 or P(O).sub.q R.sub.3, n=1, 2 or 3; q=0, 1 or 2).

摘要翻译： 本发明的烯烃聚合用催化剂作为过渡金属化合物的催化剂成分含有R1kR21R3mM（SO3R4）（M = Zr，Ti或Hf; R1-3 =具有环戊二烯基骨架的基团）。 根据本发明的催化剂，具有优异的颗粒性能的烯烃聚合物可以以高聚合活性制备，并且当两种或多种单体共聚时，可以制备组成分布窄的共聚物。 在上述过渡金属化合物中，由下式表示的化合物是迄今为止未知的新化合物，显示出优异的催化性能。 （Cp =具有环戊二烯基骨架的基团，X = SO 3 R，卤素原子，R，OR，NR n，S（O）q R，SiR 3或P（O）q R 3，n = 1,2或3; q = 0,1或2）。

公开(公告)号：US06346070B1

公开(公告)日：2002-02-12

申请号：US09470664

申请日：1999-12-22

申请人： Takeshi Ohmatsuzawa ,  Fujito Ehara ,  Hideshi Hori ,  Kazuo Toyota ,  Kenzaburou Fukutani ,  Junichi Imuta ,  Akiyoshi Shimizu ,  Takayuki Onogi ,  Seiji Noda ,  Masayuki Sakai ,  Shoji Hiraoka ,  Koji Nakamachi ,  Michio Tsugawa ,  Satoru Miyazoe

发明人： Takeshi Ohmatsuzawa ,  Fujito Ehara ,  Hideshi Hori ,  Kazuo Toyota ,  Kenzaburou Fukutani ,  Junichi Imuta ,  Akiyoshi Shimizu ,  Takayuki Onogi ,  Seiji Noda ,  Masayuki Sakai ,  Shoji Hiraoka ,  Koji Nakamachi ,  Michio Tsugawa ,  Satoru Miyazoe

IPC分类号： C08G6378

CPC分类号： C08G63/85 ,  C08G63/183 ,  C08G63/82 ,  C08G63/88

摘要： The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity and a process for producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom. The present invention further provides a polyester having excellent transparency and tint and molded products of the polyester such as a blow molded article, a film, a sheet and a fiber. The polyester is obtained by polycondensing an aromatic dicarboxylic acid or an ester-forming derivative thereof and an aliphatic diol or an ester-forming derivative thereof in the presence of a catalyst for polyester production which comprises a polycondensation catalyst component comprising a solid titanium compound and a co-catalyst component comprising a magnesium compound. This polyester has a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a weight ratio (Mg/Ti) of magnesium to titanium of not less than 0.01.

摘要翻译： 本发明提供一种能够生产具有高催化活性的聚酯的聚酯制造催化剂和使用该催化剂生产聚酯的方法。 用于聚酯生产的催化剂包括固体钛化合物，其通过脱水干燥由卤化钛水解得到的水解产物并且具有羟基（OH）与钛（Ti）的摩尔比（OH / Ti）超过钛 0.09以上且低于4.本发明还提供一种在成型时获得乙醛含量增加少的聚酯的方法。 该方法包括使通过使用钛化合物催化剂获得的反应已完成的聚酯与浓度不小于10ppm的磷酸酯水溶液等接触，换算为 磷原子。 本发明还提供一种聚酯，其具有优异的透明度和色调，并且聚酯的成型产品如吹塑制品，薄膜，片材和纤维。 在聚酯制造用催化剂的存在下，通过将芳香族二羧酸或其成酯性衍生物和脂肪族二醇或其成酯衍生物缩聚得到聚酯，该催化剂包括含有固体钛化合物的缩聚催化剂组分和 助催化剂组分包含镁化合物。 该聚酯的钛含量为1〜100ppm，镁含量为1〜200ppm，镁与钛的重量比（Mg / Ti）为0.01以上。

公开(公告)号：US07714087B2

公开(公告)日：2010-05-11

申请号：US12153003

申请日：2008-05-12

申请人： Junichi Imuta ,  Norio Kashiwa ,  Seiji Ota ,  Satoru Moriya ,  Tadahito Nobori ,  Kazumi Mizutani

发明人： Junichi Imuta ,  Norio Kashiwa ,  Seiji Ota ,  Satoru Moriya ,  Tadahito Nobori ,  Kazumi Mizutani

IPC分类号： C08F232/08

CPC分类号： C08F297/02 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08J5/18 ,  C08J2351/06 ,  C08J2371/02 ,  C08J2387/00 ,  C08L53/00 ,  C08L2666/02 ,  C09J153/00 ,  C08F4/65927 ,  C08F222/06 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/09 ,  C08F216/00

摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

摘要翻译： 含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。 含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元 例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。 含极性基团的烯烃共聚物可以通过在茂金属催化剂的存在下与含极性基团的单体和/或大分子单体进行聚合来制备。 含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

公开(公告)号：US20090137757A1

公开(公告)日：2009-05-28

申请号：US12153003

申请日：2008-05-12

申请人： Junichi Imuta ,  Norio Kashiwa ,  Seiji Ota ,  Satoru Moriya ,  Tadahito Nobori ,  Kazumi Mizutani

发明人： Junichi Imuta ,  Norio Kashiwa ,  Seiji Ota ,  Satoru Moriya ,  Tadahito Nobori ,  Kazumi Mizutani

IPC分类号： C08F4/44

CPC分类号： C08F297/02 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08J5/18 ,  C08J2351/06 ,  C08J2371/02 ,  C08J2387/00 ,  C08L53/00 ,  C08L2666/02 ,  C09J153/00 ,  C08F4/65927 ,  C08F222/06 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/09 ,  C08F216/00

摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

摘要翻译： 含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。 含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元 例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。 含极性基团的烯烃共聚物可以通过在金属茂催化剂的存在下将α-烯烃与含极性基团的单体和/或大分子单体进行聚合来制备。 含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

公开(公告)号：US6043325A

公开(公告)日：2000-03-28

申请号：US978602

申请日：1997-11-26

申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

IPC分类号： C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/904 ,  Y10S526/943

摘要： A process for olefin polymerization, including polymerizing or copolymerizing an olefin in the presence of an olefin polymerization catalyst composed of: a fine particle carrier; (A) a transition metal compound of a Group IVB metal of the periodic table, containing a ligand having a cyclopentadienyl skeleton; (B) an aluminoxane compound; and optionally (C) an organoaluminum compound, wherein said aluminoxane compound has an alkyl groups to aluminum ratio of 1.3 to 2.1; said transition metal compound (A) and said organoaluminum oxy-compound (B) and said organoaluminum compound being supported on the fine particle carrier; and said solid catalyst having a bulk density of 0.3 g/cm.sup.3 to 0.5 g/cm.sup.3 and a fluidity index of 45 to 70 and an olefin polymerization process using the olefin polymerization catalyst; and an olefin prepolymerized catalyst obtained by prepolymerizing the catalyst, and an olefin polymerization process using the olefin prepolymerized catalyst. The olefin polymerization process produces a polymer showing excellent particle properties and an olefin polymer which does not stick to the wall of the polymerization reactor.

摘要翻译： 一种烯烃聚合方法，包括在烯烃聚合催化剂存在下聚合或共聚烯烃，所述烯烃聚合催化剂由微粒载体构成; （A）周期表第ⅣB族金属的过渡金属化合物，其含有具有环戊二烯基骨架的配位体; （B）铝氧烷化合物; 和任选地（C）有机铝化合物，其中所述铝氧烷化合物具有1.3至2.1的烷基与铝的比率; 所述过渡金属化合物（A）和所述有机铝氧化合物（B）和所述有机铝化合物负载在所述微粒载体上; 所述固体催化剂的体积密度为0.3g / cm 3〜0.5g / cm 3，流动性指数为45〜70，使用该烯烃聚合催化剂的烯烃聚合方法; 和通过使催化剂预聚合获得的烯烃预聚合催化剂和使用烯烃预聚合催化剂的烯烃聚合方法。 烯烃聚合方法产生显示出优异的颗粒性能的聚合物和不粘在聚合反应器壁上的烯烃聚合物。

公开(公告)号：US5795838A

公开(公告)日：1998-08-18

申请号：US513088

申请日：1995-08-09

申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

IPC分类号： C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/904 ,  Y10S526/943

摘要： A solid olefin polymerization catalyst comprising: a fine particle carrier; (A) a transition metal compound of a Group IVB metal of the periodic table, containing a ligand having a cyclopentadienyl skeleton; (B) an organoaluminum oxy-compound; and optionally (C) an organoaluminum compound, wherein said organoaluminum oxy-compound has an alkyl to aluminum ratio of 1.3 to 2.1; said transition metal compound (A) and said organoaluminum oxy-compound (B) and said organoaluminum compound being supported on the fine particle carrier; and said solid catalyst having a bulk density of 0.3 g/cm.sup.3 to 0.5 g/cm.sup.3 and a fluidity index of 45 to 70 and an olefin polymerization process using the olefin polymerization catalyst; and an olefin prepolymerized catalyst obtained by prepolymerizing the catalyst, and an olefin polymerization process using the olefin prepolymerized catalyst. The olefin polymerization catalyst and the olefin prepolymerization catalyst when used to carry out the polymerization of olefins hardly produces a fine-powdery polymer and a polymer showing excellent particle properties can be obtained. Moreover, the resulting olefin polymer does not stick to the wall of the polymerization reactor.

摘要翻译： 一种固体烯烃聚合催化剂，包括：细颗粒载体; （A）周期表第ⅣB族金属的过渡金属化合物，其含有具有环戊二烯基骨架的配位体; （B）有机铝氧化合物; 和任选的（C）有机铝化合物，其中所述有机铝氧化合物的烷基铝比例为1.3-2.1; 所述过渡金属化合物（A）和所述有机铝氧化合物（B）和所述有机铝化合物负载在所述微粒载体上; 所述固体催化剂的体积密度为0.3g / cm 3〜0.5g / cm 3，流动性指数为45〜70，使用该烯烃聚合催化剂的烯烃聚合方法; 和通过使催化剂预聚合获得的烯烃预聚合催化剂和使用烯烃预聚合催化剂的烯烃聚合方法。 当用于进行烯烃聚合的烯烃聚合催化剂和烯烃预聚合催化剂几乎不产生细粉状聚合物，并且可以获得显示出优异的颗粒性能的聚合物。 此外，所得烯烃聚合物不粘附到聚合反应器的壁。

公开(公告)号：USRE40571E1

公开(公告)日：2008-11-11

申请号：US10942080

申请日：2004-09-16

申请人： Takeshi Ohmatsuzawa ,  Fujito Ehara ,  Hideshi Hori ,  Kazuo Toyota ,  Kenzaburou Fukutani ,  Junichi Imuta ,  Akiyoshi Shimizu ,  Takayuki Onogi ,  Seiji Noda ,  Masayuki Sakai ,  Shoji Hiraoka ,  Koji Nakamachi ,  Michio Tsugawa ,  Satoru Miyazoe

发明人： Takeshi Ohmatsuzawa ,  Fujito Ehara ,  Hideshi Hori ,  Kazuo Toyota ,  Kenzaburou Fukutani ,  Junichi Imuta ,  Akiyoshi Shimizu ,  Takayuki Onogi ,  Seiji Noda ,  Masayuki Sakai ,  Shoji Hiraoka ,  Koji Nakamachi ,  Michio Tsugawa ,  Satoru Miyazoe

IPC分类号： C08G63/82

CPC分类号： C08G63/85 ,  C08G63/183 ,  C08G63/82 ,  C08G63/88

摘要： The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.

摘要翻译： 本发明提供一种能够生产具有高催化活性的聚酯的聚酯生产催化剂，使用该催化剂生产聚酯的方法和由其制备的聚酯。 催化剂包括通过将卤化钛水解得到的水解产物脱水干燥得到的固体钛化合物，其羟基（OH）与钛（Ti）的摩尔比（OH / Ti）超过0.09且小于4 在该方法中，聚酯是通过在催化剂存在下使芳族二羧酸或其成酯衍生物和脂肪族二醇或其成酯衍生物缩聚得到的。 所得聚酯具有优异的透明度和色调，钛含量为1〜100ppm，镁含量为1〜200ppm，镁与钛的重量比为0.01以上。

公开(公告)号：US06451959B1

公开(公告)日：2002-09-17

申请号：US10024319

申请日：2001-12-21

申请人： Takeshi Ohmatsuzawa ,  Fujito Ehara ,  Hideshi Hori ,  Kazuo Toyota ,  Kenzaburou Fukutani ,  Junichi Imuta ,  Akivoshi Shimizu ,  Takayuki Onogi ,  Seiji Noda ,  Masayuki Sakai ,  Shoji Hiraoka ,  Koji Nakamachi ,  Michio Tsugawa ,  Satoru Miyazoe

发明人： Takeshi Ohmatsuzawa ,  Fujito Ehara ,  Hideshi Hori ,  Kazuo Toyota ,  Kenzaburou Fukutani ,  Junichi Imuta ,  Akivoshi Shimizu ,  Takayuki Onogi ,  Seiji Noda ,  Masayuki Sakai ,  Shoji Hiraoka ,  Koji Nakamachi ,  Michio Tsugawa ,  Satoru Miyazoe

IPC分类号： C08G6382

CPC分类号： C08G63/88 ,  C08G63/183 ,  C08G63/82 ,  C08G63/85

摘要： The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.

摘要翻译： 本发明提供一种能够生产具有高催化活性的聚酯的聚酯生产催化剂，使用该催化剂生产聚酯的方法和由其制备的聚酯。 催化剂包括通过将卤化钛水解得到的水解产物脱水干燥得到的固体钛化合物，其羟基（OH）与钛（Ti）的摩尔比（OH / Ti）超过0.09且小于4 在该方法中，聚酯是通过在催化剂存在下使芳族二羧酸或其成酯衍生物和脂肪族二醇或其成酯衍生物缩聚得到的。 所得聚酯具有优异的透明度和色调，钛含量为1〜100ppm，镁含量为1〜200ppm，镁与钛的重量比为0.01以上。