摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
The present invention provides a novel olefin polymerization catalyst having excellent olefin polymerization activity and, in polymerization with the catalyst comprising a transition metal compound, a polymerization process for preparing a polymer having a low molecular weight with high polymerization activity. The process comprises polymerizing olefin in the presence of an olefin polymerization catalyst comprising (A) a transition metal compound represented by the following [M: a Group 4 or 5 transition metal atom in the Periodic Table, m: 1–4, R1: H, a C1–C5 linear hydrocarbon group, 3- to 5-membered alicyclic hydrocarbon group, bicycloaliphatic hydrocarbon group wherein two alicyclic rings share one or more carbon atoms, R2 to R6: H, a halogen atom, hydrocarbon group etc, X: H, a halogen atom etc, and n is a valence of M], and (B) at least one compound selected from (B-1) an organometallic compound, (B-2) an organoaluminum oxy compound and (B-3) an ionizing ionic compound.
摘要:
The present invention relates to a polymer having a melt tension (MT (g)) substantially the same as or lower than that of a conventional polymer which is substantially the same as the polymer in the recurring unit of the main skeleton, the molecular weight, the molecular weight distribution and the crystallinity, and having a flow activation energy (Ea (KJ/mol)) larger than a value obtained by adding 5 KJ/mol to the Ea value of the conventional polymer. A preferred example of the polymer is a branched polyolefin comprising 50 to 100% by mol of recurring units derived from ethylene and 0 to 50% by mol of recurring units derived from an α-olefin of 3 to 20 carbon atoms and having the following properties: the flow activation energy (Ea (KJ/mol)) and the α-olefin content (C (% by weight)) satisfy a specific relation, and the melt tension (MT (g)) and the melt flow rate (MFR (g/10 min)) satisfy a specific relation. This branched polyolefin is excellent in moldability and mechanical strength.
摘要:
The invention provides a process using olefin polymerization catalysts exhibiting excellent polymerization activities. The olefin polymerization catalysts of the invention contain a transition metal compound of and at least one of an organometallic compound, an organoaluminum oxy-compound or a compound which reacts with said transition metal compound to form an ion pair. The process using the inventive catalysts is useful in producing α-olefin/conjugated diene copolymers having specific properties.
摘要:
The invention provides olefin polymerization catalysts exhibiting excellent polymerization activities, a process for olefin polymerization using the catalysts, a novel transition metal compound useful for the catalysts, and α-olefin/conjugated diene copolymers having specific properties. The olefin polymerization catalysts of the invention contain (A) a transition metal compound of formula (I), and (B) an organometallic compound, an organoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compounds of the invention are compounds of formula (I) wherein M is a transition metal atom of Group 3 or 4 of the periodic table; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc
摘要翻译:本发明提供了表现出优异聚合活性的烯烃聚合催化剂,使用该催化剂的烯烃聚合方法,用于该催化剂的新型过渡金属化合物和具有特定性质的α-烯烃/共轭二烯共聚物。 本发明的烯烃聚合催化剂含有(A)式(I)的过渡金属化合物和(B)有机金属化合物,有机铝氧化合物或离子化离子化合物。 本发明的新型过渡金属化合物是式(I)的化合物,其中M是周期表第3或4族的过渡金属原子; R 1是烃基等; R 2〜R 5各自为H,卤素,烃基等; R 6是卤素,烃基等; n是满足M价的数; X为卤素,烃基等
摘要:
Disclosed is a novel transition metal compound represented by the following formula: ##STR1## wherein M is a transition metal, X is halogen or the like, R.sup.1 is a hydrocarbon group or the like, R.sup.2 is an aryl group substituted with a halogenated hydrocarbon group, and Y is a divalent silicon-containing group or the like.Also disclosed are an olefin polymerization catalyst component comprising the transition metal compound, an olefin polymerization catalyst comprising the olefin polymerization catalyst component, and a process for olefin polymerization using the olefin polymerization catalyst.An olefin polymerization catalyst component having high polymerization activity can be formed from the transition metal compound. By the use of the olefin polymerization catalyst or the process for olefin polymerization, polyolefins having a high melting point and a high molecular weight can be prepared with high polymerization activity.
摘要:
The novel transition metal catalyst of the invention is represented by the following formula (I): ##STR1## wherein M is a zirconium or hafnium; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom; and Y is a divalent hydrocarbon group, a divalent silicon-containing group.
摘要翻译:本发明的新型过渡金属催化剂由下式(I)表示: R 1是2至6个碳原子的烃基,R 2是6至16个碳原子的芳基; X1和X2各自为卤素原子; Y为二价烃基,二价含硅基团。
摘要:
A process for polymerizing an olefin is capable of polymerizing an olefin with excellent polymerization activity, and comprises polymerizing or copolymerizing an olefin at a polymerization reaction temperature of 50 to 200° C. in the presence of a catalyst comprising a transition metal compound (A) represented by the following formula (I), a compound (B-1) having a reduction ability which reacts with the transition metal compound (A) to convert an imine structure moiety to a metal amide structure, and a compound (B-2) which reacts with the transition metal compound (A) to form an ion pair; wherein M is a transition metal atom of Groups 3 to 11 of the periodic table; m is an integer of 1 to 6; Y is O, S, Se, or —C(R7)—; R1 to R7 may be the same or different, and are each a hydrogen atom, a halogen atom, a hydrocarbon group, an oxgen-containing group, a nitrogen-containing group and the like; n is a number satisfying a valence of M; and X is a hydrogen atom, a halogen atom, a hydrocarbon group and the like.
摘要:
The present invention provides olefin polymerization catalysts which can produce olefin polymers with excellent polymerization activity and an olefin polymerization method using the catalyst, wherein the catalyst comprises a transition metal amide compound represented by general formula (I) below: where M1 is Ti, etc.; R1 is alkyl, (substituted) phenyl, etc.; R2 is C(R5)2C(R6)mC(R5)2— or —C(R5)2—X1—C(R5)2— (X1 representing a silicon-containing group, etc., and R5 and R6 representing hydrocarbon groups, etc.); and R3 is a hydrocarbon group or halogen, etc.; and at least one compound selected from among organoaluminum oxy-compounds, ionizing ionic compounds and organometallic compounds.
摘要:
The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound.