公开(公告)号：US20110213058A1

公开(公告)日：2011-09-01

申请号：US13121493

申请日：2009-09-28

申请人： Ayako Yano

发明人： Ayako Yano

IPC分类号： C08K5/49

CPC分类号： C09K3/10 ,  C08G18/4854 ,  C08G18/718 ,  C08G65/336 ,  C08G2190/00 ,  C08K5/31 ,  C08K5/51 ,  C08L71/02 ,  C08L101/10 ,  C09J171/02 ,  C09J175/08

摘要： The present invention provides a curable composition mainly comprising an organic polymer containing a reactive silyl group, which is free from toxic organotin catalysts so as to be environmentally friendly and maintains good surface properties after being cured. The curable composition of the present invention comprises: (A) an organic polymer having a silyl group cross-linkable by siloxane bond formation; (B) a carboxylic acid and/or a carboxylate metal salt; (C) an amine compound; and (D) a phosphorus compound having an aryl group and a melting point of 23° C. or higher.

摘要翻译： 本发明提供一种可固化组合物，其主要包含含有反应性甲硅烷基的有机聚合物，其不含有毒有机锡催化剂，以便环境友好并且在固化后保持良好的表面性质。 本发明的可固化组合物包含：（A）具有通过硅氧烷键形成可交联的甲硅烷基的有机聚合物; （B）羧酸和/或羧酸盐金属盐; （C）胺化合物; 和（D）具有芳基且熔点为23℃以上的磷化合物。

公开(公告)号：US08008386B2

公开(公告)日：2011-08-30

申请号：US12520967

申请日：2007-12-20

申请人： Ayako Yano ,  Noriko Matsushita ,  Shintaro Komitsu

发明人： Ayako Yano ,  Noriko Matsushita ,  Shintaro Komitsu

IPC分类号： C08K5/41

CPC分类号： C09D143/04 ,  C08G65/2609 ,  C08G65/2663 ,  C08G65/336 ,  C08G65/337 ,  C08K5/29 ,  C08K5/42 ,  C08K5/54 ,  C08L71/02 ,  C08L2666/22 ,  C09D171/02 ,  C09J11/06 ,  C09J171/02 ,  C09K3/10

摘要： The present invention has its object to provide a curable composition not containing any organotin type curing catalyst currently of concern because of the toxic feature thereof, or any volatile compound, excellent in curability and storage stability and, further, capable of providing cured products excellent in strength and elongation; the above object can be achieved by a curable composition which includes: an organic polymer (A) containing a hydrolyzable silyl group in a molecule; an amidine compound (B); and a compound (C) containing a sulfonyl group in a molecule.

摘要翻译： 本发明的目的在于提供一种固化性组合物，其不含有任何有机锡型固化催化剂，因为其毒性特征或任何挥发性化合物，其固化性和储存稳定性优异，并且还能够提供优异的固化产物 强度和伸长率; 上述目的可以通过一种可固化组合物实现，该组合物包括：在分子中含有可水解甲硅烷基的有机聚合物（A） 脒化合物（B）; 和分子中含有磺酰基的化合物（C）。

公开(公告)号：US07807746B2

公开(公告)日：2010-10-05

申请号：US10588363

申请日：2005-01-20

申请人： Hitoshi Tamai ,  Ayako Yano

发明人： Hitoshi Tamai ,  Ayako Yano

IPC分类号： C08L83/00

CPC分类号： C08F8/42 ,  C08K5/005 ,  C09J133/08 ,  Y10S528/901

摘要： The present invention provides a curable composition capable of giving rubbery cured products having excellent adhesion properties to all-purpose substrates, improved weather-resistant adhesion properties to photocatalyst-coated transparent adherends, low modulus and high elongation and, further, showing high weather resistance without undergoing surface cracking or discoloration even when used outdoors for a long period of time. The curable composition of the present invention includes a vinyl polymer (I) and an antioxidant (II). A main chain of the vinyl polymer (I) is a product of living radical polymerization, and the vinyl polymer (I) contains at least one crosslinkable silyl group.

摘要翻译： 本发明提供一种固化性组合物，其能够赋予对各向异性基材优异的粘合性的橡胶状固化物，对光催化剂涂布的透明被粘物的耐候性粘合性优异，低模量和高伸长率，并且还具有高耐候性而无 即使在室外长时间使用也会发生表面裂纹或变色。 本发明的固化性组合物包括乙烯基聚合物（I）和抗氧化剂（II）。 乙烯基聚合物（I）的主链是活性自由基聚合的产物，乙烯基聚合物（I）含有至少一个可交联甲硅烷基。

公开(公告)号：US20090186993A1

公开(公告)日：2009-07-23

申请号：US12279466

申请日：2007-02-09

申请人： Noriko Noro ,  Toshihiko Okamoto ,  Ayako Yano ,  Yoshikazu Morii

发明人： Noriko Noro ,  Toshihiko Okamoto ,  Ayako Yano ,  Yoshikazu Morii

IPC分类号： C08G77/38

CPC分类号： C09K3/1018 ,  C08G65/336 ,  C08K5/0016 ,  C08K5/31 ,  C08L71/02 ,  C08L101/10 ,  C08L2666/22 ,  C09D201/10 ,  C09J133/14

摘要： The present invention has its object to provide a curable composition which comprises a reactive silyl group-containing organic polymer, does not contain, as a silanol condensation catalyst, any organotin type curing catalyst currently of concern because of the toxic feature thereof, is excellent in surface curability and depth curability and, further, can provide cured products excellent in adhesiveness; the above object can be achieved by a curable composition which comprises: an organic polymer (A) containing a silicon-containing group capable of crosslinking under siloxane bond formation; and a guanidine compound (B-1), as a silanol condensation catalyst (B), represented by the general formula (1): R1N═C(NR12)2  (1) (wherein one of the five R1s is an aryl group and the other four R1s each independently is a hydrogen atom or a hydrocarbon group in which the carbon atom at position 1 is saturated).

摘要翻译： 本发明的目的是提供一种可固化组合物，其包含含有反应性甲硅烷基的有机聚合物，由于其毒性特征，目前令人关注的任何有机锡型固化催化剂不含硅烷醇缩合催化剂，因此其优异 表面固化性和深度固化性，并且还可以提供粘合性优异的固化物; 上述目的可以通过一种可固化组合物来实现，该组合物包括：含硅氧烷键形成交联的含硅基团的有机聚合物（A） 和由通式（1）表示的硅烷醇缩合催化剂（B）的胍化合物（B-1）：＆lt;＆lt;直列式说明=“In-Line Formulas”end =“lead” R1N-C（NR12）2（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中五个R1之一是芳基，另外四个R1各自独立地 是氢原子或其中第1位的碳原子饱和的烃基）。

公开(公告)号：US20090182091A1

公开(公告)日：2009-07-16

申请号：US12279623

申请日：2007-02-09

申请人： Noriko Noro ,  Ayako Yano ,  Toshihiko Okamoto

发明人： Noriko Noro ,  Ayako Yano ,  Toshihiko Okamoto

IPC分类号： C08L83/04

CPC分类号： C09K3/1018 ,  C08G65/336 ,  C08K5/0016 ,  C08K5/31 ,  C08L71/02 ,  C08L101/10 ,  C08L2666/22 ,  C09D201/10 ,  C09J133/14

摘要： The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): —SiX3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.

摘要翻译： 本发明的目的是提供一种可固化组合物，其包含作为非有机锡型催化剂的胍化合物，变色少，表面固化性，深度固化性，强度上升和粘合性，并且即使在保存后也能保持固化性; 上述目的可以通过一种可固化组合物来实现，该组合物包括：（A）含硅氧烷键形成能够交联的甲硅烷基的有机聚合物，所述甲硅烷基是由通式（1）表示的基团：-SiX 3（1 ）（其中X表示羟基或可水解基团，并且三个X基团可以相同或不同），（B）作为硅烷醇缩合催化剂的胍化合物（B-1）和（C）增塑剂， 其中组分（B-1）的含量不小于每100重量份组分（A）0.1重量份但低于8重量份，非邻苯二甲酸酯增塑剂占80至100重量份 （C）成分增塑剂的重量％。

公开(公告)号：US20070167583A1

公开(公告)日：2007-07-19

申请号：US10570087

申请日：2004-08-23

申请人： Ayako Yano ,  Shintaro Komitsu

发明人： Ayako Yano ,  Shintaro Komitsu

IPC分类号： C08L83/00 ,  C08G77/00

CPC分类号： C08J3/246 ,  C08J3/24 ,  C08J2333/00 ,  C09K3/10 ,  F16J15/102 ,  F16J15/14

摘要： Desirable properties required of curable compositions include: to have satisfactory storage stability; to give a cured product having a mat surface with almost no residual tack; to give a rubbery cured product having a low modulus and high elongation; and to give a cured product the surface of which is less apt to crack or discolor even in outdoor use. The present invention provides a curable composition which comprises: a vinyl polymer the main chain of which is a product of living radical polymerization and which contains at least one crosslinkable silyl group, and a primary and/or secondary amine having a melting point of not lower than 20° C. The curable composition of the present invention gives a cured product satisfying those properties.

摘要翻译： 可固化组合物所需的理想性质包括：具有令人满意的储存稳定性; 得到具有几乎没有残留粘性的垫表面的固化产物; 得到具有低模量和高伸长率的橡胶状固化产物; 并且即使在户外使用中也能使其表面不易破裂或变色的固化物。 本发明提供一种可固化组合物，其包括：主链是活性自由基聚合的产物，其含有至少一个可交联甲硅烷基的乙烯基聚合物和熔点不低的伯胺和/或仲胺 本发明的固化性组合物得到满足这些特性的固化物。

公开(公告)号：US08907024B2

公开(公告)日：2014-12-09

申请号：US13989116

申请日：2011-11-18

申请人： Kiyoshi Miyafuji ,  Ayako Yano

发明人： Kiyoshi Miyafuji ,  Ayako Yano

IPC分类号： C08L71/02 ,  C09D201/10 ,  C09J183/16 ,  C08L101/10

CPC分类号： C08L71/02 ,  C08L101/10 ,  C09D201/10 ,  C09J183/16

摘要： An object of the present invention is to provide a curable composition that provides high hardness and can be used in adhesives and coating agents. This object can be achieved by a curable composition containing: 100 parts by weight of a reactive silyl group-containing organic polymer (A) that has a number average molecular weight of 2,000 to 6,000 and contains 1.3 to 5 reactive silyl groups per molecule; and 0 to 40 parts by weight of a plasticizer (C). This curable composition is suitable for flooring adhesives and tile adhesives, which require high hardness.

摘要翻译： 本发明的目的是提供一种提供高硬度并可用于粘合剂和涂层剂的可固化组合物。 该目的可以通过含有100重量份的数均分子量为2,000〜6000的含有活性甲硅烷基的有机聚合物（A）和每分子含有1〜5个反应性甲硅烷基的固化性组合物来实现。 和0〜40重量份的增塑剂（C）。 该可固化组合物适用于需要高硬度的地板粘合剂和瓦片粘合剂。

公开(公告)号：US08853309B2

公开(公告)日：2014-10-07

申请号：US13121497

申请日：2009-09-28

申请人： Ayako Yano ,  Noriko Noro

发明人： Ayako Yano ,  Noriko Noro

IPC分类号： C08K5/52 ,  C08G65/336 ,  C09J175/08 ,  C08G18/48 ,  C08L71/02 ,  C08G18/71 ,  C09J171/02 ,  C09K3/10 ,  C08L101/10 ,  C08K5/31 ,  C08K5/51

CPC分类号： C09K3/10 ,  C08G18/4854 ,  C08G18/718 ,  C08G65/336 ,  C08G2190/00 ,  C08K5/31 ,  C08K5/51 ,  C08L71/02 ,  C08L101/10 ,  C09J171/02 ,  C09J175/08

摘要： The present invention aims to provide a curable composition without adverse effects on the environment, which exhibits excellent curability without containing a toxic organotin curing catalyst, and gives a cured product that does not have discoloration and cracks on the surface thereof even after being exposed to the atmosphere and ultraviolet light for a long time. The present invention also aims to provide the cured product. The curable composition comprises: (A) an organic polymer having a reactive silyl group; (B) a guanidine compound having a specific structure; and (C) a phosphorus compound that has an aryl group, has a phosphorus atom with an oxidation number of +5, and has a melting point of 23° C. or higher.

摘要翻译： 本发明的目的在于提供一种不会对环境产生不利影响的固化性组合物，其在不含有毒有机锡固化催化剂的情况下具有优异的固化性，并且即使在暴露于其中之后也能够赋予其表面上不变色和裂纹的固化产物 气氛和紫外线灯长时间。 本发明还旨在提供固化产物。 可固化组合物包含：（A）具有反应性甲硅烷基的有机聚合物; （B）具有特定结构的胍化合物; 和（C）具有芳基的磷化合物，其氧原子数为+5的磷原子，熔点为23℃以上。

公开(公告)号：US08759435B2

公开(公告)日：2014-06-24

申请号：US11918446

申请日：2006-04-12

申请人： Ayako Yano

发明人： Ayako Yano

IPC分类号： C08K5/098

CPC分类号： C08G59/504 ,  C08G65/336 ,  C08K5/17 ,  C08K5/57 ,  C08L33/06 ,  C08L43/04 ,  C08L71/02 ,  C08L2666/22

摘要： An object of the invention is to yield a highly transparent cured article wherein bubbles are less generated when a catalyst and others are added to a curable composition that contains an organic polymer having a silicon-containing group which can be crosslinked by the formation of a siloxane bond and then the resultant mixture is stirred. Another object thereof is to provide a cured article which is small in surface stickiness, slightly gets dirty over a long term, and has a practical adhesiveness. These objects are attained by a curable composition which comprises (A) an organic polymer having a silicon-containing group that can be crosslinked by the formation of a siloxane bond, (B) a bivalent tin carboxylate and (C) an amine compound having no reactive silicon group, and which turns transparent when cured; or a transparent cured article obtained by curing the composition.

摘要翻译： 本发明的目的是提供一种高度透明的固化制品，其中当将催化剂和其它物质加入到含有含硅基团的有机聚合物的可固化组合物中时，产生较少的气泡，所述含硅基团可通过形成硅氧烷而交联 然后将所得混合物搅拌。 其另一个目的是提供一种表面粘性小的固化物，长期稍微变脏，具有实用的粘合性。 这些目的通过可固化组合物来实现，该可固化组合物包含（A）具有可通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）二价羧酸锡和（C）不含 反应性硅基，固化后变透明; 或通过固化该组合物而得到的透明固化物。

公开(公告)号：US20130281591A1

公开(公告)日：2013-10-24

申请号：US13993927

申请日：2011-12-08

申请人： Ayako Yano ,  Takahiro Saito ,  Masaomi Sakabe

发明人： Ayako Yano ,  Takahiro Saito ,  Masaomi Sakabe

IPC分类号： C09J171/02

CPC分类号： C09J171/02 ,  C08F8/42 ,  C08G65/2609 ,  C08G65/336 ,  C08G2650/24 ,  C08L71/02 ,  C08L2205/025 ,  C09K3/10

摘要： An organic polymer, having a number-average molecular weight of 800 to 15,000, and comprising 0.5 or more but less than 1.2 reactive silicon groups in each molecule of the polymer on average, in which the reactive silicon groups are introduced into one-side out of terminals thereof, and heightening, in particular, the proportion of molecules (of the polymer) into each of which the silicon group is introduced.

摘要翻译： 数均分子量为800〜15000的有机聚合物，平均每个分子中含有0.5个以上且小于1.2个的反应性硅基团，其中将反应性硅基团引入一侧 的末端，并且特别是提高（聚合物）分子中引入硅基团的分子的比例。